Reversible Self-Assembly of Degradable Polymersomes with Upper Critical Solution Temperature in Water

2017 ◽  
Vol 139 (32) ◽  
pp. 11064-11072 ◽  
Author(s):  
Thomas Wolf ◽  
Timo Rheinberger ◽  
Johanna Simon ◽  
Frederik R. Wurm
Keyword(s):  
Self Assembly ◽  
Solution Temperature ◽  
Critical Solution Temperature ◽  
Upper Critical Solution Temperature

scholarly journals Effects of the Hydrophilic–Lipophilic Balance of Alternating Peptides on Self-Assembly and Thermo-Responsive Behaviors

2019 ◽  
Vol 20 (18) ◽  
pp. 4604 ◽  
Author(s):  
Ihsan ◽  
Nargis ◽  
Koyama
Keyword(s):  
Aqueous Solutions ◽  
Self Assembly ◽  
Polymer Chains ◽  
Systematic Evaluation ◽  
Solution Temperature ◽  
Critical Solution Temperature ◽  
Hydrophilic Lipophilic Balance ◽  
Upper Critical Solution Temperature ◽  
Cloud Points ◽  
Micellization Behavior

A series of N-substituted poly(Gly–alter–Val) peptides were successfully synthesized for the systematic evaluation of the micellization behavior of alternating peptides. Three-component polymerization employing an aldehyde, a primary ammonium chloride, and potassium isocyanoacetate afforded four alternating peptides in excellent yields. We investigated the dependence of the hydrophilic–lipophilic balance of alternating peptides on the micellization behavior. All the aqueous solutions of alternating peptides exhibited upper critical solution temperature (UCST) behaviors, strongly indicating that the alternating binary pattern would mainly contribute to the UCST behaviors. The cloud points of alternating peptides shifted to higher temperatures as the side chains became more hydrophilic, which is opposite to the trend of typical surfactants. Such unusual micellization behaviors appeared to be dependent on the quasi-stable structure of single polymer chains formed in water.

Self-Assembly of Poly(2-alkyl-2-oxazoline)s by Crystallization in Ethanol-Water Mixtures Below the Upper Critical Solution Temperature

2011 ◽  
Vol 32 (21) ◽  
pp. 1753-1758 ◽  
Author(s):  
Christina Diehl ◽  
Ina Dambowsky ◽  
Richard Hoogenboom ◽  
Helmut Schlaad
Keyword(s):  
Self Assembly ◽  
Solution Temperature ◽  
Critical Solution Temperature ◽  
Upper Critical Solution Temperature

Selective Hydrogen Bonding Controls Temperature Response of Layer-by-Layer Upper Critical Solution Temperature Micellar Assemblies

Soft Matter ◽  
2021 ◽  
Author(s):  
Aliaksei Aliakseyeu ◽  
Victoria Albright ◽  
Danielle Yarbrough ◽  
Samantha Hernandez ◽  
Qing Zhou ◽  
...  
Keyword(s):  
Hydrogen Bonding ◽  
Methacrylic Acid ◽  
Temperature Response ◽  
Solution Temperature ◽  
Layer By Layer ◽  
Critical Solution Temperature ◽  
Hydrogen Bonding Interactions ◽  
Upper Critical Solution Temperature ◽  
Lbl Films

This work establishes a correlation between the selectivity of hydrogen-bonding interactions and the functionality of micelle-containing layer-by-layer (LbL) assemblies. Specifically, we explore LbL films formed by assembly of poly(methacrylic acid)...

Smart Self-Cleaning Membrane via the Blending of an Upper Critical Solution Temperature Diblock Copolymer with PVDF

2021 ◽  
Author(s):  
Xinying Jia ◽  
Hailan Ji ◽  
Ganwei Zhang ◽  
Jiale Xing ◽  
Shusu Shen ◽  
...  
Keyword(s):  
Diblock Copolymer ◽  
Solution Temperature ◽  
Critical Solution Temperature ◽  
Upper Critical Solution Temperature ◽  
Self Cleaning

Effect of Temperature on Salt–Salt Aqueous Biphasic Systems: Manifestations of Upper Critical Solution Temperature

2014 ◽  
Vol 44 (3-4) ◽  
pp. 454-468 ◽  
Author(s):  
Meghna Dilip ◽  
Nicholas J. Bridges ◽  
Héctor Rodríguez ◽  
Jorge F. B. Pereira ◽  
Robin D. Rogers
Keyword(s):  
Effect Of Temperature ◽  
Solution Temperature ◽  
Critical Solution Temperature ◽  
Aqueous Biphasic Systems ◽  
Upper Critical Solution Temperature ◽  
Aqueous Biphasic ◽  
Biphasic Systems
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