Dielectric Constants for Binary Amino Acid−Water Solutions from (278.15 to 313.15) K

2009 ◽  
Vol 54 (1) ◽  
pp. 137-141 ◽  
Author(s):  
Kelei Zhuo ◽  
Yujuan Chen ◽  
Lei Kang ◽  
Sijiao Xu ◽  
Jianji Wang



1972 ◽  
Vol 40 (1) ◽  
pp. 49-51 ◽  
Author(s):  
P.M. Gammell ◽  
C.A. Angell


2019 ◽  
Vol 50 (17) ◽  
pp. 1675-1684
Author(s):  
Nese Keklikcioğlu Çakmak


1963 ◽  
Vol 41 (12) ◽  
pp. 3034-3041 ◽  
Author(s):  
F. Hruska ◽  
E. Bock ◽  
T. Schaefer

The proton resonance shifts relative to internal cyclohexane and tetramethylsilane of cis and trans dichloro- and dibromo-ethylenes were measured in dioxane–water solutions, aliphatic solvents, and aromatic solvents. The dielectric constants of the dioxane–water solutions could be smoothly varied between 2 and 10 and, by taking Δ = cis–trans shifts as containing only the dipolar reaction field effect, the data for these solutions were treated as a test of the Buckingham reaction field equation. Linear plots were obtained and reasonable values of the coefficients of the E term confirmed the usefulness of this equation. An equation based on a nonspherical cavity was also used. It was also shown that quadrupolar reaction fields affected the proton shifts. Sizeable deviations from the dioxane–water standards were found for halogenated aliphatic solvents and those containing double or triple bonds. These deviations are interpreted in terms of the shape of the solute molecules and dispersion and anisotropic interactions. The much larger deviations found for aromatic solvents are harder to rationalize but specific interactions were found for both cis and trans forms, indicating an inadequacy in a simple dipole-induced dipole model.



2010 ◽  
Vol 157 (2) ◽  
pp. A214 ◽  
Author(s):  
Tao Zhang ◽  
Nobuyuki Imanishi ◽  
Yuta Shimonishi ◽  
Atsushi Hirano ◽  
Jian Xie ◽  
...  


1989 ◽  
Vol 53 ◽  
pp. 261-268 ◽  
Author(s):  
Kunio Nagahama ◽  
Jiang Tai Xi


1957 ◽  
Vol 49 (8) ◽  
pp. 1307-1310 ◽  
Author(s):  
R. C. Reid ◽  
A. B. Reynolds ◽  
D. T. Morgan ◽  
G. W. Bond ◽  
J. E. Savolainen ◽  
...  


2009 ◽  
Vol 113 (30) ◽  
pp. 13209-13218 ◽  
Author(s):  
C. Magnus Johnson ◽  
Eric Tyrode ◽  
Atte Kumpulainen ◽  
Christofer Leygraf


2020 ◽  
Vol 45 (7) ◽  
pp. 1125-1136
Author(s):  
Liang Song ◽  
Feng‐Qi Zhao ◽  
Si‐Yu Xu ◽  
Xue‐Hai Ju ◽  
Cai‐Chao Ye


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