The Alkaline Hydrolysis of Ethyl Acetate in Acetone—Water Mixtures

1950 ◽  
Vol 72 (2) ◽  
pp. 674-677 ◽  
Author(s):  
Edward S. Amis ◽  
Saul Siegel
Keyword(s):  
Ethyl Acetate ◽  
Alkaline Hydrolysis ◽  
Acetone Water ◽  
Hydrolysis Of

Effect of Pressure on the Alkaline Hydrolysis of Ethyl Acetate in Acetone–Water Solutions. Parameters of Activation at Constant Volume

1975 ◽  
Vol 53 (22) ◽  
pp. 3414-3418 ◽  
Author(s):  
M. L. Tonnet ◽  
E. Whalley
Keyword(s):  
Ethyl Acetate ◽  
Solvent Effect ◽  
Internal Energy ◽  
Alkaline Hydrolysis ◽  
Constant Pressure ◽  
Constant Volume ◽  
Acetone Water ◽  
Entropy Of Activation ◽  
Enthalpy And Entropy ◽  
Hydrolysis Of

The effect of pressures up to 3 kbar on the rate of the base-catalyzed hydrolysis of ethyl acetate in acetone–water mixtures has been measured. From these measurements and the enthalpy and entropy of activation at constant pressure measured by others, the internal energy and entropy of activation at constant volume have been obtained as a function of solvent composition. The constant-volume parameters of activation vary with composition in a simpler way than the constant-pressure parameters. It seems likely that theoretical discussions of the solvent effect are easier if they are based on the constant-volume parameters. At low acetone concentrations, the addition of acetone reduces the rate constant at low pressure, but increases it at 3 kbar.

The Alkaline Hydrolysis of Ethyl Acetate from the Standpoint of Ion-Dipole Theory

1949 ◽  
Vol 71 (6) ◽  
pp. 2112-2116 ◽  
Author(s):  
James Edward. Potts ◽  
Edward S. Amis
Keyword(s):  
Ethyl Acetate ◽  
Alkaline Hydrolysis ◽  
Hydrolysis Of

scholarly journals The Influence of the Solvent on Reaction Velocity. XI. Alkaline Hydrolysis of Ethyl Bromide in Acetone-Water Mixtures.

1955 ◽  
Vol 9 ◽  
pp. 825-831 ◽  
Author(s):  
Eero Tommila ◽  
P. J. Antikainen ◽  
Jannik Bjerrum ◽  
Niels Clauson-Kaas
Keyword(s):  
Alkaline Hydrolysis ◽  
Ethyl Bromide ◽  
Reaction Velocity ◽  
Acetone Water ◽  
Hydrolysis Of

scholarly journals Heterogeneity of the reaction system of alkaline hydrolysis of ethyl acetate in a batch stirred tank.

1981 ◽  
Vol 14 (6) ◽  
pp. 499-500
Author(s):  
YASUHIRO MURAKAMI ◽  
MASAHARU TAKAO ◽  
HIDEAKI INOUE
Keyword(s):  
Ethyl Acetate ◽  
Alkaline Hydrolysis ◽  
Reaction System ◽  
Stirred Tank ◽  
Hydrolysis Of

Mass transfer enhancement by the alkaline hydrolysis of ethyl acetate in a single droplet system

2011 ◽  
Vol 17 (4) ◽  
pp. 782-787 ◽  
Author(s):  
Sang Jun Jeon ◽  
Alexander Pawelski ◽  
Matthias Kraume ◽  
Won Hi Hong
Keyword(s):  
Mass Transfer ◽  
Ethyl Acetate ◽  
Alkaline Hydrolysis ◽  
Single Droplet ◽  
Transfer Enhancement ◽  
Mass Transfer Enhancement ◽  
Hydrolysis Of

Transition state enthalpies of transfer in aqueous dimethyl sulfoxide solutions. Alkaline hydrolysis of ethyl acetate

1974 ◽  
Vol 78 (15) ◽  
pp. 1509-1511 ◽  
Author(s):  
Richard Fuchs ◽  
C. Patrick Hagan ◽  
Randolph F. Rodewald
Keyword(s):  
Transition State ◽  
Ethyl Acetate ◽  
Dimethyl Sulfoxide ◽  
Alkaline Hydrolysis ◽  
Enthalpies Of Transfer ◽  
Hydrolysis Of

Alkaline hydrolysis of glycol esters - A newly suggested criterion in the assessment of anchimeric assistance

1974 ◽  
Vol 27 (11) ◽  
pp. 2325 ◽  
Author(s):  
M Balakrishnan ◽  
Rao G Venkoba ◽  
N Venkatasubramanian
Keyword(s):  
Transition State ◽  
Solvent Effects ◽  
Alkaline Hydrolysis ◽  
Triethylene Glycol ◽  
Binary Solvent ◽  
Solvent Mixtures ◽  
Acetone Water ◽  
Anchimeric Assistance ◽  
Hydrolysis Of ◽  
Suggested Criterion

Solvent effects vis a vis structural effects on the alkaline hydrolysis of various di-and mono-benzoates of glycols have been studied in binary solvent mixtures of dimethyl sulphoxide-water, ethanol-water and acetone-water. It is observed that the higher the stabilization of the transition state by the neighbouring group, the greater is the susceptibility of the reaction to dipolar aprotic solvent acceleration[i.e. k(Me2SO)/k(EtOH) value]. The possibility of employing such solvent effects to evaluate the extent of anchimeric assistance in ester hydrolysis where the neighbouring group can stabilize the transition state is examined. The studies have been extended to triethylene glycol derivatives and it is suggested that dipolar aprotic-protic solvent effects could be used as a kinetic probe for the conformation of the molecule.

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