Sustainable Management of Peanut Shell through Biochar and Its Application as Soil Ameliorant

The current research encompasses utilization of peanut shells (PS) as feedstock for pyrolysis carried out at various temperatures (250, 400, and 550 °C) for deriving biochar, namely PS-BC250, PS-BC400, and PS-BC550. After analyzing the biochar types physicochemically, it was applied as a soil ameliorant for the growth of cucumber. The results showed that in prepared biochar type, bulk density, volatile contents, hydrogen, oxygen, and nitrogen content decreased, whereas pH, electrical conductivity, ash content, fixed carbon content, and surface area increased with the increasing temperature. Scanning electron microscopy (SEM) and Fourier Transform Infrared Spectroscopy (FTIR) presented high porosity, re-orientation of vessels, and a greater number of aromatic compounds, respectively, for PS-BC prepared at 550 °C. On applying PS-BC250, PS-BC400, and PS-BC550 as amendments in potted soil at 2, 4, and 6% (w/w), it improved soil quality (viz pH, ECe, BD, and soil water holding capacity) and increased the yield of cucumber. Because of improved soil properties and crop yield, PS-BC550 at the rate of 4% (w/w) demonstrated a great potential for agricultural application while provisioning dual circular economic indicators in the form of diverting PS waste to an effective alternative of chemical fertilizer having intensive carbon footprints in cucumber production.

A Rapid Method for the Determination of SBS Content Based on the Principle of Orthogonal Testing

The performance of Styrene-butadiene-styrene (SBS) modified asphalt is closely related to the content of SBS modifier. In the production process of modified asphalt, a certain amount of additive such as sulfur and rubber oil may be added to reduce the segregation and promote the swelling of the polymer, but the effect of these additives on determining SBS content in asphalt is not yet clear. This paper presents the calibration curves of SBS content based on rutting factor and creep slope and points out its defects according to the temperature scanning test and the bending beam rheometer test. Subsequently, using Fourier transform infrared spectroscopy (FTIR) for rapid determination of polymer content in SBS modified asphalt based on orthogonal test and then the effects of additives such as asphalt type, SBS content, rubber oil and sulfur on the accuracy of polymer content determination by FTIR were investigated. Moreover, in the orthogonal tests of adding sulfur and rubber oil, the multivariate analysis of variance (MANOVA) was firstly used to analyze the additives influence on the test accuracy of FITR. Results indicated that the influencing degree of different additives is different. The influence of sulfur on the determination accuracy is greater than that of rubber oil. Therefore, the rapid determination method needs further improvement.

Effects of Drying Temperature and Molar Concentration on Structural, Optical, and Electrical Properties of β-Ga2O3 Thin Films Fabricated by Sol–Gel Method

In this study, β-Ga2O3 films were fabricated on a quartz substrate by the sol–gel method using different drying temperatures and solutions of different molar concentrations, and their structural, optical, and electrical properties were evaluated. The as-fabricated films exhibited a monoclinic β-Ga2O3 crystal structure, whose crystallinity and crystallite size increased with increasing molar concentration of the solutions used and increasing drying temperature. Scanning electron microscopy of the as-prepared samples revealed dense surface morphologies and that the thickness of the films also depended on the deposition conditions. The average transmittance of all the samples was above 8% in visible light, and the calculated optical bandgap energy was 4.9 eV. The resistivity measured using a 4-point probe system was 3.7 × 103 Ω cm.

Self-selective formation of ordered 1D and 2D GaBi structures on wurtzite GaAs nanowire surfaces

Scaling down material synthesis to crystalline structures only few atoms in size and precisely positioned in device configurations remains highly challenging, but is crucial for new applications e.g., in quantum computing. We propose to use the sidewall facets of larger III–V semiconductor nanowires (NWs), with controllable axial stacking of different crystal phases, as templates for site-selective growth of ordered few atoms 1D and 2D structures. We demonstrate this concept of self-selective growth by Bi deposition and incorporation into the surfaces of GaAs NWs to form GaBi structures. Using low temperature scanning tunneling microscopy (STM), we observe the crystal structure dependent self-selective growth process, where ordered 1D GaBi atomic chains and 2D islands are alloyed into surfaces of the wurtzite (Wz) $$\{11{\bar{2}}0\}$$ { 11 2 ¯ 0 } crystal facets. The formation and lateral extension of these surface structures are controlled by the crystal structure and surface morphology uniquely found in NWs. This allows versatile high precision design of structures with predicted novel topological nature, by using the ability of NW heterostructure variations over orders of magnitude in dimensions with atomic-scale precision as well as controllably positioning in larger device structures.

Size, shape, and direction matters: Matching secondary genital structures in male and female mites using multiple microscopy techniques and 3D modeling

Studies of female genital structures have generally lagged behind comparable studies of male genitalia, in part because of an assumption of a lower level of variability, but also because internal genitalia are much more difficult to study. Using multiple microscopy techniques, including video stereomicroscopy, fluorescence microscopy, low-temperature scanning electron microscopy (LT-SEM), and confocal laser scanning microscopy (CLSM) we examined whether the complex sperm transfer structures in males of Megalolaelaps colossus (Acari: Mesostigmata) are matched by similarly complex internal structures in the female. While both LT-SEM and CLSM are well suited for obtaining high-quality surface images, CLSM also proved to be a valuable technique for observing internal anatomical structures. The long and coiled sperm transfer organ on the chelicera of the males (spermatodactyl) largely matches an equally complex, but internal, spiral structure in the females in shape, size, and direction. This result strongly suggests some form of genital coevolution. A hypothesis of sexual conflict appears to provide the best fit for all available data (morphology and life history).

Strain-Relief Patterns and Kagome Lattice in Self-Assembled C60 Thin Films Grown on Cd(0001)

We report an ultra-high vacuum low-temperature scanning tunneling microscopy (STM) study of the C60 monolayer grown on Cd(0001). Individual C60 molecules adsorbed on Cd(0001) may exhibit a bright or dim contrast in STM images. When deposited at low temperatures close to 100 K, C60 thin films present a curved structure to release strain due to dominant molecule–substrate interactions. Moreover, edge dislocation appears when two different wavy structures encounter each other, which has seldomly been observed in molecular self-assembly. When growth temperature rose, we found two forms of symmetric kagome lattice superstructures, 2 × 2 and 4 × 4, at room temperature (RT) and 310 K, respectively. The results provide new insight into the growth behavior of C60 films.