Kinetics of Crystalline Nucleus Formation in Supercooled Liquid Tin1,2

1952 ◽  
Vol 74 (9) ◽  
pp. 2323-2332 ◽  
Author(s):  
Guy M. Pound ◽  
Victor K. La Mer
2013 ◽  
Vol 113 (10) ◽  
pp. 104505 ◽  
Author(s):  
J. Ma ◽  
L. S. Huo ◽  
D. Q. Zhao ◽  
W. H. Wang

Metals ◽  
2020 ◽  
Vol 10 (3) ◽  
pp. 417 ◽  
Author(s):  
Andrei Makarov ◽  
Gennadii Afonin ◽  
Yurii Mitrofanov ◽  
Nikolai Kobelev ◽  
Vitaly Khonik

We show that the kinetics of endothermal and exothermal effects occurring in the supercooled liquid state and upon crystallization of metallic glasses can be well reproduced using temperature dependences of their shear moduli. It is argued that the interrelation between the heat effects and shear modulus relaxation reflects thermally activated evolution of interstitial-type defect system inherited from the maternal melt.


2009 ◽  
Vol 283-286 ◽  
pp. 209-213 ◽  
Author(s):  
Dong Ya Huang ◽  
Xiang Jin Zhao ◽  
Tao Zhang ◽  
Vincent Ji

The isothermal oxidation behavior of Zr58Nb3Cu16Ni13Al10 bulk metallic glass (BMG) under dry air in the glassy state and the supercooled liquid state (SLS) was studied by the thermogravimetric method. The oxidation rate and thickness growth speed in the SLS were both hugely higher than in the glassy state. The oxidation kinetics of BMG in both states for 1.5 hours was different, the parabolic law was followed in the glassy state at 300°C and 350°C, contrarily the linear law was followed in SLS at 400 °C. After the oxidation for 126 hours in SLS, the oxidation kinetics possessed two stages, the linear stage and the parabolic stage. The diffusion of the Cu2+ ion and CuZr intermetallic alloys were detected by GIXRD.


Author(s):  
Abash Sharma ◽  
Ebrahim Asadi ◽  
Mohamed Laradji

Abstract The present work focuses on the development of a relatively simple phase field crystal model for materials with nanoscale porous inclusions. We found that the pore's main effect is to act as a nucleation agent, promoting crystallization of material at the pore’s interface, followed by micro-structural evolution of the solid in the supercooled liquid. Details of the crystal around the pore are investigated in terms of the pore radius and density of material outside the pore. Moreover, details of the pore-material interface is investigated through the interfacial tension and pressure. Finally, the model is extended to investigate the effect of multiple pores on the kinetics of crystallization.


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