Radiolysis of chloroform vapor. Effects of phase on the Arrhenius parameters of the hydrogen-atom abstraction reaction of dichloromethyl radicals with chloroform

1970 ◽  
Vol 74 (25) ◽  
pp. 4310-4313 ◽  
Author(s):  
Richard F. Firestone ◽  
Leland C. Dickey
Keyword(s):  
Hydrogen Atom ◽  
Hydrogen Atom Abstraction ◽  
Arrhenius Parameters ◽  
Abstraction Reaction

Reaction kinetics of hydrogen atom abstraction from isopentanol by the H atom and HO2˙ radical

2018 ◽  
Vol 20 (16) ◽  
pp. 10895-10905
Author(s):  
Prajakta Rajaram Parab ◽  
K. Alexander Heufer ◽  
Ravi Xavier Fernandes
Keyword(s):  
Hydrogen Atom ◽  
Transition State ◽  
Reaction Kinetics ◽  
Hydrogen Atom Abstraction ◽  
Abstraction Reaction ◽  
Kinetics Of ◽  
Ho2 Radical

The formation of the transition state for the H-abstraction reaction from isopentanol by the HO2˙ radical.

Learning about Regiochemistry from a Hydrogen-Atom Abstraction Reaction in Water

2011 ◽  
Vol 88 (10) ◽  
pp. 1437-1438 ◽  
Author(s):  
Christopher Sears-Dundes ◽  
Yoeup Huon ◽  
Richard P. Hotz ◽  
Allan R. Pinhas
Keyword(s):  
Hydrogen Atom ◽  
Hydrogen Atom Abstraction ◽  
Abstraction Reaction ◽  
Reaction In Water

Arrhenius parameters for the reaction of propyl radicals with propane

1969 ◽  
Vol 47 (18) ◽  
pp. 3305-3311 ◽  
Author(s):  
R. E. Berkley ◽  
G. N. C. Woodall ◽  
O. P. Strausz ◽  
H. E. Gunning
Keyword(s):  
Hydrogen Atom ◽  
Thermodynamic Data ◽  
Reverse Reaction ◽  
Hydrogen Atom Abstraction ◽  
Arrhenius Parameters ◽  
Complicating Factors

The reaction of n-propyl radicals from the photolysis of azo-n-propane with propane has been studied and Arrhenius parameters for hydrogen atom abstraction relative to the recombination of n-propyl radicals determined. From the Arrhenius parameters obtained and the available thermodynamic data, the Arrhenius parameters of the reverse reaction, the hydrogen atom abstraction from propane by iso-propyl radicals, have been calculated.Some complicating factors in the photolysis of azopropane are discussed.

scholarly journals Hydrogen-Atom Abstraction Reaction of CF3CH2OCF3by Hydroxyl Radical

2010 ◽  
Vol 31 (12) ◽  
pp. 3718-3722 ◽  
Author(s):  
Hari Ji Singh ◽  
Bhupesh Kumar Mishra ◽  
Pradeep Kumar Rao
Keyword(s):  
Hydrogen Atom ◽  
Hydroxyl Radical ◽  
Hydrogen Atom Abstraction ◽  
Abstraction Reaction

On the Rate of the Hydrogen Atom Abstraction Reaction in Liquid Hexane1

1966 ◽  
Vol 70 (1) ◽  
pp. 317-318 ◽  
Author(s):  
D. Perner ◽  
Robert H. Schuler
Keyword(s):  
Hydrogen Atom ◽  
Hydrogen Atom Abstraction ◽  
Abstraction Reaction

Indication of a Hydrogen-Atom Abstraction Reaction Relevant to a Mechanistic Proposal for the Oxygen-Evolving Complex of Photosystem II

2001 ◽  
Vol 40 (20) ◽  
pp. 5066-5067 ◽  
Author(s):  
Kenneth Bendix Jensen ◽  
Christine J. McKenzie ◽  
Jens Zacho Pedersen
Keyword(s):  
Hydrogen Atom ◽  
Photosystem Ii ◽  
Hydrogen Atom Abstraction ◽  
Oxygen Evolving Complex ◽  
Abstraction Reaction ◽  
Oxygen Evolving

Theoretical study on the reaction path and rate constants of the hydrogen atom abstraction reaction of CH2O with CH3/OH

2004 ◽  
Vol 307 (1) ◽  
pp. 35-43 ◽  
Author(s):  
Hui-Ying Li ◽  
Min Pu ◽  
Yong-Qiang Ji ◽  
Zhen-Feng Xu ◽  
Wen-Lin Feng
Keyword(s):  
Hydrogen Atom ◽  
Rate Constants ◽  
Theoretical Study ◽  
Reaction Path ◽  
Hydrogen Atom Abstraction ◽  
Abstraction Reaction

Transition states for the hydrogen atom abstraction reaction by ga-oxygen substituted radicals: Felkin-Anh Rule in Radical Chemistry

1993 ◽  
Vol 34 (3) ◽  
pp. 431-434 ◽  
Author(s):  
Wolfgang Damm ◽  
Joachim Dickhaut ◽  
Frank Wetterich ◽  
Bernd Giese
Keyword(s):  
Hydrogen Atom ◽  
Transition States ◽  
Hydrogen Atom Abstraction ◽  
Radical Chemistry ◽  
Abstraction Reaction
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