Ruthenium(II) and Ruthenium(IV) Complexes Containing κ1-P-, κ2-P,O-, and κ3-P,N,O-Iminophosphorane-Phosphine Ligands Ph2PCH2P{NP(O)(OR)2}Ph2(R = Et, Ph):  Synthesis, Reactivity, Theoretical Studies, and Catalytic Activity in Transfer Hydrogenation of Cyclohexanone

2003 ◽  
Vol 42 (10) ◽  
pp. 3293-3307 ◽  
Author(s):  
Victorio Cadierno ◽  
Pascale Crochet ◽  
Josefina Díez ◽  
Joaquín García-Álvarez ◽  
Sergio E. García-Garrido ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Phosphine Ligands ◽  
Transfer Hydrogenation ◽  
Theoretical Studies

Unsaturated Mo in Mo4O4N3 for efficient catalytic transfer hydrogenation of nitrobenzene using stoichiometric hydrazine hydrate

2021 ◽  
Author(s):  
Shicheng Luo ◽  
Yu Long ◽  
Kun Liang ◽  
Jiaheng Qin ◽  
Yi Qiao ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Hydrazine Hydrate ◽  
Transfer Hydrogenation ◽  
Catalytic Transfer Hydrogenation ◽  
Catalytic Transfer

Unsaturated Mo in Mo4O4N3 exhibited efficient catalytic activity for transfer hydrogenation of nitrobenzene using stoichiometric N2H4·H2O.

scholarly journals Preparation of monocarbonyl ruthenium complexes bearing bidentate nitrogen and phosphine ligands and their catalytic activity in carbonyl compound reduction

2019 ◽  
Vol 48 (33) ◽  
pp. 12560-12576 ◽  
Author(s):  
Steven Giboulot ◽  
Clara Comuzzi ◽  
Alessandro Del Zotto ◽  
Rosario Figliolia ◽  
Giovanna Lippe ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Carbonyl Compound ◽  
Ruthenium Complexes ◽  
Ruthenium Catalysts ◽  
Phosphine Ligands ◽  
Diphosphine Ligands ◽  
Straightforward Approach

A series of novel monocarbonyl ruthenium catalysts containing bidentate dinitrogen or/and diphosphine ligands are easily obtained through a general and straightforward approach.

Artificial metalloenzymes derived from bovine β-lactoglobulin for the asymmetric transfer hydrogenation of an aryl ketone – synthesis, characterization and catalytic activity

2014 ◽  
Vol 43 (14) ◽  
pp. 5482-5489 ◽  
Author(s):  
Alice Chevalley ◽  
Mickael V. Cherrier ◽  
Juan C. Fontecilla-Camps ◽  
Mahsa Ghasemi ◽  
Michèle Salmain
Keyword(s):  
Catalytic Activity ◽  
Fatty Acid ◽  
Transfer Hydrogenation ◽  
Asymmetric Transfer Hydrogenation ◽  
P Protein ◽  
Artificial Metalloenzymes ◽  
Diimine Complexes ◽  
Β Lactoglobulin ◽  
Aryl Ketone

Protein hybrids resulting from the supramolecular anchoring to bovine β-lactoglobulin of fatty acid-derived Rh(iii) diimine complexes catalysed the asymmetric transfer hydrogenation of trifluoroacetophenone with up to 32% ee.

Nitrogen-enriched porous carbon supported Pd-nanoparticles as an efficient catalyst for the transfer hydrogenation of alkenes

2018 ◽  
Vol 42 (20) ◽  
pp. 16823-16828 ◽  
Author(s):  
Jie Li ◽  
Xin Zhou ◽  
Ning-Zhao Shang ◽  
Cheng Feng ◽  
Shu-Tao Gao ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Porous Carbon ◽  
Pd Nanoparticles ◽  
Transfer Hydrogenation ◽  
High Catalytic Activity ◽  
Efficient Catalyst ◽  
Supported Pd

Well-dispersed Pd nanoparticles supported on nitrogen-enriched porous carbon were prepared and this material displayed excellent catalytic activity for the transfer hydrogenation of alkenes. The Pd@NPC catalyst exhibited high catalytic activity and stability for the hydrogenation of alkenes.

The origin of different driving forces between O–H/N–H functional groups in metal ligand cooperation: mechanistic insight into Mn(i) catalysed transfer hydrogenation

2020 ◽  
Vol 10 (1) ◽  
pp. 169-179 ◽  
Author(s):  
Li Zhou ◽  
Datai Liu ◽  
Haiyi Lan ◽  
Xiujian Wang ◽  
Cunyuan Zhao ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Functional Groups ◽  
Driving Forces ◽  
Transfer Hydrogenation ◽  
Bifunctional Catalysts ◽  
Mechanistic Insight ◽  
Insight Into ◽  
Metal Ligand

The origin of different catalytic activity between two structurally similar Lewis basic bifunctional catalysts.

scholarly journals Complexes of the tripodal phosphine ligands PhSi(XPPh2)3(X = CH2, O): synthesis, structure and catalytic activity in the hydroboration of CO2

2016 ◽  
Vol 45 (37) ◽  
pp. 14774-14788 ◽  
Author(s):  
Alicia Aloisi ◽  
Jean-Claude Berthet ◽  
Caroline Genre ◽  
Pierre Thuéry ◽  
Thibault Cantat
Keyword(s):  
Catalytic Activity ◽  
Coordination Chemistry ◽  
Electronic Properties ◽  
Phosphine Ligands ◽  
Phosphorus Ligands ◽  
The Impact

The coordination chemistry of Fe2+, Co2+and Cu+ions was explored with the ligands PhSi{CH2PPh2}3(1) and PhSi{OPPh2}3(2), so as to evaluate the impact of the electronic properties of the tripodal phosphorus ligands on the structure and reactivity of the corresponding complexes.

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