scholarly journals X-ray Spectroscopic Observation of an Interstitial Carbide in NifEN-Bound FeMoco Precursor

2013 ◽  
Vol 135 (2) ◽  
pp. 610-612 ◽  
Author(s):  
Kyle M. Lancaster ◽  
Yilin Hu ◽  
Uwe Bergmann ◽  
Markus W. Ribbe ◽  
Serena DeBeer



2020 ◽  
Vol 635 ◽  
pp. L7 ◽  
Author(s):  
S. Belladitta ◽  
A. Moretti ◽  
A. Caccianiga ◽  
C. Spingola ◽  
P. Severgnini ◽  
...  

We present the discovery of PSO J030947.49+271757.31, the radio brightest (23.7 mJy at 1.4 GHz) active galactic nucleus (AGN) at z >  6.0. It was selected by cross-matching the NRAO VLA Sky Survey and the Panoramic Survey Telescope and Rapid Response System PS1 databases and its high-z nature was confirmed by a dedicated spectroscopic observation at the Large Binocular Telescope. A pointed Neil Gehrels Swift Observatory XRT observation allowed us to measure a flux of ∼3.4 × 10−14 erg s−1 cm−2 in the [0.5–10] keV energy band, which also makes this object the X-ray brightest AGN ever observed at z >  6.0. Its flat radio spectrum (ανr <  0.5), very high radio loudness (R >  103), and strong X-ray emission, compared to the optical, support the hypothesis of the blazar nature of this source. Assuming that this is the only blazar at this redshift in the surveyed area of sky, we derive a space density of blazars at z ∼ 6 and with M1450 Å < −25.1 of 5.5+11.2−4.6 × 10−3 Gpc−3. From this number, and assuming a reasonable value of the bulk velocity of the jet (Γ = 10), we can also infer a space density of the entire radio-loud AGN population at z ∼ 6 with the same optical/UV absolute magnitude of 1.10+2.53−0.91 Gpc−3. Larger samples of blazars will be necessary to better constrain these estimates.



1997 ◽  
pp. 1265-1266 ◽  
Author(s):  
J. He ◽  
D. D. Klug ◽  
J. S. Tse ◽  
K. F. Preston


2020 ◽  
Vol 641 ◽  
pp. A62
Author(s):  
A. Paggi ◽  
M. Bonato ◽  
C. M. Raiteri ◽  
M. Villata ◽  
G. De Zotti ◽  
...  

Context. Blazars are the rarest and most powerful active galactic nuclei. They play a crucial and expanding role in the multifrequency and multimessenger astrophysics of today. Dominating the high-energy extragalactic sky, they have been recently associated with high-energy astrophysical neutrinos and they may be among the accelerators of the ultra-high energy cosmic rays. Current blazar catalogs, however, are incomplete and they are depleted, in particular, at low Galactic latitudes. Aims. Our study is aimed at augmenting the current blazar census, starting from a sample of ALMA calibrators that provides more homogeneous sky coverage, especially at low Galactic latitudes, to build a catalog of blazar candidates that can provide candidate counterparts to unassociated γ-ray sources and sources of high-energy neutrino emission or ultra-high energy cosmic rays. Methods. Based on the ALMA Calibrator Catalog, we compiled a selection of 1580 ALMA Blazar Candidates (ABCs) for which we collected multiwavelength information, including Gaia photometric, parallax, and proper motion data, as well as SDSS and LAMOST photometric and spectral data, WISE photometric data, X-ray (Swift-XRT, Chandra-ACIS and XMM-Newton-EPIC) count-rates and spectra, and Fermi-LAT fluxes and spectral slopes. We also compared our ALMA Blazar Candidates with existing blazar catalogs, such as 4FGL, 3HSP, WIBRaLS2, and the KDEBLLACS. Results. The ABC catalog fills in the gaps with regard to low Galactic latitude sources in current blazar catalogs. By cross-matching this catalog with Gaia DR2, SDSS DR12, LAMOST DR5, AllWISE, and 4FGL catalogs, we obtained 805, 295, 31, 1311, and 259 matches, respectively. ALMA Blazar Candidates are significantly dimmer than known blazars in the Gaia g band, while the difference in the Gaia b − r color between the two populations is less pronounced. Also, ABC sources appear bluer in SDSS than known blazars, although with low statistical significance. Most ABCs classified as QSO and BL Lac fall into the SDSS color regions of low redshift quasars, with some QSOs entering the regions of higher redshift quasars. We collected 110 optical spectra in SDSS DR12 and LAMOST DR5, which mostly classify the corresponding sources as QSO (98), while 12 sources turned out to be galactic objects. Regarding the WISE colors, we found that ABC sources are significantly bluer than known blazars in the w2 − w3 and w3 − w4 colors. In X-ray, we detected 173 ABCs and we were able to extract X-ray spectra for 92 of them. Our sources are, on average, similar in the X-ray band to known blazars in terms of count rates and spectral slopes, implying that our sample covers the same region of the blazar parameter space in this band. A comparison of γ-ray properties shows that the ABCs are, on average, dimmer and that their γ-ray spectra are softer than known blazars, indicating a significant contribution on the part of FSRQ sources. Making use of WISE colors, we classified 715 ABCs as candidate γ-ray blazar of different classes. Conclusions. We built a new catalog of 1580 candidate blazars with a rich multiwavelength data-set, filling in the gaps for low Galactic latitude sources in current blazar catalogs. This will be particularly important for the identification of the source population of high-energy neutrinos or ultra-high energy cosmic rays, or to verify the Gaia optical reference frame. In addition, ALMA Blazar Candidates can be investigated both through optical spectroscopic observation campaigns or through repeated photometric observations for variability studies. In this context, the data collected by the upcoming LSST surveys will provide a key tool for investigating the possible blazar nature of these sources.



2007 ◽  
Vol 330-332 ◽  
pp. 1203-1206 ◽  
Author(s):  
Junji Ikeda ◽  
Giuseppe Pezzotti ◽  
Mikio Iwamoto ◽  
Masaru Ueno

The kinetics of tetragonal-to-monoclinic phase transformation (t→m transformation) in the earlier generation zirconia femoral heads was evaluated by X-ray diffractometry, laser microscopy and Raman microprobe spectroscopy. From previous results of hip-simulator study, it was confirmed that phase transformation on the surface of zirconia femoral heads had little influence on wear rate of UHMWPE sockets, and in some zirconia femoral heads, only a slight increase in monoclinic fraction was observed during hip-simulator test. In this study, we suggest that the models of phase transformation progress during tests in hip-simulator and aging tests are different based on both laser microscopic and Raman/fluorescence spectroscopic observation. Besides this finding, this study shows that Raman spectroscopy is a useful technique for the evaluation of the kinetics of phase transformation in femoral heads after both in vitro and in vivo environmental exposure.





2005 ◽  
Vol 23 (3) ◽  
pp. 497-502 ◽  
Author(s):  
Md. Nizam Uddin ◽  
Iwao Shimoyama ◽  
Yuji Baba ◽  
Tetsuhiro Sekiguchi ◽  
Masamitsu Nagano


1998 ◽  
Vol 51 (6) ◽  
pp. 461 ◽  
Author(s):  
David A. Buckingham ◽  
David A. Buckingham ◽  
Charles R. Clark ◽  
Charles R. Clark ◽  
Andrew J. Rogers ◽  
...  

The reaction of [Co(cyclen)(OH2)OH]2+ (cyclen = 1,4,7,10-tetraazacyclododecane) with (S)-alanine at pH 7·2 gives a mixture of three [Co(cyclen)((S)-AlaO)]2+ isomers (1)–(3). These have been isolated by using both cation ion-exchange chromatography (Dowex 50 W×2, HCl eluent) and reversed phase ion-pair chromatography (C18, p-toluenephosphate in MeOH/H2O eluent). By using a combination of 1H n.m.r. techniques (n.O.e. and COSY) for solutions in (CD3)2SO the syn(N),anti(O) (1), syn(O), anti(N) (2) and syn(N), syn(O) (3) configurations have been assigned to these isomers. These have been confirmed by single-crystal X-ray analysis: [Co(cyclen)((S)-AlaO)] I2.H2O, isomer (1), P43212, a = b = 8·55150(10), c 51·8693(11) Å, Z 8, R 0·0343; [Co(cyclen)((S)-AlaO)] (ClO4)2.H2O, isomer (2), P212121, a 8·499(3), b 14·538(5), c 16·592(4) Å, Z 4, R 0·0388; [Co(cyclen)((S/R)-AlaO)] ZnBr4, a 1 : 1 mixture containing both (S)-alanine (isomer (3)) and (R)-alanine, P21/c, a 7·618(2), b 13·806(4), c 19·094(7) Å, Z 4, R 0·0726. In alkaline solution (0·1–1·0 M NaOH, 25·0°C, I = 1·0 M (NaClO4)), equilibration between (1), (2) and (3) is faster than hydrolysis to give cis-[Co(cyclen)(OH)2]++(S)-AlaO-. Time zero spectroscopic observation (300 nm) allowed the equilibrium constant, K, for the reaction [Co(cyclen)((S)-AlaO)]2+ + OH- ↔ [Co(cyclen – H)((S)-AlaO)]+ +H2O to be determined as 1·05 M-1 at 25·0°C and I = 1·0 M. The hydrolysis reaction follows the rate law kobs = kKK1K2[OH-]2/(1+K[OH-]+KK1K2[OH-]2) with k = 1·0 s-1 corresponding to rate-determining loss of (S)-AlaO- from the ring-opened complex, [Co(cyclen – H)((S)-AlaO)OH].



2017 ◽  
Vol 19 (22) ◽  
pp. 14224-14229 ◽  
Author(s):  
Ying-Rui Lu ◽  
Tzung-Zing Wu ◽  
Han-Wei Chang ◽  
Jeng-Lung Chen ◽  
Chi-Liang Chen ◽  
...  

In situ/operando X-ray spectroscopic observation of color switchable smart film under gasochromic coloration.



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