Transition-Metal-Triggered High-Efficiency Lithium Ion Storage via Coordination Interactions with Redox-Active Croconate in One-Dimensional Metal–Organic Anode Materials

2018 ◽  
Vol 10 (7) ◽  
pp. 6398-6406 ◽  
Author(s):  
Lin Zhang ◽  
Fangyi Cheng ◽  
Wei Shi ◽  
Jun Chen ◽  
Peng Cheng
CrystEngComm ◽  
2019 ◽  
Vol 21 (12) ◽  
pp. 1862-1866 ◽  
Author(s):  
Hai-Yang Wu ◽  
Min Huang ◽  
Chao Qin ◽  
Xin-Long Wang ◽  
Hai Hu ◽  
...  

Three polyoxometalates have been synthesized to be utilized as anode materials for lithium ion batteries.


2019 ◽  
Vol 43 (4) ◽  
pp. 1710-1715 ◽  
Author(s):  
Yan Zhou ◽  
Mengke Wu ◽  
Yulin Luo ◽  
Baocheng Pang ◽  
Xiaoru Su ◽  
...  

Two redox active azo-based metal–organic frameworks (Cu-MOF 1 and Ni-MOF 2) exhibit high specific capacities, good rate performances and cycling stabilities when directly used as anode materials for lithium-ion batteries (LIBs).


2020 ◽  
Vol 341 ◽  
pp. 136063
Author(s):  
Jorge Montero ◽  
Daniel Arenas-Esteban ◽  
David Ávila-Brande ◽  
Elizabeth Castillo-Martínez ◽  
Silvia Licoccia ◽  
...  

RSC Advances ◽  
2015 ◽  
Vol 5 (26) ◽  
pp. 20386-20389 ◽  
Author(s):  
Chongchong Zhao ◽  
Cai Shen ◽  
Weiqiang Han

Metal organic nanofibers (MONFs) synthesized from precursors of amino acid and copper nitrate were applied as anode materials for Li-ion batteries.


Author(s):  
Ming-Jun Xiao ◽  
Hong Zhang ◽  
Bo Ma ◽  
Ze-Qi Zhang ◽  
Xiangyang Li ◽  
...  

Developing novel composite materials with delicate micro or nanoscale structures that enable fast lithium transport are crucial for the high performance anode materials of lithium batteries. Herein, we developed a...


Energies ◽  
2020 ◽  
Vol 13 (10) ◽  
pp. 2480
Author(s):  
Evgenii V. Beletskii ◽  
Daniil A. Lukyanov ◽  
Petr S. Vlasov ◽  
Andrei N. Yankin ◽  
Arslan B. Atangulov ◽  
...  

Conjugated coordination polymers attract attention as materials for electrochemical energy storage, mostly as cathode materials for supercapacitors. Faradaic capacity may be introduced to such materials using redox-active building blocks, metals, or ligands. Using this strategy, a novel hybrid cathode material was developed based on a Ni2+ metal-organic polymer. The proposed material, in addition to double-layer capacitance, shows high pseudocapacitance, which arises from the contributions of both the metal center and ligand. A tailoring strategy in the ligand design allows us to minimize the molecular weight of the ligand, which increases its gravimetric energy. According to computational results, the ligand makes the prevailing contribution to the pseudocapacitance of the material. Different approaches to metal–organic polymer (MOP) synthesis were implemented, and the obtained materials were examined by FTIR, Raman spectroscopy, powder XRD, SEM/EDX (energy-dispersive X-ray spectroscopy), TEM, and thermal analysis. Energy-storage performance was comparatively studied with cyclic voltammetry (CV) and galvanostatic charge–discharge (GCD). As a result, materials with an excellent discharge capacity were obtained, reaching the gravimetric energy density of common inorganic cathode materials.


2021 ◽  
Vol 855 ◽  
pp. 157387
Author(s):  
Yanli Tan ◽  
Chunxiao Yang ◽  
Weiwei Qian ◽  
Xin Sui ◽  
Chao Teng ◽  
...  

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