scholarly journals Potentiometric MRI of a Superconcentrated Lithium Electrolyte: Testing the Irreversible Thermodynamics Approach

2021 ◽  
pp. 3086-3095
Author(s):  
Andrew A. Wang ◽  
Anna B. Gunnarsdóttir ◽  
Jack Fawdon ◽  
Mauro Pasta ◽  
Clare P. Grey ◽  
...  
Author(s):  
Antony N. Beris ◽  
Brian J. Edwards

This much-needed monograph presents a systematic, step-by-step approach to the continuum modeling of flow phenomena exhibited within materials endowed with a complex internal microstructure, such as polymers and liquid crystals. By combining the principles of Hamiltonian mechanics with those of irreversible thermodynamics, Antony N. Beris and Brian J. Edwards, renowned authorities on the subject, expertly describe the complex interplay between conservative and dissipative processes. Throughout the book, the authors emphasize the evaluation of the free energy--largely based on ideas from statistical mechanics--and how to fit the values of the phenomenological parameters against those of microscopic models. With Thermodynamics of Flowing Systems in hand, mathematicians, engineers, and physicists involved with the theoretical study of flow behavior in structurally complex media now have a superb, self-contained theoretical framework on which to base their modeling efforts.


2005 ◽  
Vol 14 (03n04) ◽  
pp. 667-676 ◽  
Author(s):  
S. D. MAHARAJ ◽  
M. GOVENDER

In a recent approach in modeling a radiating relativistic star undergoing gravitational collapse the role of the Weyl stresses was emphasized. It is possible to generate a model which is physically reasonable by approximately solving the junction conditions at the boundary of the star. In this paper we demonstrate that it is possible to solve the Einstein field equations and the junction conditions exactly. This exact solution contains the Friedmann dust solution as a limiting case. We briefly consider the radiative transfer within the framework of extended irreversible thermodynamics and show that relaxational effects significantly alter the temperature profiles.


2017 ◽  
Vol 62 (4) ◽  
pp. 753-774
Author(s):  
M. Abdia ◽  
H. Molladavoodi ◽  
H. Salarirad

Abstract The rock materials surrounding the underground excavations typically demonstrate nonlinear mechanical response and irreversible behavior in particular under high in-situ stress states. The dominant causes of irreversible behavior are plastic flow and damage process. The plastic flow is controlled by the presence of local shear stresses which cause the frictional sliding. During this process, the net number of bonds remains unchanged practically. The overall macroscopic consequence of plastic flow is that the elastic properties (e.g. the stiffness of the material) are insensitive to this type of irreversible change. The main cause of irreversible changes in quasi-brittle materials such as rock is the damage process occurring within the material. From a microscopic viewpoint, damage initiates with the nucleation and growth of microcracks. When the microcracks length reaches a critical value, the coalescence of them occurs and finally, the localized meso-cracks appear. The macroscopic and phenomenological consequence of damage process is stiffness degradation, dilatation and softening response. In this paper, a coupled elastoplastic-logarithmic damage model was used to simulate the irreversible deformations and stiffness degradation of rock materials under loading. In this model, damage evolution & plastic flow rules were formulated in the framework of irreversible thermodynamics principles. To take into account the stiffness degradation and softening on post-peak region, logarithmic damage variable was implemented. Also, a plastic model with Drucker-Prager yield function was used to model plastic strains. Then, an algorithm was proposed to calculate the numerical steps based on the proposed coupled plastic and damage constitutive model. The developed model has been programmed in VC++ environment. Then, it was used as a separate and new constitutive model in DEM code (UDEC). Finally, the experimental Oolitic limestone rock behavior was simulated based on the developed model. The irreversible strains, softening and stiffness degradation were reproduced in the numerical results. Furthermore, the confinement pressure dependency of rock behavior was simulated in according to experimental observations.


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