Gas-phase reactions of carbanions with triplet and singlet molecular oxygen

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C. H. DePuy
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E. A. Ogryzlo

Rate constants have been determined for several reactions of O2(1Δg) in the gas phase, at temperatures between 300 and 550 °K. The following values were obtained when the data was fitted to the Arrhenius equation:[Formula: see text]A charge-transfer interaction in the transition-state is invoked to account for the data available for such reactions.


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