Controllable Synthesis of Ruthenium Phosphides (RuP and RuP2) for pH-Universal Hydrogen Evolution Reaction

2018 ◽  
Vol 6 (5) ◽  
pp. 6388-6394 ◽  
Author(s):  
Qingbo Chang ◽  
Jingwen Ma ◽  
Yuanzhi Zhu ◽  
Zhen Li ◽  
Danyun Xu ◽  
...  
2021 ◽  
Author(s):  
He-qiang Chang ◽  
Guo-Hua Zhang ◽  
Kuo-Chih Chou

Abstract In order to evaluate the effect of precursors and synthesis strategies on catalytic ability of Mo2C in the hydrogen evolution reaction (HER), four kinds of Mo2C were synthesized using two kinds of MoO3 by two strategies. Compared with the one-step direct carbonization strategy, Mo2C with a large special surface area and a better performance could be synthesized by the two-step strategy composed of a nitridation reaction and a carbonization reaction. Additionally, the as-prepared porous Mo2C nanobelts (NBs) exhibit good electrocatalytic performance with a small overpotential of 165 mV (0.5 M H2SO4) and 124 mV (1 M KOH) at 10 mA cm-2, as well as a Tafel slope of 58 mV dec-1 (0.5 M H2SO4) and 59 mV dec-1 (1 M KOH). The excellent catalytic activity is ascribed to the nano crystallites and porous structure. What’s more, the belt structure also facilitates the charge transport in the materials during the electrocatalytic HER process. Therefore, the two-step strategy provides a new insight into the structural design with superior performance for electrocatalytic HER.


2019 ◽  
Vol 7 (37) ◽  
pp. 21514-21522 ◽  
Author(s):  
Anchun Long ◽  
Wanrong Li ◽  
Min Zhou ◽  
Weicheng Gao ◽  
Bitao Liu ◽  
...  

Catalytic mechanisms and activity trend of Ni-based heterostructures were revealed by combining experimental data and theoretical calculation results.


2018 ◽  
Vol 6 (45) ◽  
pp. 22526-22533 ◽  
Author(s):  
Yuan Sun ◽  
Jie Meng ◽  
Huanxin Ju ◽  
Junfa Zhu ◽  
Qunxiang Li ◽  
...  

The controllable synthesis of 1T′ structured ReSe2−x nanosheets with Se vacancies was achieved; the nanosheets were used as an efficient electrocatalyst for the hydrogen evolution reaction.


2014 ◽  
Vol 134 ◽  
pp. 182-186 ◽  
Author(s):  
Chenjiao Ge ◽  
Ping Jiang ◽  
Wei Cui ◽  
ZongHua Pu ◽  
Zhicai Xing ◽  
...  

2019 ◽  
Vol 7 (30) ◽  
pp. 17790-17796 ◽  
Author(s):  
Juntao Yang ◽  
Guoqing Ning ◽  
Lei Yu ◽  
Yao Wang ◽  
Chenglong Luan ◽  
...  

Morphology-controllable synthesis of PtNi CNCs enclosed by HIFs supported on PG for enhanced HER.


Author(s):  
Lalita Sharma ◽  
Ankita Mathur ◽  
Aditi Halder

Transition oxysulfides (TOS) possess great catalytic activities towards electrochemical applications, however, controllable synthesis of TOS has many constraints. In this article, molybdenum oxysulfide nano-flowers decorated on reduced graphene oxide sheets...


Author(s):  
Min Li ◽  
Minmin Wang ◽  
Dongyuan Liu ◽  
Yuan Pan ◽  
Shoujie Liu ◽  
...  

Single-atom catalysts (SACs) regulated by heteroatoms have displayed great potential as electrocatalysts for highly efficient hydrogen evolution reaction (HER); however, the controllable synthesis of an axial coordination structure of SACs...


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