Development of Adsorbents for Selective Carbon Capture: Role of Homo- and Cross-Coupling in Conjugated Microporous Polymers and Their Carbonized Derivatives

2018 ◽  
Vol 6 (12) ◽  
pp. 17419-17426 ◽  
Author(s):  
Sachin Mane ◽  
Yu-Xia Li ◽  
Xiao-Qin Liu ◽  
Ming Bo Yue ◽  
Lin-Bing Sun
Keyword(s):  
Carbon Capture ◽  
Cross Coupling ◽  
Microporous Polymers ◽  
Conjugated Microporous Polymers

scholarly journals The effects of the crosslinking position and degree of conjugation in perylene tetraanhydride bisimide microporous polymers on fluorescence sensing performance

RSC Advances ◽  
2020 ◽  
Vol 10 (9) ◽  
pp. 5108-5115 ◽  
Author(s):  
Chen Hu ◽  
Ying-Chun Gao ◽  
Can Zhang ◽  
Min Liu ◽  
Tong-Mou Geng
Keyword(s):  
Cross Coupling ◽  
Fluorescence Sensing ◽  
Microporous Polymers ◽  
Efficient Detection ◽  
Sensing Performance ◽  
Coupling Polymerization ◽  
Conjugated Microporous Polymers

In this study, two fluorescence conjugated microporous polymers based on perylene tetraanhydride bisimide (DP4A0 and DP4A2) were prepared via Sonogashira–Hagihara cross-coupling polymerization for the efficient detection of o-nitrophenol (o-NP).

Hypercrosslinked conjugated microporous polymers for carbon capture and energy storage

2017 ◽  
Vol 41 (10) ◽  
pp. 3915-3919 ◽  
Author(s):  
Xiaowei Jiang ◽  
Yunfei Liu ◽  
Jun Liu ◽  
Xiaohui Fu ◽  
Yali Luo ◽  
...  
Keyword(s):  
Energy Storage ◽  
Carbon Capture ◽  
Alkylation Reaction ◽  
Microporous Polymers ◽  
Conjugated Microporous Polymers

Three monomers with different geometrical configurations were employed to synthesize hypercrosslinked conjugated microporous polymers via Friedel–Crafts alkylation reaction.

Theoretical study of the physisorption of organic molecules on conjugated microporous polymers: the critical role of skeleton structures on binding strength

RSC Advances ◽  
2016 ◽  
Vol 6 (60) ◽  
pp. 54841-54847 ◽  
Author(s):  
Wen-Jie Fan ◽  
Gui-Juan Yang ◽  
Jian-Wei Chi ◽  
You Yu ◽  
Da-Zhi Tan
Keyword(s):  
Binding Energy ◽  
Organic Molecules ◽  
Theoretical Study ◽  
Critical Role ◽  
Binding Strength ◽  
Microporous Polymers ◽  
Substituent Group ◽  
Conjugated Microporous Polymers

By enlarging the size (area) in the linker or adding substituent group in the node, the binding energy between CMPs and adsorbates will increase significantly, which demonstrates the critical role of skeleton structures on binding strength.

scholarly journals Exploiting Hansen solubility parameters to tune porosity and function in conjugated microporous polymers

2020 ◽  
Vol 8 (43) ◽  
pp. 22657-22665
Author(s):  
Jie Chen ◽  
Ting Qiu ◽  
Wei Yan ◽  
Charl F. J. Faul
Keyword(s):  
Cross Coupling ◽  
Solubility Parameters ◽  
Coupling Reactions ◽  
Hansen Solubility Parameters ◽  
Microporous Polymers ◽  
Cross Coupling Reactions ◽  
And Function ◽  
Fine Tune ◽  
Hansen Solubility ◽  
Conjugated Microporous Polymers

We expand our recently reported Bristol–Xi'an Jiaotong (BXJ) approach using simple salts to fine tune the porosity of conjugated microporous materials, from Buchwald–Hartwig to Sonogashira–Hagihara, oxidative and Suzuki cross-coupling reactions.

The influences of the structure of thiophene-based conjugated microporous polymers on the fluorescence sensing properties

2020 ◽  
Vol 44 (45) ◽  
pp. 19663-19671
Author(s):  
Tong-Mou Geng ◽  
Chen Hu ◽  
Min Liu ◽  
Can Zhang ◽  
Heng Xu ◽  
...  
Keyword(s):  
Cross Coupling ◽  
Fluorescence Sensing ◽  
Sensing Properties ◽  
Microporous Polymers ◽  
Elemental Analyses ◽  
Coupling Polymerization ◽  
C Nmr ◽  
Conjugated Microporous Polymers

Three thiophene-based conjugated microporous polymers (CMPs: TTPTh, DBTh, and TBTh) were prepared by Sonogashira–Hagihara cross-coupling polymerization, and their structures were characterized by FTIR, ss 13C NMR, and elemental analyses.

Design, preparation and application of conjugated microporous polymers

2013 ◽  
Vol 63 (3) ◽  
pp. 381-392 ◽  
Author(s):  
Qingquan Liu ◽  
Zhe Tang ◽  
Minda Wu ◽  
Zhihua Zhou
Keyword(s):  
Microporous Polymers ◽  
Conjugated Microporous Polymers

scholarly journals Impact of Chemical Structure on the Dynamics of Mass Transfer of Water in Conjugated Microporous Polymers: A Neutron Spectroscopy Study

2021 ◽  
Vol 3 (2) ◽  
pp. 765-776
Author(s):  
Anne A. Y. Guilbert ◽  
Yang Bai ◽  
Catherine M. Aitchison ◽  
Reiner Sebastian Sprick ◽  
Mohamed Zbiri
Keyword(s):  
Mass Transfer ◽  
Chemical Structure ◽  
Neutron Spectroscopy ◽  
Spectroscopy Study ◽  
Microporous Polymers ◽  
Conjugated Microporous Polymers

scholarly journals Rational design of bifunctional conjugated microporous polymers

2021 ◽  
Author(s):  
Yanpei Song ◽  
Pui Ching Lan ◽  
Kyle Martin ◽  
Shengqian Ma
Keyword(s):  
Rational Design ◽  
Organic Polymers ◽  
Porous Organic Polymers ◽  
First Report ◽  
Microporous Polymers ◽  
Conjugated Microporous Polymers

Conjugated microporous polymers (CMPs) are an emerging class of porous organic polymers that combine -conjugated skeletons with permanent micropores. Since their first report in 2007, the enormous exploration of linkage...

Sulfur-doped triazine-conjugated microporous polymers for achieving the robust visible-light-driven hydrogen evolution

2021 ◽  
Vol 421 ◽  
pp. 129825
Author(s):  
Ahmed M. Elewa ◽  
Ahmed F.M. EL-Mahdy ◽  
Mohamed Hammad Elsayed ◽  
Mohamed Gamal Mohamed ◽  
Shiao-Wei Kuo ◽  
...  
Keyword(s):  
Visible Light ◽  
Hydrogen Evolution ◽  
Microporous Polymers ◽  
Visible Light Driven ◽  
Conjugated Microporous Polymers
Sign in / Sign up

Export Citation Format

Share Document