The Alkaline Hydrolysis of Ethyl Acetate from the Standpoint of Ion-Dipole Theory

1949 ◽  
Vol 71 (6) ◽  
pp. 2112-2116 ◽  
Author(s):  
James Edward. Potts ◽  
Edward S. Amis

1981 ◽  
Vol 14 (6) ◽  
pp. 499-500
Author(s):  
YASUHIRO MURAKAMI ◽  
MASAHARU TAKAO ◽  
HIDEAKI INOUE


2011 ◽  
Vol 17 (4) ◽  
pp. 782-787 ◽  
Author(s):  
Sang Jun Jeon ◽  
Alexander Pawelski ◽  
Matthias Kraume ◽  
Won Hi Hong


1950 ◽  
Vol 72 (2) ◽  
pp. 674-677 ◽  
Author(s):  
Edward S. Amis ◽  
Saul Siegel




1975 ◽  
Vol 53 (22) ◽  
pp. 3414-3418 ◽  
Author(s):  
M. L. Tonnet ◽  
E. Whalley

The effect of pressures up to 3 kbar on the rate of the base-catalyzed hydrolysis of ethyl acetate in acetone–water mixtures has been measured. From these measurements and the enthalpy and entropy of activation at constant pressure measured by others, the internal energy and entropy of activation at constant volume have been obtained as a function of solvent composition. The constant-volume parameters of activation vary with composition in a simpler way than the constant-pressure parameters. It seems likely that theoretical discussions of the solvent effect are easier if they are based on the constant-volume parameters. At low acetone concentrations, the addition of acetone reduces the rate constant at low pressure, but increases it at 3 kbar.



1966 ◽  
Vol 39 (9) ◽  
pp. 1837-1842 ◽  
Author(s):  
Hiroo Tsujikawa ◽  
Hakuai Inoue


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