Synthesis and Characterization of a New Tetradentate Ligand for Cu(II) Metal Ions

2002 ◽  
Vol 67 (12) ◽  
pp. 4040-4044 ◽  
Author(s):  
Ronnie Benshafrut ◽  
Avner Haran ◽  
Dmitry Shvarts ◽  
Benjamin Schneider
Keyword(s):  
Metal Ions ◽  
Synthesis And Characterization ◽  
Tetradentate Ligand

scholarly journals Synthesis and Characterization of Tripodal Tetradentate Ligand Type NS3 and its Complexes with Re(V), Ni(II), Cu(II), Zn(II), Cd(II), and Hg(II)

2009 ◽  
Vol 6 (1) ◽  
pp. 173-187
Author(s):  
Baghdad Science Journal
Keyword(s):  
Electrical Conductivity ◽  
Metal Ions ◽  
Synthesis And Characterization ◽  
Planar Geometry ◽  
Spectroscopic Techniques ◽  
Tetradentate Ligand ◽  
Ligand Type ◽  
Square Planar ◽  
1H Nuclear Magnetic Resonance

This work represents the preparation of the starting material, 3-chloro-2-oxo-1,4-dithiacyclohexane (S) using a new method. This material was reacted with, 4-phenylthiosemicarbazide to give (H3NS3) as a tetradentate ligand H3L. New complex of rhenium (V) with this ligand of the formula [ReO(L)] was prepared. New complexes of the general formula [M(HL)] of this ligand when reacted with some metal ions where: M = Ni(II), Cu(II), Cd(II), Zn(II), Hg(II) have been reported. The ligand and the complexes were characterized by infrared, ultraviolet–visible, mass, 1H nuclear magnetic resonance and atomic absorption spectroscopic techniques and by (HPLC), elemental analysis, and electrical conductivity. The proposed structure for H3L with Re (V) is square pyramidal, while Ni(II) complex was square planar geometry, and with the rest of metal ions are distorted tetrahedral.

Synthesis and Characterization of Glyoxalic Acid Thiosemicarbazone Complexes of Some Bivalent Metal Ions

1995 ◽  
Vol 25 (3) ◽  
pp. 417-427 ◽  
Author(s):  
Jun—Lian Tian ◽  
En—Qing Gao ◽  
Yan—Tuan Li ◽  
Shu—Xiang Liu
Keyword(s):  
Metal Ions ◽  
Synthesis And Characterization ◽  
Bivalent Metal ◽  
Thiosemicarbazone Complexes ◽  
Glyoxalic Acid ◽  
Bivalent Metal Ions

scholarly journals Synthesis and characterization of the Bi2-xHox/2Zr3x/8O3 compounds

2011 ◽  
Vol 47 (2) ◽  
pp. 105-112 ◽  
Author(s):  
P. Sulcová ◽  
P. Bystrzycki ◽  
L. Válek ◽  
M. Trojan
Keyword(s):  
Thermal Analysis ◽  
Metal Ions ◽  
Powder Diffraction ◽  
Synthesis And Characterization ◽  
Inorganic Pigments

A series of novel environmentally inorganic pigments based on Bi2O3 doped by metal ions such as Zr4+ and Ho3+ have been developed and characterized using of methods of thermal analysis, Xray powder diffraction and CIE L

scholarly journals Synthesis and Characterization of Orange Pigments from Rare Earth Metal Ions

2017 ◽  
Vol 29 (8) ◽  
pp. 1673-1676 ◽  
Author(s):  
R. Govinda Rao ◽  
D. Divya
Keyword(s):  
Rare Earth ◽  
Metal Ions ◽  
Rare Earth Metal ◽  
Earth Metal ◽  
Synthesis And Characterization

Synthesis and characterization of novel cation exchange adsorbent for the treatment of real samples for metal ions

2012 ◽  
Vol 200-202 ◽  
pp. 426-432 ◽  
Author(s):  
S.A. Nabi ◽  
A.S. Raeissi ◽  
Mohammad Shahadat ◽  
Rani Bushra ◽  
Amjad Mumtaz Khan
Keyword(s):  
Metal Ions ◽  
Cation Exchange ◽  
Synthesis And Characterization ◽  
Real Samples

Adsorption of Cu2+ Metal Ions on Dithizone-Immobilized Natural Bentonite

2020 ◽  
Vol 840 ◽  
pp. 64-70
Author(s):  
Dian Mira Fadela ◽  
Mudasir Mudasir ◽  
Adhitasari Suratman
Keyword(s):  
Adsorption Isotherm ◽  
Complex Formation ◽  
Metal Ions ◽  
Electrostatic Interaction ◽  
Metal Ion ◽  
Synthesis And Characterization ◽  
Optimum Conditions ◽  
Initial Concentration ◽  
Activated Bentonite

The research of adsorption of Cu2+ metal ion on dithizone-immobilized natural bentonite (DNB) had been carried out. The experiment was begun by the activation of natural bentonite with HCl 4 M and dithizone-immobilized on activated bentonite surface. This study included synthesis and characterization of dithizone-immobilized bentonite and its application in adsorption of Cu2+ metal ions. The type of interaction occurred in the adsorption was tested by sequential desorption. The result showed that dithizone successfully immobilized on activated natural bentonite (ANB). The optimum conditions for Cu2+ metal ions adsorption using dithizone-immobilized natural bentonite are at pH 5; 0.1 g mass of adsorbent, with interaction time 60 min, and the initial concentration of ion at 80 ppm. Kinetics and adsorption isotherm studies suggest that the capacity, of the dithizone-immobilized natural bentonite in adsorbing Cu2+ metal ion is significantly improved compared to activated natural bentonite. The adsorption of Cu2+ metal ions by activated natural bentonite was through several interactions dominated by electrostatic interaction (82%). Otherwise, the interaction of dithizone-immobilized natural bentonite with Cu2+ metal ions in the sequence were dominated by the mechanism of complex formation of (75%). The result shows that the immobilization of dithizone changes the type of electrostatic interaction into complex formation.

Synthesis and Characterization of Phosphonate Ester/Phosphonic Acid Grafted Styrene−Divinylbenzene Copolymer Microbeads and Their Utility in Adsorption of Divalent Metal Ions in Aqueous Solutions

2008 ◽  
Vol 47 (6) ◽  
pp. 2010-2017 ◽  
Author(s):  
Adriana Popa ◽  
Corneliu-Mircea Davidescu ◽  
Petru Negrea ◽  
Gheorghe Ilia ◽  
Antonis Katsaros ◽  
...  
Keyword(s):  
Aqueous Solutions ◽  
Metal Ions ◽  
Phosphonic Acid ◽  
Divalent Metal ◽  
Synthesis And Characterization ◽  
Divalent Metal Ions ◽  
Styrene Divinylbenzene
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