Photonic Microresonators from Charge Transfer in Polymer Particles: Toward Enhanced and Tunable Two-Photon Emission

2018 ◽  
Vol 10 (19) ◽  
pp. 16723-16730 ◽  
Author(s):  
Radhika Vattikunta ◽  
Dasari Venkatakrishnarao ◽  
Chakradhar Sahoo ◽  
Sri Ram Gopal Naraharisetty ◽  
Desai Narayana Rao ◽  
...  
2005 ◽  
pp. 4973 ◽  
Author(s):  
Toby D. M. Bell ◽  
Josemon Jacob ◽  
Maria Angeles-Izquierdo ◽  
Eduard Fron ◽  
Fabian Nolde ◽  
...  

1996 ◽  
Vol 80 (Appendix) ◽  
pp. 339-340
Author(s):  
Makoto Toho ◽  
Hideyoshi Kimura
Keyword(s):  

1970 ◽  
Vol 31 (5) ◽  
pp. 256-257 ◽  
Author(s):  
L.L. Hope ◽  
M.O. Vassell

1994 ◽  
Vol 49 (5) ◽  
pp. 4009-4015 ◽  
Author(s):  
Lin-sheng He ◽  
Xun-li Feng

2012 ◽  
Vol 86 (3) ◽  
Author(s):  
Alexander N. Poddubny ◽  
Pavel Ginzburg ◽  
Pavel A. Belov ◽  
Anatoly V. Zayats ◽  
Yuri S. Kivshar

RSC Advances ◽  
2016 ◽  
Vol 6 (52) ◽  
pp. 46853-46863 ◽  
Author(s):  
Zhi-Bin Cai ◽  
Hai-Min Shen ◽  
Mao Zhou ◽  
Sheng-Li Li ◽  
Yu-Peng Tian

Novel A–(π–D–π–A)3 compounds bearing pyridine end groups are apparently effective in achieving large two-photon responses owing to strong charge transfer.


2018 ◽  
Vol 98 (12) ◽  
Author(s):  
J. K. Verma ◽  
Harmanpreet Singh ◽  
P. K. Pathak

2019 ◽  
Author(s):  
Pralok K. Samanta ◽  
Md Mehboob Alam ◽  
Ramprasad Misra ◽  
Swapan K. Pati

Solvents play an important role in shaping the intramolecular charge transfer (ICT) properties of π-conjugated molecules, which in turn can affect their one-photon absorption (OPA) and two-photon absorption (TPA) as well as the static (hyper)polarizabilities. Here, we study the effect of solvent and donor-acceptor arrangement on linear and nonlinear optical (NLO) response properties of two novel ICT-based fluorescent sensors, one consisting of hemicyanine and dimethylaniline as electron withdrawing and donating groups (molecule 1), respectively and its boron-dipyrromethene (BODIPY, molecule 2)-fused counterpart (molecule 3). Density functional theoretical (DFT) calculations using long-range corrected CAM-B3LYP and M06-2X functionals, suitable for studying properties of ICT molecules, are employed to calculate the desired properties. The dipole moment (µ) as well as the total first hyperpolarizability (β<sub>total</sub>) of the studied molecules in the gas phase is dominantly dictated by the component in the direction of charge transfer. The ratios of vector component of first hyperpolarizability (β<sub>vec</sub>) to β<sub>total</sub> also reveal unidirectional charge transfer process. The properties of the medium significantly affect the OPA, hyperpolarizability and TPA properties of the studied molecules. Time dependent DFT (TDDFT) calculations suggest interchanging between two lowest excited states of molecule 3 from the gas phase to salvation. The direction of charge polarization and dominant transitions among molecular orbitals involved in the OPA and TPA processes are studied. The results presented are expected to be useful in tuning the NLO response of many ICT-based chromophores, especially those with BODIPY acceptors.<br>


2020 ◽  
Vol 27 (4) ◽  
pp. 902-911
Author(s):  
V. G. Bagrov ◽  
D. M. Gitman ◽  
A. A. Shishmarev ◽  
A. J. D. Farias

Synchrotron radiation was originally studied by classical methods using the Liénard–Wiechert potentials of electric currents. Subsequently, quantum corrections to the classical formulas were studied, considering the emission of photons arising from electronic transitions between spectral levels, described in terms of the Dirac equation. In this paper, an intermediate approach is considered, in which electric currents generating the radiation are considered classically while the quantum nature of the radiation is taken into account exactly. Such an approximate approach may be helpful in some cases; it allows one to study one-photon and multi-photon radiation without complicating calculations using corresponding solutions of the Dirac equation. Here, exact quantum states of an electromagnetic field interacting with classical currents are constructed and their properties studied. With their help, the probability of photon emission by classical currents is calculated and relatively simple formulas for one-photon and multi-photon radiation are obtained. Using the specific circular electric current, the corresponding synchrotron radiation is calculated. The relationship between the obtained results and those known before are discussed, for example with the Schott formula, with Schwinger calculations, with one-photon radiation of scalar particles due to transitions between Landau levels, and with some previous results of calculating two-photon synchrotron radiation.


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