Self-assembly and Li-ion storage performance of three new Nb/W mixed-addendum polyoxometalates based on the {SiNb3W9O40} clusters and transition-metal cations

CrystEngComm ◽  
2019 ◽  
Vol 21 (12) ◽  
pp. 1862-1866 ◽  
Author(s):  
Hai-Yang Wu ◽  
Min Huang ◽  
Chao Qin ◽  
Xin-Long Wang ◽  
Hai Hu ◽  
...  

Three polyoxometalates have been synthesized to be utilized as anode materials for lithium ion batteries.

2020 ◽  
Vol 8 (24) ◽  
pp. 12124-12133 ◽  
Author(s):  
Jin-Sung Park ◽  
Jeong Hoo Hong ◽  
Su Hyun Yang ◽  
Yun Chan Kang

The search for promising anode materials with optimum compositions for use in lithium ion batteries (LIBs) is still underway.


2014 ◽  
Vol 2 (20) ◽  
pp. 7454-7460 ◽  
Author(s):  
H. Z. Zhang ◽  
Q. Q. Qiao ◽  
G. R. Li ◽  
X. P. Gao

PO43− polyanion-doped Li-rich layered oxides offer excellent energy density retention during long cycling due to the stronger anion bonding of PO43− polyanions to transition metal cations.


2016 ◽  
Vol 4 (37) ◽  
pp. 14106-14110 ◽  
Author(s):  
Linyi Bai ◽  
Qiang Gao ◽  
Yanli Zhao

Two fully conjugated covalent organic frameworks present high performance for both gas capture and Li ion storage, confirming their high potential in future Li–gas battery applications.


2017 ◽  
Vol 5 (40) ◽  
pp. 21134-21139 ◽  
Author(s):  
Xinhui Xia ◽  
Shengjue Deng ◽  
Shangshen Feng ◽  
Jianbo Wu ◽  
Jiangping Tu

Hierarchical porous Ti2Nb10O29 nanospheres prepared by a facile solvothermal method are demonstrated with superior Li-ion storage performance with high capacities and good cycling life.


2019 ◽  
Vol 222 ◽  
pp. 31-36 ◽  
Author(s):  
Xuelin Chen ◽  
Ting Xiao ◽  
Shulin Wang ◽  
Jin Li ◽  
Peng Xiang ◽  
...  

2019 ◽  
Vol 48 (34) ◽  
pp. 12832-12838 ◽  
Author(s):  
Qi-Long Wu ◽  
Shi-Xi Zhao ◽  
Le Yu ◽  
Lü-Qiang Yu ◽  
Xiao-Xiao Zheng ◽  
...  

MoO3−x nanobelts with different concentrations of oxygen vacancies were synthesized in situ, whose effects on lithium-ion storage performance were researched.


Materials ◽  
2021 ◽  
Vol 14 (15) ◽  
pp. 4348
Author(s):  
Chi Zhang ◽  
Zheng Wang ◽  
Yu Cui ◽  
Xuyao Niu ◽  
Mei Chen ◽  
...  

The volume expansion during Li ion insertion/extraction remains an obstacle for the application of Sn-based anode in lithium ion-batteries. Herein, the nanoporous (np) Cu6Sn5 alloy and Cu6Sn5/Sn composite were applied as a lithium-ion battery anode. The as-dealloyed np-Cu6Sn5 has an ultrafine ligament size of 40 nm and a high BET-specific area of 15.9 m2 g−1. The anode shows an initial discharge capacity as high as 1200 mA h g−1, and it remains a capacity of higher than 600 mA h g−1 for the initial five cycles at 0.1 A g−1. After 100 cycles, the anode maintains a stable capacity higher than 200 mA h g−1 for at least 350 cycles, with outstanding Coulombic efficiency. The ex situ XRD patterns reveal the reverse phase transformation between Cu6Sn5 and Li2CuSn. The Cu6Sn5/Sn composite presents a similar cycling performance with a slightly inferior rate performance compared to np-Cu6Sn5. The study demonstrates that dealloyed nanoporous Cu6Sn5 alloy could be a promising candidate for lithium-ion batteries.


RSC Advances ◽  
2015 ◽  
Vol 5 (26) ◽  
pp. 20386-20389 ◽  
Author(s):  
Chongchong Zhao ◽  
Cai Shen ◽  
Weiqiang Han

Metal organic nanofibers (MONFs) synthesized from precursors of amino acid and copper nitrate were applied as anode materials for Li-ion batteries.


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