Notes - Kinetics of Reaction of Acyl Chlorides. III. Hydrolysis of Phosphinyl Chlorides.

1956 ◽  
Vol 21 (2) ◽  
pp. 248-249 ◽  
Author(s):  
H. K. Hall, Jr.
Keyword(s):  
Acyl Chlorides ◽  
Kinetics Of Reaction ◽  
Kinetics Of ◽  
Hydrolysis Of

Studies on the kinetics of reaction and hydrolysis of fluorescamine

1974 ◽  
Vol 163 (1) ◽  
pp. 400-403 ◽  
Author(s):  
Stanley Stein ◽  
Peter Böhlen ◽  
Sidney Udenfriend
Keyword(s):  
Kinetics Of Reaction ◽  
Kinetics Of ◽  
Hydrolysis Of

Kinetics of the hydrolysis of acyl chlorides in pure water

1967 ◽  
Vol 45 (14) ◽  
pp. 1619-1629 ◽  
Author(s):  
A. Queen
Keyword(s):  
Pure Water ◽  
Activation Parameters ◽  
Acyl Chlorides ◽  
Reversible Addition ◽  
Electron Donation ◽  
Kinetics Of ◽  
Hydrolysis Of ◽  
Chlorine Bond ◽  
Oxygen Bond ◽  
Bimolecular Mechanism

The activation parameters ΔH≠, ΔS≠, and ΔCP≠ for the hydrolyses of a series of alkyl chloroformates and dimethylcarbamyl chloride in water have been determined. The results indicate that, with increasing electron donation to the chlorocarbonyl group, the mechanism changes from bimolecular to unimolecular (SN1) displacement at this position. For isopropyl chloroformate, some concurrent alkyl–oxygen bond fission is also indicated. The bimolecular mechanism involves reversible addition of water to the carbonyl group followed by ionization of the carbon–chlorine bond.

Étude cinétique de la N-chloration de l'acide cyanurique en phase aqueuse

1990 ◽  
Vol 68 (2) ◽  
pp. 307-313 ◽  
Author(s):  
Denise Matte ◽  
Bernard Solastiouk ◽  
André Merlin ◽  
Xavier Deglise
Keyword(s):  
Aqueous Medium ◽  
Rate Constants ◽  
Cyanuric Acid ◽  
Stopped Flow ◽  
Experimental Values ◽  
Kinetics Of Reaction ◽  
Limiting Case ◽  
Kinetics Of ◽  
Hydrolysis Of ◽  
Phase Aqueuse

A complete kinetic study of the N-chlorination, in basic aqueous medium, of cyanuric acid by the stopflow spectrophotometric method is presented. Our experimental results can be interpreted by two pairs of kinetically indistinguishable mechanisms.[Formula: see text]or[Formula: see text]and[Formula: see text]or[Formula: see text]The rate constants and their corresponding activation energies were determined in the limiting case where one of the elementary steps in each pair is involved alone in the kinetics of reaction.[Formula: see text]The rate constants for hydrolysis of the monochlorinated cyanuric acid derivatives were derived from our experimental values. Keywords: kinetics, N-chlorination, 1,3,5-triazine-2,4,6-trione, aqueous medium, stopped flow.

Kinetics of reaction of 1-chloro-2,3-epoxypropane with low glycols

1972 ◽  
Vol 37 (5) ◽  
pp. 1698-1705 ◽  
Author(s):  
J. Novák
Keyword(s):  
Kinetics Of Reaction ◽  
Kinetics Of

Kinetics of reaction of 4-substituted 2-nitrofluorobenzenes with piperidine in benzene-acetonitrile mixtures

1973 ◽  
Vol 38 (3) ◽  
pp. 884-891 ◽  
Author(s):  
J. Kaválek ◽  
V. Štěrba
Keyword(s):  
Kinetics Of Reaction ◽  
Kinetics Of

Influence of medium on alkaline hydrolysis of succinic acid monomethyl and monopropyl esters

1980 ◽  
Vol 45 (11) ◽  
pp. 2873-2882
Author(s):  
Vladislav Holba ◽  
Ján Benko
Keyword(s):  
Succinic Acid ◽  
Kinetic Parameters ◽  
Alkaline Hydrolysis ◽  
Specific Interactions ◽  
Nonaqueous Media ◽  
The Media ◽  
Kinetics Of ◽  
Hydrolysis Of

The kinetics of alkaline hydrolysis of succinic acid monomethyl and monopropyl esters were studied in mixed aqueous-nonaqueous media at various temperatures and ionic strengths. The results of measurements are discussed in terms of electrostatic and specific interactions between the reactants and other components of the reaction mixture. The kinetic parameters in the media under study are related to the influence of the cosolvent on the solvation sphere of the reactants.

Belousov–Zhabotinskii type oscillation reaction with glycerol and kinetics of reactions between the system components

1987 ◽  
Vol 52 (10) ◽  
pp. 2375-2382 ◽  
Author(s):  
Ľubica Adamčíková ◽  
Peter Ševčík
Keyword(s):  
Oscillation System ◽  
Chemical Oscillations ◽  
Oscillation Reaction ◽  
Reaction Solution ◽  
System Components ◽  
Probable Source ◽  
Belousov Zhabotinskii Reaction ◽  
Kinetics Of ◽  
Hydrolysis Of ◽  
Type Oscillation

Glycerol causes chemical oscillations in Belousov-Zhabotinskii reaction in a closed system as well as in a reaction solution bubbled with nitrogen. Since the oxidation of glycerol with bromate ions does not proceed autocatalytically and bromine in the oxidation state 0 or +1 in the absence of light does not react with glycerol, hydrolysis of bromine is the probable source of bromide ions in the studied oscillation system.

Kinetics of hydrolysis of peroxodisulphate ions in acidic medium to peroxomonosulphuric acid

1981 ◽  
Vol 46 (5) ◽  
pp. 1229-1236 ◽  
Author(s):  
Jan Balej ◽  
Milada Thumová
Keyword(s):  
Ionic Strength ◽  
Rate Constants ◽  
Acidic Medium ◽  
Measured Data ◽  
Molar Ratios ◽  
Starting Solution ◽  
Kinetics Of Hydrolysis ◽  
Rate Of Hydrolysis ◽  
Kinetics Of ◽  
Hydrolysis Of

The rate of hydrolysis of S2O82- ions in acidic medium to peroxomonosulphuric acid was measured at 20 and 30 °C. The composition of the starting solution corresponded to the anolyte flowing out from an electrolyser for production of this acid or its ammonium salt at various degrees of conversion and starting molar ratios of sulphuric acid to ammonium sulphate. The measured data served to calculate the rate constants at both temperatures on the basis of the earlier proposed mechanism of the hydrolysis, and their dependence on the ionic strength was studied.

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