Donor–Acceptor Polymers Containing 4,8-Dithienylbenzo[1,2-b:4,5-b′]dithiophene via Highly Selective Direct Arylation Polymerization

2021 ◽  
Vol 3 (2) ◽  
pp. 830-836
Author(s):  
Masayuki Wakioka ◽  
Naohiro Torii ◽  
Masahiko Saito ◽  
Itaru Osaka ◽  
Fumiyuki Ozawa
Keyword(s):  
Direct Arylation ◽  
Donor Acceptor ◽  
Direct Arylation Polymerization

Direct arylation polymerization of asymmetric push–pull aryl halides

2017 ◽  
Vol 8 (16) ◽  
pp. 2438-2441 ◽  
Author(s):  
Liyan You ◽  
Saadia T. Chaudhry ◽  
Yan Zhao ◽  
Junchen Liu ◽  
Xikang Zhao ◽  
...  
Keyword(s):  
Conjugated Polymers ◽  
Aryl Halides ◽  
Direct Arylation ◽  
Donor Acceptor ◽  
Direct Arylation Polymerization ◽  
Polymerization Method

Recently, direct arylation polymerization (DArP) has emerged as a greener polymerization method for donor–acceptor (D–A) type conjugated polymers.

Mixed-Ligand Approach to Palladium-Catalyzed Direct Arylation Polymerization: Synthesis of Donor–Acceptor Polymers Containing Unsubstituted Bithiophene Units

2019 ◽  
Vol 53 (1) ◽  
pp. 158-164 ◽  
Author(s):  
Masayuki Wakioka ◽  
Hazuki Morita ◽  
Nobuko Ichihara ◽  
Masahiko Saito ◽  
Itaru Osaka ◽  
...  
Keyword(s):  
Mixed Ligand ◽  
Direct Arylation ◽  
Palladium Catalyzed ◽  
Donor Acceptor ◽  
Direct Arylation Polymerization

scholarly journals Synthesis of a 1,2-Dithienylethene-Containing Donor-Acceptor Polymer via Palladium-Catalyzed Direct Arylation Polymerization (DArP)

Molecules ◽  
2018 ◽  
Vol 23 (4) ◽  
pp. 981 ◽  
Author(s):  
Masayuki Wakioka ◽  
Natsumi Yamashita ◽  
Hiroki Mori ◽  
Yasushi Nishihara ◽  
Fumiyuki Ozawa
Keyword(s):  
Direct Arylation ◽  
Palladium Catalyzed ◽  
Donor Acceptor ◽  
Direct Arylation Polymerization

scholarly journals Synthesis of donor–acceptor conjugated polymers based on benzo[1,2-b:4,5-b′]dithiophene and 2,1,3-benzothiadiazole via direct arylation polycondensation: towards efficient C–H activation in nonpolar solvents

2014 ◽  
Vol 5 (19) ◽  
pp. 5784-5792 ◽  
Author(s):  
Xiaochen Wang ◽  
Mingfeng Wang
Keyword(s):  
Conjugated Polymers ◽  
Boiling Point ◽  
Direct Arylation ◽  
Nonpolar Solvents ◽  
Donor Acceptor ◽  
High Boiling Point ◽  
Direct Arylation Polymerization ◽  
Direct Arylation Polycondensation

1,2-Dimethylbenzene, as a nonpolar high boiling point solvent, has been discovered to be a superior medium to perform direct-arylation polymerization.

Influence of the aryl spacer in 2,5-dialkoxyphenylene and diaryl substituted thieno[3,4-c]pyrrole-4,6-dione copolymers

2018 ◽  
Vol 6 (22) ◽  
pp. 5992-5998 ◽  
Author(s):  
Robert M. Pankow ◽  
John D. Munteanu ◽  
Barry C. Thompson
Keyword(s):  
Conjugated Polymers ◽  
Direct Arylation ◽  
Donor Acceptor ◽  
Direct Arylation Polymerization ◽  
Polymerization Conditions

Polymerization conditions for direct arylation polymerization (DArP) now allow for the preparation of conjugated polymers, such as donor–acceptor copolymers, where undesired couplings (donor–donor, acceptor–acceptor, or branching defects) are undetectable.

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