Substrate Induced Thermal Decomposition of Perfluoro-Pentacene Thin Films on the Coinage Metals

2012 ◽  
Vol 116 (45) ◽  
pp. 24098-24106 ◽  
Author(s):  
Christian Schmidt ◽  
Tobias Breuer ◽  
Stefan Wippermann ◽  
Wolf Gero Schmidt ◽  
Gregor Witte
Keyword(s):  
Thin Films ◽  
Thermal Decomposition ◽  
Coinage Metals

Influence of thermal decomposition behavior of titanium precursors on (Ba,Sr)TiO3 thin films

2001 ◽  
Vol 11 (PR3) ◽  
pp. Pr3-675-Pr3-682 ◽  
Author(s):  
Y. S. Min ◽  
Y. J. Cho ◽  
D. Kim ◽  
J. H. Lee ◽  
B. M. Kim ◽  
...  
Keyword(s):  
Thin Films ◽  
Thermal Decomposition ◽  
Thermal Decomposition Behavior ◽  
Decomposition Behavior

scholarly journals Thermal decomposition of tris(O-ethyldithiocarbonato)-antimony(III)—a single-source precursor for antimony sulfide thin films

2021 ◽  
Author(s):  
Jako S. Eensalu ◽  
Kaia Tõnsuaadu ◽  
Jasper Adamson ◽  
Ilona Oja Acik ◽  
Malle Krunks
Keyword(s):  
Thin Films ◽  
Thermal Decomposition ◽  
Mass Loss ◽  
Solid Phase ◽  
Evolved Gas Analysis ◽  
Gas Analysis ◽  
Thermal Decomposition Mechanism ◽  
Product Analysis ◽  
Gaseous Species ◽  
Single Source Precursor

AbstractThermal decomposition of tris(O-ethyldithiocarbonato)-antimony(III) (1), a precursor for Sb2S3 thin films synthesized from an acidified aqueous solution of SbCl3 and KS2COCH2CH3, was monitored by simultaneous thermogravimetry, differential thermal analysis and evolved gas analysis via mass spectroscopy (TG/DTA-EGA-MS) measurements in dynamic Ar, and synthetic air atmospheres. 1 was identified by Fourier transform infrared spectroscopy (FTIR) and nuclear magnetic resonance (NMR) measurements, and quantified by NMR and elemental analysis. Solid intermediates and final decomposition products of 1 prepared in both atmospheres were determined by X-ray diffraction (XRD), Raman spectroscopy, and FTIR. 1 is a complex compound, where Sb is coordinated by three ethyldithiocarbonate ligands via the S atoms. The thermal degradation of 1 in Ar consists of three mass loss steps, and four mass loss steps in synthetic air. The total mass losses are 100% at 800 °C in Ar, and 66.8% at 600 °C in synthetic air, where the final product is Sb2O4. 1 melts at 85 °C, and decomposes at 90–170 °C into mainly Sb2S3, as confirmed by Raman, and an impurity phase consisting mostly of CSO 2 2− ligands. The solid-phase mineralizes fully at ≈240 °C, which permits Sb2S3 to crystallize at around 250 °C in both atmospheres. The gaseous species evolved include CS2, C2H5OH, CO, CO2, COS, H2O, SO2, and minor quantities of C2H5SH, (C2H5)2S, (C2H5)2O, and (S2COCH2CH3)2. The thermal decomposition mechanism of 1 is described with chemical reactions based on EGA-MS and solid intermediate decomposition product analysis.

Explosive Thermal Decomposition Mechanism of NTO

1995 ◽  
Vol 418 ◽  
Author(s):  
David J. Beardall ◽  
Tod R. Botcher ◽  
Charles A. Wight
Keyword(s):  
Thin Films ◽  
Thermal Decomposition ◽  
Fourier Transform ◽  
Infrared Spectroscopy ◽  
Condensed Phase ◽  
Decomposition Product ◽  
Rapid Heating ◽  
Initial Step ◽  
Thermal Decomposition Mechanism ◽  
Decomposition Products

AbstractThe initial step of the thermal decomposition of NTO (5-nitro-2,4-dihydro-3H-1,2,4- triazol-3-one) is determined by pulsed infrared laser pyrolysis of thin films. Rapid heating of the film and quenching to 77 K allows one to trap the initial decomposition products in the condensed phase and analyze them using transmission Fourier-transform infrared spectroscopy. The initial decomposition product is CO2; NO2 and HONO are not observed. We propose a new mechanism for NTO decomposition in which CO2 is formed.

scholarly journals Thermal decomposition of barium trifluoroacetate thin films

2013 ◽  
Vol 556 ◽  
pp. 58-62 ◽  
Author(s):  
H. Eloussifi ◽  
J. Farjas ◽  
P. Roura ◽  
S. Ricart ◽  
T. Puig ◽  
...  
Keyword(s):  
Thin Films ◽  
Thermal Decomposition

High-TcSuperconducting Bi-Pb-Sr-Ca-Cu-O Thin Films Prepared by Thermal Decomposition of Metallic Complex Salts

1989 ◽  
Vol 28 (Part 2, No. 4) ◽  
pp. L624-L627 ◽  
Author(s):  
Toshiro Maruyama ◽  
Seiji Higashi
Keyword(s):  
Thin Films ◽  
Thermal Decomposition ◽  
Metallic Complex ◽  
Complex Salts

Physical characterization of a-Si thin films deposited by thermal decomposition of iodosilanes

1991 ◽  
Vol 24 (6) ◽  
pp. 1015-1021 ◽  
Author(s):  
G Tamizhmani ◽  
M Cocivera ◽  
T Oakley ◽  
C Fischer ◽  
M Fujimoto
Keyword(s):  
Thin Films ◽  
Thermal Decomposition ◽  
Physical Characterization

Synthesis, crystal structure and thermal decomposition of [La2(CH3CH2COO)6·(H2O)3]·3.5H2O precursor for high-k La2O3 thin films deposition

2010 ◽  
Vol 45 (9) ◽  
pp. 1203-1208 ◽  
Author(s):  
L. Ciontea ◽  
M. Nasui ◽  
T. Petrisor ◽  
R.B. Mos ◽  
M.S. Gabor ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Thin Films ◽  
Thermal Decomposition ◽  
High K

scholarly journals Formation of RuO2-TiO2 Thin Films by Thermal Decomposition Technique

1992 ◽  
Vol 100 (1161) ◽  
pp. 663-667 ◽  
Author(s):  
Shinji SAITO ◽  
Kazuyuki OKANO ◽  
Chiharu HAYASHI ◽  
Keizaburo KURAMASU ◽  
Yasutaka TAKAHASHI
Keyword(s):  
Thin Films ◽  
Thermal Decomposition ◽  
Decomposition Technique ◽  
Tio2 Thin Films

Thermal decomposition of copper nitride thin films and dots formation by electron beam writing

2001 ◽  
Vol 169-170 ◽  
pp. 358-361 ◽  
Author(s):  
Toshikazu Nosaka ◽  
Masaaki Yoshitake ◽  
Akio Okamoto ◽  
Soichi Ogawa ◽  
Yoshikazu Nakayama
Keyword(s):  
Thin Films ◽  
Thermal Decomposition ◽  
Electron Beam ◽  
Copper Nitride
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