The Determination of Silicon-Carbon and Silicon-Hydrogen Bond Dissociation Energies by Electron Impact

1962 ◽  
Vol 84 (23) ◽  
pp. 4441-4445 ◽  
Author(s):  
W. C. Steele ◽  
L. D. Nichols ◽  
F. G. A. Stone

1988 ◽  
Vol 110 (12) ◽  
pp. 4090-4092 ◽  
Author(s):  
P. Mulder ◽  
O. W. Saastad ◽  
D. Griller


The paper describes a pyrolytic method of investigating the kinetics of gaseous reactions in which toluene is used as a carrier gas. It is shown that the method is particularly suitable for the determination of bond dissociation energies. The scope of the method is illustrated by various examples. A list of bond dissociation energies obtained is given. The manner in which the experimental results obtained can be cross-checked, is indicated and illustrated by examples. The effects of various constitutional factors on the bond dissociation energies are discussed.





Sign in / Sign up

Export Citation Format

Share Document