Progressive Assessment on the Decomposition Reaction of Na Superionic Conducting Ceramics

2016 ◽  
Vol 9 (1) ◽  
pp. 304-310 ◽  
Author(s):  
Jae-Il Jung ◽  
Daekyeom Kim ◽  
Hyojin Kim ◽  
Yong Nam Jo ◽  
Jung Sik Park ◽  
...  

1986 ◽  
Vol 47 (C7) ◽  
pp. C7-435-C7-440
Author(s):  
G.-K. CHUAH ◽  
N. KRUSE ◽  
G. ABEND ◽  
J. H. BLOCK


1980 ◽  
Vol 45 (6) ◽  
pp. 1780-1784 ◽  
Author(s):  
Atanas Andreev ◽  
Lachezar Prahov ◽  
Dimitar Shopov

The formation of Oxygen paramagnetic adducts of Co(II) containing ion-exchange resins in the presence of adsorbed ethylenediamine has been found. The EPR parameters of a complex of the type Co(III) (en)2O-2 and of O-2 species formed in the presence of Co(en)2+3 have been described. The catalytic properties of Co-ethylenediamine surface complexes with respect to the hydrogen peroxide decomposition reaction have been investigated and a probable mechanism has been suggested.



2019 ◽  
Vol 254 ◽  
pp. 300-311 ◽  
Author(s):  
Anchu Ashok ◽  
Anand Kumar ◽  
Janarthanan Ponraj ◽  
Said A. Mansour ◽  
Faris Tarlochan


2019 ◽  
Vol 38 (2) ◽  
pp. 202-212 ◽  
Author(s):  
Ghulam Ali ◽  
Jan Nisar ◽  
Munawar Iqbal ◽  
Afzal Shah ◽  
Mazhar Abbas ◽  
...  

Due to a huge increase in polymer production, a tremendous increase in municipal solid waste is observed. Every year the existing landfills for disposal of waste polymers decrease and the effective recycling techniques for waste polymers are getting more and more important. In this work pyrolysis of waste polystyrene was performed in the presence of a laboratory synthesized copper oxide. The samples were pyrolyzed at different heating rates that is, 5°Cmin−1, 10°Cmin−1, 15°Cmin−1 and 20°Cmin−1 in a thermogravimetric analyzer in inert atmosphere using nitrogen. Thermogravimetric data were interpreted using various model fitting (Coats–Redfern) and model free methods (Ozawa–Flynn–Wall, Kissinger–Akahira–Sunose and Friedman). Thermodynamic parameters for the reaction were also determined. The activation energy calculated applying Coats–Redfern, Ozawa–Flynn–Wall, Kissinger–Akahira–Sunose and Friedman models were found in the ranges 105–148.48 kJmol−1, 99.41–140.52 kJmol−1, 103.67–149.15 kJmol−1 and 99.93–141.25 kJmol−1, respectively. The lowest activation energy for polystyrene degradation in the presence of copper oxide indicates the suitability of catalyst for the decomposition reaction to take place at lower temperature. Moreover, the obtained kinetics and thermodynamic parameters would be very helpful in determining the reaction mechanism of the solid waste in a real system.





2012 ◽  
Vol 37 (4) ◽  
pp. 3602-3611 ◽  
Author(s):  
Deepak Tyagi ◽  
K. Scholz ◽  
S. Varma ◽  
K. Bhattacharya ◽  
S. Mali ◽  
...  


2004 ◽  
Vol 113 (1-3) ◽  
pp. 67-71 ◽  
Author(s):  
Zhao Feng-qi ◽  
Chen Pei ◽  
Hu Rong-zu ◽  
Luo Yang ◽  
Zhang Zhi-zhong ◽  
...  


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