scholarly journals Synergistic Catalysis of Brønsted Acid and Lewis Acid Coexisted on Ordered Mesoporous Resin for One-Pot Conversion of Glucose to 5-Hydroxymethylfurfural

ACS Omega ◽  
2019 ◽  
Vol 4 (1) ◽  
pp. 1053-1059 ◽  
Author(s):  
Kaixuan Wang ◽  
Chao Liang ◽  
Qingxiao Zhang ◽  
Fang Zhang
Keyword(s):  
Lewis Acid ◽  
Bronsted Acid ◽  
Brønsted Acid ◽  
One Pot ◽  
Synergistic Catalysis ◽  
Ordered Mesoporous ◽  
Brönsted Acid

scholarly journals Tartaric Acid–Zinc Nitrate as an Efficient Brønsted Acid-Assisted Lewis Acid Catalyst for the Mannich Reaction

2018 ◽  
Vol 42 (9) ◽  
pp. 463-466 ◽  
Author(s):  
Hao Dong ◽  
Qing Liu ◽  
Yuanyu Tian ◽  
Yingyun Qiao
Keyword(s):  
Tartaric Acid ◽  
Lewis Acid ◽  
Mannich Reaction ◽  
Reaction Times ◽  
Acid Catalyst ◽  
Zinc Nitrate ◽  
Bronsted Acid ◽  
Brønsted Acid ◽  
One Pot ◽  
Brönsted Acid

Tartaric acid–zinc nitrate has been found to be an efficient Brønsted acid-assisted Lewis acid catalytic system for the facile synthesis of β-amino carbonyl compounds through the one-pot Mannich reaction of aldehydes, aromatic amines and ketones in ethanol at room temperature. Remarkable enhancement of reactivity by tartaric acid (Brønsted acid) was observed in these reactions in the presence of anhydrous zinc nitrate (Lewis acid), due to coordination of the tartaric acid ligand to zinc ions increasing the acidity of the system. This procedure shows some advantages such as mild reaction conditions, short reaction times and high yields.

One-Pot Conversion of Carbohydrates into 5-(Hydroxymethyl)furfural using Heterogeneous Lewis-Acid and Brønsted-Acid Catalysts

2016 ◽  
Vol 5 (5) ◽  
pp. 747-755 ◽  
Author(s):  
Tingwei Zhang ◽  
Wei Fan ◽  
Wenzhi Li ◽  
Zhiping Xu ◽  
Haosheng Xin ◽  
...  
Keyword(s):  
Lewis Acid ◽  
Acid Catalysts ◽  
Bronsted Acid ◽  
Brønsted Acid ◽  
One Pot ◽  
Hydroxymethyl Furfural ◽  
Brönsted Acid ◽  
Bronsted Acid Catalysts

scholarly journals Tailoring Lewis/Brønsted acid properties of MOF nodes via hydrothermal and solvothermal synthesis: simple approach with exceptional catalytic implications

2021 ◽  
Author(s):  
Sergio Rojas-Buzo ◽  
Benjamin Bohigues ◽  
Christian W. Lopes ◽  
Débora M. Meira ◽  
Mercedes Boronat ◽  
...  
Keyword(s):  
Lewis Acid ◽  
Active Site ◽  
Solvothermal Synthesis ◽  
Simple Approach ◽  
Organic Reactions ◽  
Bronsted Acid ◽  
Brønsted Acid ◽  
Acid Properties ◽  
Brönsted Acid

The Brønsted/Lewis acid properties of Hf-MOF-808 can be tuned by simply controlling the solvent employed in its synthesis, with direct catalytic implications on the activity and selectivity of organic reactions sensitive to the active site nature.

Study on the removal and depolymerization of lignin from corn stover through the synergistic effect of Brønsted acid, Lewis acid and hydrogenation sites

Fuel ◽  
2021 ◽  
Vol 305 ◽  
pp. 121509
Author(s):  
Baikai Zhang ◽  
Wenzhi Li ◽  
Tingwei Zhang ◽  
Xu Li ◽  
Ajibola T. Ogunbiyi ◽  
...  
Keyword(s):  
Synergistic Effect ◽  
Corn Stover ◽  
Lewis Acid ◽  
Bronsted Acid ◽  
Brønsted Acid ◽  
Brönsted Acid

Critical role of Bronsted acid in Lewis-acid-catalyzed synthesis of Amadori and Heyns compounds of β-amino acids

2021 ◽  
pp. 1-11
Author(s):  
Debasree Chanda ◽  
Gangothri M. Venkataswamy ◽  
Lagamawwa V. Hipparagi ◽  
Nanishankar V. Harohally
Keyword(s):  
Amino Acids ◽  
Lewis Acid ◽  
Critical Role ◽  
Bronsted Acid ◽  
Brønsted Acid ◽  
Brönsted Acid ◽  
Acid Catalyzed

scholarly journals Brønsted acid-catalyzed metal-free one-pot synthesis of benzimidazoles via [4+1] heteroannulation of ortho-phenylenediamines with β-oxodithioesters

ARKIVOC ◽  
2017 ◽  
Vol 2018 (2) ◽  
pp. 81-89
Author(s):  
Abhijeet Srivastava ◽  
Gaurav Shukla ◽  
Dhananjay Yadav ◽  
Maya Shankar Singh
Keyword(s):  
Bronsted Acid ◽  
Brønsted Acid ◽  
One Pot ◽  
Metal Free ◽  
One Pot Synthesis ◽  
Brönsted Acid ◽  
Acid Catalyzed

Facile synthesis of chiral indolines through asymmetric hydrogenation of in situ generated indoles

2018 ◽  
Vol 5 (19) ◽  
pp. 2805-2809 ◽  
Author(s):  
Chang-Bin Yu ◽  
Jie Wang ◽  
Yong-Gui Zhou
Keyword(s):  
Asymmetric Hydrogenation ◽  
Hydrogenation Process ◽  
Bronsted Acid ◽  
Brønsted Acid ◽  
Facile Synthesis ◽  
One Pot ◽  
Brönsted Acid ◽  
Palladium Catalyzed ◽  
Intramolecular Condensation

A concise synthesis of chiral indolines has been developed through intramolecular condensation, deprotection and palladium-catalyzed asymmetric hydrogenation in a one-pot process with up to 96% ee. A strong Brønsted acid played an important role in both the formation of indoles and asymmetric hydrogenation process.

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