Vibrational Spectroscopy of High Temperature Metal-Halide Vapor Complexes

1982 ◽  
pp. 309-325 ◽  
Author(s):  
G. N. PAPATHEODOROU
Keyword(s):  
High Temperature ◽  
Vibrational Spectroscopy ◽  
Metal Halide

A Review on Stability of Inorganic Metal Halide Perovskites: Challenge and Opportunity for Stable Solar Cells

2021 ◽  
Author(s):  
Wanchun Xiang ◽  
Shengzhong Liu ◽  
Wolfgang Tress
Keyword(s):  
Solar Cells ◽  
High Temperature ◽  
Metal Halide ◽  
Inorganic Perovskite ◽  
The Past ◽  
Intrinsic Stability ◽  
Halide Perovskites

Inorganic perovskite based solar cells (PSCs) have been receiving unprecedented attention worldwide in the past several years due to their higher intrinsic stability towards high temperature and high theoretical power...

Crystal-chemistry and vibrational spectroscopy of ferrinatrite, Na3[Fe(SO4)3]·3H2O, and its high-temperature decomposition

2018 ◽  
Vol 46 (2) ◽  
pp. 119-131 ◽  
Author(s):  
Gennaro Ventruti ◽  
Giancarlo Della Ventura ◽  
Maria Lacalamita ◽  
Marco Sbroscia ◽  
Armida Sodo ◽  
...  
Keyword(s):  
High Temperature ◽  
Crystal Chemistry ◽  
Vibrational Spectroscopy ◽  
Temperature Decomposition

Some Metal Halide – Phosphorus Halide – Alkyl Halide Complexes. Part III. The µ-Trihalohexahalodimetallate Ions of Titanium and Zirconium

1974 ◽  
Vol 52 (16) ◽  
pp. 2880-2888 ◽  
Author(s):  
Joseph I. Bullock ◽  
Frederick W. Parrett ◽  
Nicholas J. Taylor
Keyword(s):  
Vibrational Spectroscopy ◽  
Titanium Tetrachloride ◽  
Alkyl Halide ◽  
Metal Halide ◽  
The Other ◽  
Butyl Chloride ◽  
Halide Complexes ◽  
Titanium Tetrabromide

Titanium tetrachloride reacts rapidly with trichloro-, tribromo- and methyldichlorophosphine in the presence of t-butyl chloride to give compounds containing a phosphonium cation R1R2PX2+ (R1 = t-butyl, R2 = chloride, bromide, or methyl, X = chloride or bromide) and the principal metal-containing anion, Ti2Cl9−. For tribromophosphine and t-butyl chloride a stoichiometric product, [ButPBr3][Ti2Cl9] was obtained which was characterized using vibrational spectroscopy. The other reactions gave non-stoichiometric materials, the sublimates of which may contain higher polymeric anions whilst the residues contained TiCl5− along with the parent dimeric anion.Zirconium tetrachloride and titanium tetrabromide reacted in a similar way to give the new ions Zr2Cl9− and Ti2Br9− in stoichiometric reactions.

scholarly journals β-Eu(BO2)3 – a new member of the β-RE(BO2)3 (RE=Y, Nd, Sm, Gd–Lu) structure family

2019 ◽  
Vol 74 (9) ◽  
pp. 685-692 ◽  
Author(s):  
Birgit Fuchs ◽  
Hubert Huppertz
Keyword(s):  
High Pressure ◽  
High Temperature ◽  
Vibrational Spectroscopy ◽  
Powder Diffraction ◽  
Title Compound ◽  
Line Emission ◽  
Orthorhombic Space Group ◽  
X Ray ◽  
High Pressure High Temperature ◽  
Temperature Experiment

AbstractThe title compound β-Eu(BO2)3 was synthesized in a high-pressure/high-temperature experiment at 4 GPa and 1473 K. The europium borate crystallizes in the orthorhombic space group Pnma (no. 62) with the lattice parameters a = 16.071(2), b = 7.440(4), and c = 12.362(5) Å. The structure is isotypic to the already known meta-borates β-RE(BO2)3 (RE = Y, Nd, Sm, Gd, Dy–Lu) and is built up of approximately triangular ribbons of BO4 tetrahedra. The compound was further characterized by X-ray powder diffraction, vibrational spectroscopy and shows a typical Eu3+ line emission upon excitation at 448 nm.

High-Temperature Switchable Dielectric of an Organic–Inorganic Hybrid Metal Halide with Four-fold Cross-Linking Inorganic Anion Spiral Chains

2020 ◽  
Vol 2 (5) ◽  
pp. 1421-1425
Author(s):  
Yan Sui ◽  
Liang-Jun Wang ◽  
Hui-Qi Lai ◽  
Yu-Xiao Ma ◽  
Yu-Ling Jiang ◽  
...  
Keyword(s):  
High Temperature ◽  
Metal Halide ◽  
Cross Linking ◽  
Inorganic Anion ◽  
Inorganic Hybrid

Conformation of the cycloalkanes C14H28, C16H32, and C22H44 in the liquid and high-temperature crystalline phases by vibrational spectroscopy

1989 ◽  
Vol 111 (6) ◽  
pp. 1947-1958 ◽  
Author(s):  
V. L. Shannon ◽  
H. L. Strauss ◽  
Robert G. Snyder ◽  
C. A. Elliger ◽  
W. L. Mattice
Keyword(s):  
High Temperature ◽  
Vibrational Spectroscopy ◽  
Crystalline Phases

Vibrational spectroscopy study of zinc-containing mixed oxides as regenerable sulphur sorbents at high temperature

1998 ◽  
Vol 16 (1) ◽  
pp. 1-10 ◽  
Author(s):  
J.V Ibarra ◽  
C Cilleruelo ◽  
E Garcı́a ◽  
M Pineda ◽  
J.M Palacios
Keyword(s):  
High Temperature ◽  
Vibrational Spectroscopy ◽  
Mixed Oxides ◽  
Spectroscopy Study
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