Rare Earth pcu Metal–Organic Framework Platform Based on RE4(μ3-OH)4(COO)62+ Clusters: Rational Design, Directed Synthesis, and Deliberate Tuning of Excitation Wavelengths

2017 ◽  
Vol 139 (27) ◽  
pp. 9333-9340 ◽  
Author(s):  
Tian-Yi Luo ◽  
Chong Liu ◽  
Svetlana V. Eliseeva ◽  
Patrick F. Muldoon ◽  
Stéphane Petoud ◽  
...  
Keyword(s):  
Rare Earth ◽  
Rational Design ◽  
Metal Organic Framework ◽  
Directed Synthesis ◽  
Metal Organic ◽  
Organic Framework

Rational fabrication of two-photon responsive metal-organic framework for enhanced photodynamic therapy

2021 ◽  
Author(s):  
Xin Yao ◽  
Xinxin Pei ◽  
Bo Li ◽  
Mengqi Lv ◽  
Wen Zhang ◽  
...  
Keyword(s):  
Photodynamic Therapy ◽  
Side Effects ◽  
Rational Design ◽  
Metal Organic Framework ◽  
Cancer Treatments ◽  
Two Photon ◽  
Metal Organic ◽  
Organic Framework

Rational design of specific platform which can address the unavoidable side effects of traditional cancer treatments is of great interest. In this sense, herein, an intelligent nanoplatform (ZnL1@MOF-199@FA) with efficient...

Metal–organic framework-derived hierarchical MoS2/CoS2 nanotube arrays as pH-universal electrocatalysts for efficient hydrogen evolution

2019 ◽  
Vol 7 (21) ◽  
pp. 13339-13346 ◽  
Author(s):  
Baoshan Tang ◽  
Zhi Gen Yu ◽  
Yaoxin Zhang ◽  
Chunhua Tang ◽  
Hwee Leng Seng ◽  
...  
Keyword(s):  
Hydrogen Evolution ◽  
Rational Design ◽  
Metal Organic Framework ◽  
Nanotube Arrays ◽  
Metal Organic ◽  
Organic Framework

The rational design of novel hierarchical MoS2/CoS2 heterogeneous nanotube arrays as self-supported and pH-universal electrocatalysts for efficient HER.

Solvent exchange in a metal–organic framework single crystal monitored by dynamicin situX-ray diffraction

2017 ◽  
Vol 73 (4) ◽  
pp. 669-674 ◽  
Author(s):  
Jordan M. Cox ◽  
Ian M. Walton ◽  
Gage Bateman ◽  
Cassidy A. Benson ◽  
Travis Mitchell ◽  
...  
Keyword(s):  
Rational Design ◽  
Metal Organic Framework ◽  
X Ray Diffraction ◽  
Guest Molecules ◽  
Time Resolved ◽  
Ethanol Solvate ◽  
Significant Step ◽  
Metal Organic ◽  
Flexible Metal ◽  
Organic Framework

Understanding the processes by which porous solid-state materials adsorb and release guest molecules would represent a significant step towards developing rational design principles for functional porous materials. To elucidate the process of liquid exchange in these materials, dynamicin situX-ray diffraction techniques have been developed which utilize liquid-phase chemical stimuli. Using these time-resolved diffraction techniques, the ethanol solvation process in a flexible metal–organic framework [Co(AIP)(bpy)0.5(H2O)]·2H2O was examined. The measurements provide important insight into the nature of the chemical transformation in this system including the presence of a previously unreported neat ethanol solvate structure.

Sign in / Sign up

Export Citation Format

Share Document