Activation Parameters for Cyclohexene Oxygenation by an Oxoiron(IV) Porphyrin π-Cation Radical Complex:  Entropy Control of an Allylic Hydroxylation Reaction

2007 ◽  
Vol 46 (16) ◽  
pp. 6227-6229 ◽  
Author(s):  
Akihiro Takahashi ◽  
Takuya Kurahashi ◽  
Hiroshi Fujii
Keyword(s):  
Cation Radical ◽  
Activation Parameters ◽  
Radical Complex ◽  
Hydroxylation Reaction ◽  
Allylic Hydroxylation ◽  
Complex Entropy

Effect of the Axial Ligand on the Reactivity of the Oxoiron(IV) Porphyrin π-Cation Radical Complex: Higher Stabilization of the Product State Relative to the Reactant State

2012 ◽  
Vol 51 (13) ◽  
pp. 7296-7305 ◽  
Author(s):  
Akihiro Takahashi ◽  
Daisuke Yamaki ◽  
Kenichiro Ikemura ◽  
Takuya Kurahashi ◽  
Takashi Ogura ◽  
...  
Keyword(s):  
Cation Radical ◽  
Axial Ligand ◽  
Product State ◽  
Radical Complex

Preparation and characterization of an A1u (Oxo) iron(IV) porphyrin .pi.-cation-radical complex

1992 ◽  
Vol 31 (6) ◽  
pp. 1110-1112 ◽  
Author(s):  
Hiroshi Fujii ◽  
Kazuhiko Ichikawa
Keyword(s):  
Cation Radical ◽  
Radical Complex

Biomimetic Alkane Hydroxylations by an Iron(III) Porphyrin Complex with H2O2and by a High-Valent Iron(IV) Oxo Porphyrin Cation Radical Complex

1999 ◽  
Vol 38 (13) ◽  
pp. 3238-3240 ◽  
Author(s):  
Wonwoo Nam ◽  
Yeong Mee Goh ◽  
Yoon Jung Lee ◽  
Mi Hee Lim ◽  
Cheal Kim
Keyword(s):  
Cation Radical ◽  
Porphyrin Complex ◽  
Radical Complex ◽  
High Valent ◽  
Porphyrin Cation

A Manganese(V)–Oxo π-Cation Radical Complex: Influence of One-Electron Oxidation on Oxygen-Atom Transfer

2011 ◽  
Vol 133 (40) ◽  
pp. 15874-15877 ◽  
Author(s):  
Katharine A. Prokop ◽  
Heather M. Neu ◽  
Sam P. de Visser ◽  
David P. Goldberg
Keyword(s):  
Oxygen Atom ◽  
Cation Radical ◽  
Atom Transfer ◽  
Oxygen Atom Transfer ◽  
Radical Complex ◽  
Complex Influence
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