Nucleophilic, electrophilic and homolytic reaction chemistry of transition-metal carbonyl trihalomethyl complexes

1984 ◽  
Vol 3 (2) ◽  
pp. 314-319 ◽  
Author(s):  
Thomas G. Richmond ◽  
Ann M. Crespi ◽  
Duward F. Shriver
Keyword(s):  
Transition Metal ◽  
Metal Carbonyl ◽  
Homolytic Reaction

Carbon Chain Growth by Sequential Reactions of CO and CO2 with a Transition Metal Carbonyl Complex

2018 ◽  
Author(s):  
Richard Kong ◽  
Mark Crimmin
Keyword(s):  
Transition Metal ◽  
Metal Carbonyl ◽  
Carbon Chain ◽  
Chain Growth ◽  
Carbonyl Complex ◽  
Fischer Tropsch ◽  
Carbon Chains ◽  
Sequential Coupling ◽  
Energy Economy ◽  
Sequential Reactions

<i>The formation of carbon chains by the coupling of COx (X = 1 or 2) units on transition metals is a fundamental step relevant to Fischer-Tropsch catalysis. Fischer-Tropsch catalysis produces energy dense liquid hydrocarbons from synthesis gas (CO and H2) and has been a mainstay of the energy economy since its discovery nearly a century ago. Despite detailed studies aimed at elucidating the steps of catalysis, experimental evidence for chain growth (Cn to Cn+1 ; n > 2) from the reaction of CO with metal complexes is unprecedented. In this paper, we show that carbon chains can be grown from sequential reactions of CO or CO2 with a transition metal carbonyl complex. By exploiting the cooperative effect of transition and main group metals, we document the first example of chain propagation from sequential coupling of CO units (C1 to C3 to C4), along with the first example of incorporation of CO2 into the growing carbon chain.</i><br>

Transition Metal Carbonyl Complexes of an N-Heterocyclic Carbene Stabilized Silyliumylidene Ion

2019 ◽  
Vol 58 (21) ◽  
pp. 14931-14937 ◽  
Author(s):  
Philipp Frisch ◽  
Tibor Szilvási ◽  
Amelie Porzelt ◽  
Shigeyoshi Inoue
Keyword(s):  
Transition Metal ◽  
Metal Carbonyl ◽  
Carbonyl Complexes ◽  
Metal Carbonyl Complexes

ChemInform Abstract: Transition Metal Carbonyl Linker Units

ChemInform ◽  
2010 ◽  
Vol 41 (43) ◽  
pp. no-no
Author(s):  
Susan E. Gibson ◽  
Amol A. Walke
Keyword(s):  
Transition Metal ◽  
Metal Carbonyl

Hydrogen bond of transition metal carbonyl complexes with perfluoro-tert-butanol

1988 ◽  
Vol 37 (3) ◽  
pp. 470-475 ◽  
Author(s):  
B. V. Lokshin ◽  
S. G. Kazaryan ◽  
A. G. Ginzburg
Keyword(s):  
Hydrogen Bond ◽  
Transition Metal ◽  
Metal Carbonyl ◽  
Carbonyl Complexes ◽  
Metal Carbonyl Complexes ◽  
Tert Butanol

Silicon-transition metal chemistry. VII. Metal carbonyl derivatives of 1,2-bis(dimethylsilyl)ethane

1974 ◽  
Vol 13 (3) ◽  
pp. 511-513 ◽  
Author(s):  
L. Vancea ◽  
W. A. G. Graham
Keyword(s):  
Transition Metal ◽  
Metal Carbonyl ◽  
Transition Metal Chemistry ◽  
Metal Chemistry ◽  
Carbonyl Derivatives ◽  
Derivatives Of

ChemInform Abstract: Reactions of Dimethylsilylferrocenes with Some Transition Metal Carbonyl Complexes.

ChemInform ◽  
2010 ◽  
Vol 23 (6) ◽  
pp. no-no
Author(s):  
S. KOTANI ◽  
T. TANIZAWA ◽  
K. SHIINA ◽  
K. SONOGASHIRA
Keyword(s):  
Transition Metal ◽  
Metal Carbonyl ◽  
Carbonyl Complexes ◽  
Metal Carbonyl Complexes

Group VI transition metal carbonyl hydrosulfides Na[M(CO)5(SH)] (M = Cr, Mo, W) as water-soluble H2S-releasing agents

RSC Advances ◽  
2015 ◽  
Vol 5 (14) ◽  
pp. 10703-10706
Author(s):  
Hwa Tiong Poh ◽  
Ashfaq A. Bengali ◽  
Wai Yip Fan
Keyword(s):  
Transition Metal ◽  
Metal Carbonyl ◽  
Water Soluble ◽  
Group Vi

Group VI metal carbonyl hydrosulfides as water-soluble H2S-releasing molecules.

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