scholarly journals Transition From Low-K to High-K Calc-Alkaline Magmatism at Approximately 84 Ma in the Eastern Pontides (NE Turkey): Magmatic Response to Slab Rollback of the Black Sea

2018 ◽  
Vol 123 (9) ◽  
pp. 7604-7628 ◽  
Author(s):  
Ze Liu ◽  
Di-Cheng Zhu ◽  
Qing Wang ◽  
Yener Eyuboglu ◽  
Zhi-Dan Zhao ◽  
...  
2021 ◽  
Author(s):  
Cemre Ay ◽  
Gürsel Sunal ◽  
Aral I. Okay

<p>Upper Cretaceous arc-related volcanic and volcanoclastic units overlying the Paleozoic sedimentary rocks of the Istanbul Zone are a key unit related to the opening of the Black Sea as a back-arc basin. They formed as a result of north dipping subduction of the Neo-Tethys Ocean beneath Laurasia. We studied the Upper Cretaceous volcanic units north of Istanbul along several stratigraphic sections, and present new geochemical data from the volcanic rocks in order to understand Cretaceous geodynamic evolution of the İstanbul Zone.</p><p>The Upper Cretaceous  volcanic units north of Istanbul are divided into two formations. At the base there is a fore-arc turbidite succession,the İshaklı Formation, which is made up of volcaniclastic sandstone, shale, marl, tuff, debris flow horizons and epiclastic rocks of Turonian age. The İshaklı Formation is conformably overlain by the volcanoclastics,  tuffs, andesite and basalt lavas and agglomerates- the Riva Formation, which represents the arc/ intra-arc series.</p><p>Geochemically, basalts and basaltic andesites of the Riva Formation are low K calc-alkaline to medium-high K calc-alkaline and with magnesium numbers ranging from 32.6% to 51.5% Primitive mantle normalized spider diagram of trace elements show  enrichment in LILE elements (K, Rb, Sr, Cs, Ba, Th and U) and depletion in HFS elements ( Nb,Ta and Ti) . The high ratio of LILE/ HFS and negative Nb-Ta anomalies indicate that the volcanism evolved in subduction setting. Chondirite-normalized REE pattern display slight negative Eu anomalies and the La/Yb ratios of the samples range between 2,76 and 4,89. Our new geochemical, stratigraphical and the regional geological data suggest that north of Istanbul there was a transition from fore-arc deposition to arc volcanism during the Late Cretaceous opening of the Western Black Sea.  Considering the whole Pontide – Sredna-Gora Upper Cretaceous magmatic arc, it can be stated that calc-alkaline volcanism developed in relation to northward subduction of the Neo-Tethys oceanic lithosphere during the Turonian, and may have passed into high-K calc alkaline and shoshonitic magmatism as a result of the progressive extentional tectonism during the Campanian.</p>


Lithos ◽  
1998 ◽  
Vol 45 (1-4) ◽  
pp. 329-348 ◽  
Author(s):  
A. Rottura ◽  
G.M. Bargossi ◽  
A. Caggianelli ◽  
A. Del Moro ◽  
D. Visonà ◽  
...  

2001 ◽  
Vol 172 (2) ◽  
pp. 189-200 ◽  
Author(s):  
Olivier Blein ◽  
Henriette Lapierre ◽  
Richard A. Schweickert ◽  
Arnaud Pecher ◽  
Cedric Reynaud

Abstract Two types of island-arc occur in the North American Cordillera during the Permian-Triassic times. The first type is exposed in the eastern Klamath and Blue Mountains (fig. 1). Its stratigraphy is continuous from Permian to Triassic, and is composed of arc-tholeiites with minor calc-alkaline lavas. This suite shows high epsilon Nd (sub (T)) values similar to the range of intra-oceanic island-arc [Lapierre et al., 1987; Brouxel et al., 1987, 1988; Charvet et al., 1990; Lapierre et al., 1990, 1994]. In contrast, the second type, exposed in northern Sierra Nevada and central-western Nevada (Black Dyke) (fig. 1), is characterized by an early Permian calc-alkaline suite, with positive to negative epsilon Nd (sub (T)) values. Its basement is inferred to present continental affinities [Rouer et Lapierre, 1989; Rouer et al., 1989; Blein et al., 1996, 2000]. In western Nevada, volcanic rocks of early Triassic age are present in few localities: (1) the Triassic Koipato Group in central Nevada (fig. 1); (2) the Pablo Formation in the Shoshone mountains and the Paradise Range (figs. 1 and 2); and (3) the Garfield Flat formation in the Excelsior mountains (figs. 1 and 2). Silberling [1959] has subdivided the Pablo formation into three members: clastic, limestone, and greenstone (fig. 3). The clastic member consists of andesites, interbedded with volcaniclastic turbidites. The contact between the clastic and the limestone members is gradational and interlensing. The limestones are locally bioclastic with shell fragments, indicating a shallow-water deposition. They yielded a reworked late Permian fauna which suggests a late Permian or younger age. The clastic and limestone members could represent the recurrent rapid deposition in a shallow marine basin of volcanic flows, reworked material from a nearby terrane of volcanic, granitic, and sedimentary rocks. The greenstone member is composed of andesites, volcanic breccias and tuffs. The middle Triassic Granstville formation rests conformably on the Pablo formation. Both formations are affected by Mesozoic polyphase deformations [Oldow, 1985]. The Permian and/or Triassic Garfield Flat formation is composed of ignimbrites and pyroclastic breccia interlayered with conglomerates, sandstones, calcareous and red pelites (fig. 4). The Jurassic-Triassic Gabbs-Sunrise formation rests unconformably on the Garfield Flat formation. Both formations are affected by Mesozoic polyphase deformations [Oldow, 1985]. In the Pablo formation, lavas are shoshonitic basalts and calc-alkaline andesites, while calc-alkaline andesites and rhyolites predominate in the Garfield Flat formation. Basalts and andesites exhibit enriched LREE patterns (fig. 6) with slight negative anomalies in TiO 2 , Nb and Ta typical of subducted-related magmas in the primitive mantle-normalized spidergrams (fig. 7). The lavas show epsilon Sr (sub (T)) and epsilon Nd (sub (T)) values which range between -0.4 to +19.6, and -1.4 to +0.8 respectively (fig. 8). Most of the samples are displaced from the mantle array toward higher epsilon Sr (sub (T)) values, due to the alteration. The epsilon Nd (sub (T)) values, close to the Bulk Earth composition, record an interaction between material from a juvenile pole (mantle or young crust) and from an old crust. The Pablo and Garfield Flat formations differ from the Permian Black Dyke formation. This latter is characterized by calc-alkaline basalts and mafic andesites enriched in LREE, and a mantle source contaminated by subducted sediments or arc-basement [Blein et al., 2000]. The Pablo and Garfield Flat formations show many similarities with the Koipato Group. In central Nevada, the Koipato Group is a sequence of andesites, dacites and rhyolites interbedded with tuffs and volcaniclastic sediments. It rests with a marked angular unconformity on folded Upper Paleozoic oceanic rocks [Silberling and Roberts, 1962]. Fission-track dating on zircon [McKee and Burke, 1972] indicate an age of 225+ or -30 Ma for the Koipato Group. Ammonites, near the top, are considered to be upper early Triassic [Silberling, 1973]. The Pablo and Garfield Flat lavas share in common with the Koipato Group: (1) late Permian to middle Triassic ages; (2) abundant andesites and rhyolites with minor basalts, associated with felsic pyroclastic breccias; (3) LILE and LREE enrichement; (4) low epsilon Nd (sub (T)) values suggesting a juvenile source with slight contamination by a crustal component; (5) La/Nb ratios close to the lower limit of orogenic andesites [Gill, 1981]; and (6) high Nb/Zr ratios suggesting a generation far from a subduction zone [Thieblemont and Tegyey, 1994]. This Triassic high-K calc-alkaline to shoshonitic magmatism is enriched in K, Rb, Th, Nb and Ta relative to the calc-alkaline Black Dyke lavas, and is mainly juvenile judging from Nd isotopic ratios. The source may correspond either to a juvenile crust composed of high-K andesites [Roberts and Clemens, 1993], which could be the Black Dyke lavas, or to phlogopite-K-richterite enriched lithospheric mantle. In both cases, the generation of the high-K calc-alkaline magmatism needs the former existence of an important subduction phase to generate its source. The lavas of the Pablo and Garfield Flat formations are similar to calc-alkaline and shoshonitic lavas emitted in post-collisional setting. Post-collisional arc/continent magmatism is varied from intermediate to felsic, calc-alkaline to shoshonitic, low to high-K and meta-aluminous to hyper-aluminous. The studied lavas may be compared to the arc/passive margin collision of Papua-New Guinea, where a post-collisional magmatism characterized by high-K basalts, andesites and shoshonites [McKenzie, 1976]. In Nevada, this post-collisional event develops after the accretion of the Permian Black Dyke island-arc (Type 2), and before the accretion of the intra-oceanic Permo-Triassic arc (Type 1).


2021 ◽  
pp. jgs2020-221
Author(s):  
Guichun Liu ◽  
Guangyan Chen ◽  
M. Santosh ◽  
Xin Qian ◽  
Zaibo Sun ◽  
...  

Early Paleozoic trondhjemites, gneissic granites and alkali granites in southern Yunnan preserve important records of the tectonic evolution of the Prototethyan Ocean and regional correlations. Zircon ages suggest that these granitoids were emplaced from 476 to 436 Ma. The trondhjemites are characterized by high Na2O and low K2O contents, with εNd(t) values of −1.9 to −3.5 and εHf(t) values of −2.8 to +3.9. The trondhjemites were derived from an amphibolite source with a juvenile mafic component. The gneissic granites belong to the metaluminous low-K calc-alkaline series with an εNd(t) value of −6.2 and εHf(t) values of −5.0 to −0.4. The alkali granites belong to the high-K calc-alkaline series and yield εNd(t) values of −10.1 to −10.7 and εHf(t) values of −7.9 to −2.3. The gneissic granites were derived from an ‘ancient' lower mafic crust, whereas the alkali granites were derived from a meta-sedimentary source. These granitoids were formed during the subduction of the Prototethyan Ocean beneath the Simao Block and can be compared with similar igneous rocks from the Truong Son and Tam Ky-Phuoc Son zones in southern Laos. Our study, along with Early Paleozoic igneous suites from southern Laos, central Vietnam and the Malay Peninsula, suggests an arc–back-arc system along the northern margin of Gondwana.Supplementary material: Tables of zircon U–Pb and in-situ Hf and geochemical data are available at https://doi.org/10.6084/m9.figshare.c.5322386


2017 ◽  
Vol 60 (11-14) ◽  
pp. 1326-1360 ◽  
Author(s):  
Cailai Wu ◽  
Shuwen Dong ◽  
Di Wu ◽  
Xin Zhang ◽  
W. G. Ernst

Author(s):  
Avril V. Somlyo ◽  
H. Shuman ◽  
A.P. Somlyo

This is a preliminary report of electron probe analysis of rabbit portal-anterior mesenteric vein (PAMV) smooth muscle cryosectioned without fixation or cryoprotection. The instrumentation and method of electron probe quantitation used (1) and our initial results with cardiac (2) and skeletal (3) muscle have been presented elsewhere.In preparations depolarized with high K (K2SO4) solution, significant calcium peaks were detected over the sarcoplasmic reticulum (Fig 1 and 2) and the continuous perinuclear space. In some of the fibers there were also significant (up to 200 mM/kg dry wt) calcium peaks over the mitochondria. However, in smooth muscle that was not depolarized, high mitochondrial Ca was found in fibers that also contained elevated Na and low K (Fig 3). Therefore, the possibility that these Ca-loaded mitochondria are indicative of cell damage remains to be ruled out.


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