Operational criteria for concerted bond breaking in gas-phase molecular elimination reactions

1969 ◽  
Vol 91 (13) ◽  
pp. 3688-3689 ◽  
Author(s):  
Simon Harvey Bauer
Keyword(s):  
Gas Phase ◽  
Bond Breaking ◽  
Elimination Reactions ◽  
Operational Criteria

Molecular rearrangements in homogeneous gas-phase elimination reactions. Pyrolysis kinetics of alkyl methanesulphonates

1993 ◽  
Vol 6 (2) ◽  
pp. 85-94 ◽  
Author(s):  
Gabriel Chuchani ◽  
Ignacio Martin ◽  
Rosa M. Dominguez ◽  
Alexandra Rotinov ◽  
Sara Pekerarm ◽  
...  
Keyword(s):  
Gas Phase ◽  
Pyrolysis Kinetics ◽  
Molecular Rearrangements ◽  
Elimination Reactions ◽  
Kinetics Of ◽  
Phase Elimination

The Gas Phase Radiolysis of Ethyl Chloride

1963 ◽  
Vol 2 (2) ◽  
Author(s):  
Ralph N. Schindler
Keyword(s):  
Gas Phase ◽  
Vinyl Chloride ◽  
Rate Constant ◽  
Ethyl Chloride ◽  
Molecular Processes ◽  
Primary Reactions ◽  
Elimination Reactions ◽  
Chemical Event

SummaryEthyl chloride has been bombarded with 2.8 MeV electrons in the gas phase. The main radicals produced in the primary chemical event are monochloroethyl and ethyl with the corresponding fragments. Their major reactions during radiolysis include:CI· + CC2CC2CThe rate constant <xxx>has been determined to be 1.92 ̅± 0.2.Disproportionation reactions of chloroethyl radicals were found negligible. In addition, ethylene, acetylene, vinyl chloride, and hydrogen, in part, are formed by molecular elimination reactions. The molecular processes account for roughly half of all primary reactions observed.

Gas-phase kinetics of elimination reactions of pentane-2,4-dione derivatives

1995 ◽  
Vol 27 (5) ◽  
pp. 517-523 ◽  
Author(s):  
Nouria A. Al-Awadi ◽  
Mohamed H. El-Nagdi ◽  
Tommy Mathew
Keyword(s):  
Gas Phase ◽  
Gas Phase Kinetics ◽  
Elimination Reactions ◽  
Kinetics Of

Kinetics of the homogeneous, unimolecular elimination reactions of ethyl oxamate, ethylN,N-dimethyloxamate and ethyl oxanilate in the gas phase

2005 ◽  
Vol 18 (6) ◽  
pp. 539-545 ◽  
Author(s):  
Esker V. Chacin ◽  
María Tosta ◽  
Armando Herize ◽  
Rosa M. Domínguez ◽  
Ysaias Alvarado ◽  
...  
Keyword(s):  
Gas Phase ◽  
Elimination Reactions ◽  
Kinetics Of
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