Material-scale tests involving milligrams of samples are used to optimize fire-retardant coating formulations, but actual applications of these coatings require them to be assessed with structural-scale fire tests. This significant difference in the scale of testing (milligrams to kilograms of sample) raises many questions on the relations between the inherent flammability and thermal characteristics of the coating materials and their “performance” at the structural scale. Moreover, the expected “performance” requirements and the definition of “performance” varies at different scales. In this regard, the pathway is not established when designing and formulating fire-retardant coatings for structural steel sections or members. This manuscript explores the fundamental relationships across different scales of testing with the help of a fire-protective system based on acrylic resin with a typical combination of intumescent additives, viz. ammonium polyphosphate, pentaerythritol, and expandable graphite. One of the main outcomes of this work dictates that higher heat release rate values and larger amounts of material participating in the pyrolysis process per unit time will result in a rapid rise in steel substrate temperature. This information is very useful in the design and development of generic fire-retardant coatings.
Improving the flame retardancy of waterborne polyurethanes based on the synergistic effect of P–N flame retardants and a Schiff base