Strong Metal-Metal Coupling in a Dinuclear Terpyridinebipyridineruthenium Mixed-Valence Complex Incorporating the Bridging Ligand 1,4-Dicyanamidobenzene Dianion

Ali R. Rezvani; Christopher E. B. Evans; Robert J. Crutchley

doi:10.1021/ic00122a016

Strong Metal-Metal Coupling in a Dinuclear Terpyridinebipyridineruthenium Mixed-Valence Complex Incorporating the Bridging Ligand 1,4-Dicyanamidobenzene Dianion

Inorganic Chemistry ◽

10.1021/ic00122a016 ◽

1995 ◽

Vol 34 (18) ◽

pp. 4600-4604 ◽

Cited By ~ 27

Author(s):

Ali R. Rezvani ◽

Christopher E. B. Evans ◽

Robert J. Crutchley

Keyword(s):

Mixed Valence ◽

Bridging Ligand ◽

Metal Metal ◽

Mixed Valence Complex

A pentaammineruthenium mixed-valence complex with 1,4-dicyanamido-2,3,5,6-tetrachlorobenzene dianion as bridging ligand: symmetry-attenuated electronic coupling between redox sites

Inorganic Chemistry ◽

10.1021/ic00344a005 ◽

1990 ◽

Vol 29 (19) ◽

pp. 3641-3644 ◽

Cited By ~ 10

Author(s):

Manuel A. S. Aquino ◽

Ann E. Bostock ◽

Robert J. Crutchley

Keyword(s):

Mixed Valence ◽

Electronic Coupling ◽

Bridging Ligand ◽

Redox Sites ◽

Mixed Valence Complex

Intramolecular, base-induced formation of a metal-metal bond in [L2MoIII2(.mu.-OH)(.mu.-CH3CO2)2]3+ (L = 1,4,7-trimethyl-1,4,7-triazacyclononane). Crystal structures of [L2MoIII2(.mu.-OH)(.mu.-CH3CO2)2](ClO4)3.cntdot.H2O and [L2MoIII2(.mu.-O)(.mu.-CH3CO2)2](ClO4)(BF4).cntdot.H2O and of the mixed-valence complex [L2MoIIIMoIV(.mu.-O)(.mu.-CH3CO2)2](ClO43.cntdot.H2O

Inorganic Chemistry ◽

10.1021/ic00302a013 ◽

1989 ◽

Vol 28 (3) ◽

pp. 432-440 ◽

Cited By ~ 9

Author(s):

Karl Wieghardt ◽

Ursula Bossek ◽

Ademir Neves ◽

Bernhard Nuber ◽

Johannes Weiss

Keyword(s):

Crystal Structures ◽

Mixed Valence ◽

Metal Bond ◽

Metal Metal ◽

Mixed Valence Complex

Determination of the metal-metal distance in the mixed valence complex K2Pt(CN)4BO 3•3H2O

Journal of Chemical Education ◽

10.1021/ed062p254 ◽

1985 ◽

Vol 62 (3) ◽

pp. 254 ◽

Cited By ~ 2

Author(s):

Diana L. Sedney ◽

Martin Tanner

Keyword(s):

Mixed Valence ◽

Metal Metal ◽

Mixed Valence Complex

Mixed-valence properties of a dinuclear ruthenium complex bridged by bis(phenylcyanamido)tetrazine

Canadian Journal of Chemistry ◽

10.1139/cjc-2014-0307 ◽

2014 ◽

Vol 92 (11) ◽

pp. 1081-1085 ◽

Cited By ~ 1

Author(s):

Fatemeh Habibagahi ◽

Robert J. Crutchley

Keyword(s):

Ruthenium Complex ◽

Mixed Valence ◽

Transition Dipole Moment ◽

The Novel ◽

Transition Dipole ◽

H Nmr ◽

Bridging Ligand ◽

Metal Metal ◽

Dinuclear Ruthenium ◽

The Stability

The novel bridging ligand 3,6-bis(phenylcyanamido)-1,2,4,5-tetrazine (tdpcH2) and its dinuclear complex [{Ru(ttpy)(bpy)}2(μ-tdpc)][PF6]2 were prepared and characterized by elemental analysis and 1H NMR spectroscopy. Cyclic voltammetry and vis-NIR and IR spectroelectrochemistry of [{Ru(ttpy)(bpy)}2(μ-tdpc)]2+ showed that [{Ru(ttpy)(bpy)}2(μ-tdpc)]3+ is a Class II mixed-valence system with metal−metal coupling of 400 cm−1 assuming a transition dipole moment length of 21 Å. DFT calculations of tdpc2− suggested that the stability of the HOMO results in weak metal−metal coupling via the hole-superexchange mechanism.

A Donor−Acceptor−Donor Bridging Ligand in a Class III Mixed-Valence Complex

Inorganic Chemistry ◽

10.1021/ic001268u ◽

2001 ◽

Vol 40 (6) ◽

pp. 1189-1195 ◽

Cited By ~ 55

Author(s):

Peter J. Mosher ◽

Glenn P. A. Yap ◽

Robert J. Crutchley

Keyword(s):

Mixed Valence ◽

Class Iii ◽

Bridging Ligand ◽

Donor Acceptor ◽

Mixed Valence Complex

The First Example of Isomerization of a Dimetal Complex Involving the Switch of a Metal−Metal Bond Order from 3 to 0. Synthesis and Characterization of the Paramagnetic Mixed-Valence Complex Cation [(XylNC)(OC)Re(μ-Cl)2(μ-dppm)2ReCl(CNXyl)]+ 1

Journal of the American Chemical Society ◽

10.1021/ja962910f ◽

1996 ◽

Vol 118 (51) ◽

pp. 13091-13092 ◽

Cited By ~ 4

Author(s):

Wengan Wu ◽

Phillip E. Fanwick ◽

Richard A. Walton

Keyword(s):

Bond Order ◽

Complex Cation ◽

Mixed Valence ◽

Synthesis And Characterization ◽

Metal Bond ◽

Metal Metal ◽

Mixed Valence Complex

The influence of cis/trans isomerism on the physical properties of a cyano-bridged dinuclear mixed valence complex

Journal of the Chemical Society Dalton Transactions ◽

10.1039/b110461f ◽

2002 ◽

pp. 1435 ◽

Cited By ~ 30

Author(s):

Paul V. Bernhardt ◽

Brendan P. Macpherson ◽

Manuel Martinez

Keyword(s):

Physical Properties ◽

Mixed Valence ◽

Mixed Valence Complex

Design, synthesis and physico-chemical studies of a Co(II)/Co(III) mixed-valence complex: An experimental and DFT approach.

Journal of Molecular Structure ◽

10.1016/j.molstruc.2021.130384 ◽

2021 ◽

pp. 130384

Author(s):

Intissar Hamdi ◽

Noureddine Mhadhbi ◽

Noureddine Issaoui ◽

Andreas Roodt ◽

Mark M. Turnbull ◽

...

Keyword(s):

Mixed Valence ◽

Design Synthesis ◽

Physico Chemical ◽

Chemical Studies ◽

Mixed Valence Complex

ChemInform Abstract: EXPERIMENTAL EVIDENCE FOR TRAPPED VALENCES IN THE MIXED-VALENCE COMPLEX μ-PYRAZINE-BIS(PENTAAMMINERUTHENIUM) TOSYLATE. ELECTRON PARAMAGNETIC RESONANCE, MAGNETIC SUSCEPTIBILITY, AND NUCLEAR MAGNETIC RESONANCE RESULTS

Chemischer Informationsdienst ◽

10.1002/chin.197838290 ◽

1978 ◽

Vol 9 (38) ◽

Author(s):

B. C. BUNKER ◽

R. S. DRAGO ◽

D. N. HENDRICKSON ◽

R. M. RICHMAN ◽

S. L. KESSELL

Keyword(s):

Nuclear Magnetic Resonance ◽

Electron Paramagnetic Resonance ◽

Magnetic Susceptibility ◽

Magnetic Resonance ◽

Experimental Evidence ◽

Mixed Valence ◽

Paramagnetic Resonance ◽

Electron Paramagnetic ◽

Mixed Valence Complex ◽

Nuclear Magnetic

Elemental Carbon Chain Bridging Two Iron Centers: Syntheses and Spectroscopic Properties of [Cp(dppe)Fe-C4-FeCp(dppe)]n+.cntdot.n[PF6]-. X-ray Crystal Structure of the Mixed Valence Complex (n = 1)

Journal of the American Chemical Society ◽

10.1021/ja00132a013 ◽

1995 ◽

Vol 117 (27) ◽

pp. 7129-7138 ◽

Cited By ~ 262

Author(s):

Nathalie Le Narvor ◽

Loic Toupet ◽

Claude Lapinte

Keyword(s):

Crystal Structure ◽

Elemental Carbon ◽

Mixed Valence ◽

Spectroscopic Properties ◽

Carbon Chain ◽

X Ray ◽

Mixed Valence Complex

Strong Metal-Metal Coupling in a Dinuclear Terpyridinebipyridineruthenium Mixed-Valence Complex Incorporating the Bridging Ligand 1,4-Dicyanamidobenzene Dianion

A pentaammineruthenium mixed-valence complex with 1,4-dicyanamido-2,3,5,6-tetrachlorobenzene dianion as bridging ligand: symmetry-attenuated electronic coupling between redox sites

Determination of the metal-metal distance in the mixed valence complex K2Pt(CN)4BO 3•3H2O

Mixed-valence properties of a dinuclear ruthenium complex bridged by bis(phenylcyanamido)tetrazine

A Donor−Acceptor−Donor Bridging Ligand in a Class III Mixed-Valence Complex

The First Example of Isomerization of a Dimetal Complex Involving the Switch of a Metal−Metal Bond Order from 3 to 0. Synthesis and Characterization of the Paramagnetic Mixed-Valence Complex Cation [(XylNC)(OC)Re(μ-Cl)2(μ-dppm)2ReCl(CNXyl)]+ 1

The influence of cis/trans isomerism on the physical properties of a cyano-bridged dinuclear mixed valence complex

Design, synthesis and physico-chemical studies of a Co(II)/Co(III) mixed-valence complex: An experimental and DFT approach.

ChemInform Abstract: EXPERIMENTAL EVIDENCE FOR TRAPPED VALENCES IN THE MIXED-VALENCE COMPLEX μ-PYRAZINE-BIS(PENTAAMMINERUTHENIUM) TOSYLATE. ELECTRON PARAMAGNETIC RESONANCE, MAGNETIC SUSCEPTIBILITY, AND NUCLEAR MAGNETIC RESONANCE RESULTS

Elemental Carbon Chain Bridging Two Iron Centers: Syntheses and Spectroscopic Properties of [Cp*(dppe)Fe-C4-FeCp*(dppe)]n+.cntdot.n[PF6]-. X-ray Crystal Structure of the Mixed Valence Complex (n = 1)

Elemental Carbon Chain Bridging Two Iron Centers: Syntheses and Spectroscopic Properties of [Cp(dppe)Fe-C4-FeCp(dppe)]n+.cntdot.n[PF6]-. X-ray Crystal Structure of the Mixed Valence Complex (n = 1)