Kinetics of Diffusion-Controlled Reactions. An Experimental Test of the Theory as Applied to Fluorescence Quenching

1966 ◽  
Vol 70 (10) ◽  
pp. 3246-3253 ◽  
Author(s):  
William R. Ware ◽  
Joel S. Novros
Keyword(s):  
Fluorescence Quenching ◽  
Experimental Test ◽  
Diffusion Controlled ◽  
Kinetics Of

Kinetics of partly diffusion controlled reactions. I. Transient and apparent transient effect in fluorescence quenching

1978 ◽  
Vol 28 (3) ◽  
pp. 371-377 ◽  
Author(s):  
J.C. Andre ◽  
M. Niclause ◽  
W.R. Ware
Keyword(s):  
Fluorescence Quenching ◽  
Transient Effect ◽  
Diffusion Controlled ◽  
Kinetics Of

Kinetics of partly diffusion controlled reactions. X. Use of a high pressure cell in fluorescence quenching experiments

1982 ◽  
Vol 20 (3-4) ◽  
pp. 395-402 ◽  
Author(s):  
I. Kawenoki ◽  
J. Kossanyi ◽  
J. Y. Jezequel ◽  
J. C. Andre
Keyword(s):  
High Pressure ◽  
Fluorescence Quenching ◽  
High Pressure Cell ◽  
Pressure Cell ◽  
Diffusion Controlled ◽  
Kinetics Of

Kinetics of partly diffusion-controlled reactions XX: Fluorescence quenching by the nearest-neighbours model

1988 ◽  
Vol 42 (2-3) ◽  
pp. 233-239 ◽  
Author(s):  
J.C. Andre ◽  
F. Baros ◽  
A.T. Reis E Sousa
Keyword(s):  
Fluorescence Quenching ◽  
Diffusion Controlled ◽  
Nearest Neighbours ◽  
Kinetics Of

Kinetics of partly diffusion-controlled reactions. XVI. The use of liquid state physics for fluorescence quenching models

1986 ◽  
Vol 103 (2-3) ◽  
pp. 391-397 ◽  
Author(s):  
J.C. André ◽  
F. Baros ◽  
M. Bouchy ◽  
J.P. Badiali
Keyword(s):  
State Physics ◽  
Fluorescence Quenching ◽  
Liquid State ◽  
Diffusion Controlled ◽  
Kinetics Of

scholarly journals Synthesis and Polymerization Kinetics of Rigid Tricyanate Ester

Polymers ◽  
2021 ◽  
Vol 13 (11) ◽  
pp. 1686
Author(s):  
Andrey Galukhin ◽  
Roman Nosov ◽  
Ilya Nikolaev ◽  
Elena Melnikova ◽  
Daut Islamov ◽  
...  
Keyword(s):  
Kinetic Analysis ◽  
Single Step ◽  
Polymerization Kinetics ◽  
Scanning Calorimetry ◽  
Modulated Differential Scanning Calorimetry ◽  
Diffusion Controlled ◽  
Polymerization Product ◽  
The One ◽  
Kinetics Of

A new rigid tricyanate ester consisting of seven conjugated aromatic units is synthesized, and its structure is confirmed by X-ray analysis. This ester undergoes thermally stimulated polymerization in a liquid state. Conventional and temperature-modulated differential scanning calorimetry techniques are employed to study the polymerization kinetics. A transition of polymerization from a kinetic- to a diffusion-controlled regime is detected. Kinetic analysis is performed by combining isoconversional and model-based computations. It demonstrates that polymerization in the kinetically controlled regime of the present monomer can be described as a quasi-single-step, auto-catalytic, process. The diffusion contribution is parameterized by the Fournier model. Kinetic analysis is complemented by characterization of thermal properties of the corresponding polymerization product by means of thermogravimetric and thermomechanical analyses. Overall, the obtained experimental results are consistent with our hypothesis about the relation between the rigidity and functionality of the cyanate ester monomer, on the one hand, and its reactivity and glass transition temperature of the corresponding polymer, on the other hand.

Exciplex photophysics. V. The kinetics of fluorescence quenching of anthracene by N,N-dimethylaniline in cyclohexane

1976 ◽  
Vol 98 (16) ◽  
pp. 4718-4727 ◽  
Author(s):  
Man Him Hui ◽  
William R. Ware
Keyword(s):  
Fluorescence Quenching ◽  
Kinetics Of

Fluoreszenzlöschung alternierender und nicht-alternierender polycyclischer aromatischer Kohlenwasserstoffe durch Nitroverbindungen / Fluorescence Quenching of Alternant and Non-alternant Polycyclic Hydrocarbons by Nitro Compounds

1977 ◽  
Vol 32 (12) ◽  
pp. 1561-1563 ◽  
Author(s):  
M. Zander
Keyword(s):  
Electron Transfer ◽  
Fluorescence Quenching ◽  
Excitation Energy ◽  
Reduction Potential ◽  
Nitro Compounds ◽  
Polycyclic Hydrocarbons ◽  
Electron Transfer Mechanism ◽  
Diffusion Controlled ◽  
Polycyclic Aromatic ◽  
Alternant Hydrocarbons

Abstract Fluorescence Quenching of Alternant and Non-alternant Polycyclic Hydrocarbons by Nitro Compounds Fluorescence quenching of polycyclic aromatic hydro­ carbons by nitromethane or nitrobenzene in fluid solutions is due to an electron transfer mechanism. The non diffusion controlled rate constant of quenching is very much greater for alternant than for non-alternant hydrocarbons with equal singlet excitation energy. This is explained by the known more positive reduction potential of non-alternant compared to alternant hydrocarbons.

Kinetics of Fluorescence Quenching by Electron and H-Atom Transfer

1970 ◽  
Vol 8 (2) ◽  
pp. 259-271 ◽  
Author(s):  
Dieter Rehm ◽  
Albert Weller
Keyword(s):  
Fluorescence Quenching ◽  
Atom Transfer ◽  
Kinetics Of
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