Electron Recombination Kinetics and the Analysis of Collection Efficiency and Diffusion Length Measurements in Dye Sensitized Solar Cells

2010 ◽  
Vol 114 (44) ◽  
pp. 19134-19140 ◽  
Author(s):  
Piers R. F. Barnes ◽  
Brian C. O’Regan

2013 ◽  
Vol 2013 ◽  
pp. 1-7 ◽  
Author(s):  
En Mei Jin ◽  
Kyung-Hee Park ◽  
Ju-Young Park ◽  
Jae-Wook Lee ◽  
Soon-Ho Yim ◽  
...  

A chitosan binder-based TiO2photoelectrode is used in dye-sensitized solar cells (DSSCs). Field-emission scanning electron microscope (FE-SEM) images revealed that the grain size, thickness, and distribution of TiO2films are affected by the chitosan content. With addition of 2.0 wt% chitosan to the TiO2film (D2), the surface pore size became the smallest, and the pores were fairly evenly distributed. The electron transit time, electron recombination lifetime, diffusion coefficient, and diffusion length were analyzed by IMVS and IMPS. The best DSSC, with 2.0 wt% chitosan addition to the TiO2film, had a shorter electron transit time, longer electron recombination lifetime, and larger diffusion coefficient and diffusion length than the other samples. The results of 2.0 wt% chitosan-added TiO2DSSCs are an electron transit time of  s, electron recombination lifetime of  s, diffusion coefficient of  cm2s−1, diffusion length of 14.81 μm, and a solar conversion efficiency of 4.18%.



ChemPhysChem ◽  
2009 ◽  
Vol 10 (15) ◽  
pp. 2698-2702 ◽  
Author(s):  
Daniel Kwan-Pang Wong ◽  
Chen-Hao Ku ◽  
Yen-Ru Chen ◽  
Guan-Ren Chen ◽  
Jih-Jen Wu






RSC Advances ◽  
2015 ◽  
Vol 5 (43) ◽  
pp. 33855-33862 ◽  
Author(s):  
Molang Cai ◽  
Xu Pan ◽  
Weiqing Liu ◽  
John Bell ◽  
Songyuan Dai

DMImBS is used as a novel additive in dye-sensitized solar cells to restrain the electron recombination and intercalation of Li+.



2016 ◽  
Vol 40 (11) ◽  
pp. 9176-9186 ◽  
Author(s):  
Hee-Je Kim ◽  
Jeong-Hoon Kim ◽  
Ikkurthi Kanaka Durga ◽  
Dinah Punnoose ◽  
Nagabhushanam Kundakarla ◽  
...  

A graphical diagram of DSSCs without and with ZnS as a compact layer on a TiO2 film.



Nanomaterials ◽  
2019 ◽  
Vol 9 (12) ◽  
pp. 1645 ◽  
Author(s):  
Seong Il Cho ◽  
Hye Kyeong Sung ◽  
Sang-Ju Lee ◽  
Wook Hyun Kim ◽  
Dae-Hwan Kim ◽  
...  

At an elevated temperature of 90 °C, a chemical bath deposition using an aqueous solution of Zn(NO3)2·6H2O and (CH2)6N4 resulted in the formation of both nanoflowers and microrods of ZnO on F-doped SnO2 glass with a seed layer. The nanoflowers and microrods were sensitized with dyes for application to the photoelectrodes of dye-sensitized solar cells (DSSCs). By extending the growth time of ZnO, the formation of nanoflowers was reduced and the formation of microrods favored. As the growth time was increased from 4 to 6 and then to 8 h, the open circuit voltage (Voc) values of the DSSCs were increased, whilst the short circuit current (Jsc) values varied only slightly. Changes in the dye-loading amount, dark current, and electrochemical impedance were monitored and they revealed that the increase in Voc was found to be due to a retardation of the charge recombination between photoinjected electrons and I3− ions and resulted from a reduction in the surface area of ZnO microrods. A reduced surface area decreased the dye contents adsorbed on the ZnO microrods, and thereby decreased the light harvesting efficiency (LHE). An increase in the electron collection efficiency attributed to the suppressed charge recombination counteracted the decreased LHE, resulting in comparable Jsc values regardless of the growth time.



2011 ◽  
Vol 13 (38) ◽  
pp. 17359 ◽  
Author(s):  
Hongxia Wang ◽  
Meinan Liu ◽  
Min Zhang ◽  
Peng Wang ◽  
Hidetoshi Miura ◽  
...  


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