Impedance Spectra of Nonhomogeneous, Multilayered Porous Composite Graphite Electrodes for Li-Ion Batteries: Experimental and Theoretical Studies

2011 ◽  
Vol 115 (18) ◽  
pp. 9210-9219 ◽  
Author(s):  
Shou-Dong Xu ◽  
Quan-Chao Zhuang ◽  
Lei-Lei Tian ◽  
Yin-Ping Qin ◽  
Liang Fang ◽  
...  



2006 ◽  
Vol 9 (4) ◽  
pp. A196 ◽  
Author(s):  
Xiaoxi Zuo ◽  
Mengqing Xu ◽  
Weishan Li ◽  
Dagen Su ◽  
Jiansheng Liu


Nanoscale ◽  
2016 ◽  
Vol 8 (29) ◽  
pp. 14004-14014 ◽  
Author(s):  
Lukas Seidl ◽  
Slađana Martens ◽  
Jiwei Ma ◽  
Ulrich Stimming ◽  
Oliver Schneider


2021 ◽  
pp. 150269
Author(s):  
Xiaojie He ◽  
Anwen Tang ◽  
Yi Li ◽  
Yongfan Zhang ◽  
Wenkai Chen ◽  
...  


2018 ◽  
Author(s):  
Zhujie Li ◽  
Guillaume Jeanmairet ◽  
Trinidad Mendez-Morales ◽  
Benjamin Rotenberg ◽  
Mathieu Salanne

<div>Water-in-salts is a new family of electrolytes with very promising electrochemical properties for energy storage applications. Despite several studies involving them inside Li-ion batteries and supercapacitors, their interfacial properties remain largely unknown. Here we simulate the interface between electrified graphite electrodes and a highly concentrated waterin- salt (where the salt is Bis(trifluoromethane)sulfonimide lithium, LiTFSI) using constant applied potential molecular dynamics. We show that the capacitance differs markedly between the positive and the negative electrodes, which is due to the large asymmetry in size (and</div><div>shape) between the ions. By using importance sampling, we further investigate the changes in the structure of the salt at the interface and we observe that large variations occur, that are at</div><div>the origin of a series of peaks in the differential capacitance.</div>



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