One-Pot Large-Scale Synthesis of Carbon Quantum Dots: Efficient Cathode Interlayers for Polymer Solar Cells

2017 ◽  
Vol 9 (17) ◽  
pp. 14953-14959 ◽  
Author(s):  
Yuzhao Yang ◽  
Xiaofeng Lin ◽  
Wenlang Li ◽  
Jiemei Ou ◽  
Zhongke Yuan ◽  
...  
ACS Nano ◽  
2017 ◽  
Vol 11 (2) ◽  
pp. 1540-1547 ◽  
Author(s):  
Qunwei Tang ◽  
Wanlu Zhu ◽  
Benlin He ◽  
Peizhi Yang

2021 ◽  
Author(s):  
Dineshkumar Sengottuvelu ◽  
Abdul Kalam Shaik ◽  
Satish Mishra ◽  
Mahsa Abbaszadeh ◽  
Nathan Hammer ◽  
...  

Carbon quantum dots (CQDs) are fascinating luminous materials from the carbonaceous family and are increasingly being investigated in many optoelectronic applications due to their unique photoluminescence (PL) characteristics. Herein, we report the synthesis of nitrogen-doped carbon quantum dots (NCQDs) from citric acid and m-phenylenediamine using a one-pot hydrothermal approach. The environment-dependent emission changes of NCQDs were extensively investigated in various solvents, in solid-state, and in physically assembled PMMA-PnBA-PMMA copolymer gels in 2-ethyl hexanol. The NCQDs display bright emission in various solvents as well as in solid-state and a temperature-dependent enhanced emission in gels. In detail, these NCQDs exhibit multicolor PL emission across the visible region and its enhancement upon changing the environment (solutions and polymer matrices). The NCQDs also exhibit excitation-dependent PL and solvatochromism, which are rarely observed in CQDs. Most CQDs are non-emissive in the aggregated or solid-state due to the aggregation-caused quenching (ACQ) effect, limiting their solid-state applications. However, these NCQDs display a strong solid-state emission centered at 568 nm ascribed to the presence of abundant surface functional groups, which helps to prevent the - interaction between the NCQDs and to overcome the ACQ effect in the solid-state. Interestingly, the NCQD containing gels display a significant fluorescence enhancement than the NCQDs in 2-ethyl hexanol solution because of the interaction between the polar PMMA blocks and NCQDs. This research opens up the development of large-scale, low-cost multicolor phosphor for the fabrication of optoelectronic devices, sensing, and bioimaging applications.


2019 ◽  
Vol 30 (12) ◽  
pp. 11063-11069
Author(s):  
Jianan Wang ◽  
Hairong Li ◽  
Qi Lei ◽  
Fangzhi Chang ◽  
Wenhao Fan ◽  
...  

2014 ◽  
Vol 16 (6) ◽  
Author(s):  
Cuiling Ren ◽  
Haosen Yuan ◽  
Yifang Yang ◽  
Hongli Chen ◽  
Yonglei Chen ◽  
...  

2014 ◽  
Vol 105 (7) ◽  
pp. 073306 ◽  
Author(s):  
Chunyu Liu ◽  
Kaiwen Chang ◽  
Wenbin Guo ◽  
Hao Li ◽  
Liang Shen ◽  
...  

2010 ◽  
Vol 2 (4) ◽  
pp. 1211-1219 ◽  
Author(s):  
Li Zhou ◽  
Chao Gao ◽  
Xiaozhen Hu ◽  
Weijian Xu

Nanomaterials ◽  
2020 ◽  
Vol 10 (3) ◽  
pp. 460
Author(s):  
Qiming Yang ◽  
Wen Yang ◽  
Yong Zhang ◽  
Wen Ge ◽  
Xin Yang ◽  
...  

Dye-sensitized solar cells are regarded as promising candidates to resolve the energy and environmental issues in recent years, arising from their solution-processable fabrication technology and high power conversion efficiency. However, there are still several problems regarding how to accelerate the development of this type of photovoltaics, including the limited light-harvesting ability and high-production cost of molecular dye. In the current work, we have systematically studied the role of nitrogen-doped carbon quantum dots (N-CQDs) as co-sensitizers in traditional dye sensitized solar cells. A series of N-CQDs have been prepared by employing chitosan as a precursor via one-pot hydrothermal technology for various times, demonstrating a maximized efficiency as high as 0.089% for an only N-CQDs-based device. Moreover, the co-sensitized solar cell based on N719 dye (C58H86N8O8RuS2) and optimized N-CQDs shows significantly enhanced performance, yielding a solar-to-electric conversion efficiency of up to 9.15% under one standard sun (AM 1.5G) irradiation, which is much higher than the 8.5%-efficiency of the controlled device without N-CQDs. The matched characteristics of energy level, excellent up-convention, and FRET (Förster resonance energy transfer) abilities of N-CQDs are responsible for their improved power conversion efficiency.


2018 ◽  
Vol 10 (5) ◽  
pp. 4895-4903 ◽  
Author(s):  
Ruqin Zhang ◽  
Min Zhao ◽  
Zhongqiang Wang ◽  
Zongtao Wang ◽  
Bo Zhao ◽  
...  

Nanoscale ◽  
2016 ◽  
Vol 8 (8) ◽  
pp. 4742-4747 ◽  
Author(s):  
Jing Tan ◽  
Rui Zou ◽  
Jie Zhang ◽  
Wang Li ◽  
Liqun Zhang ◽  
...  

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