Concurrent MORB-type and ultrapotassic volcanism in an extensional basin along the Laurentian Iapetus margin: Tectonomagmatic response to Ordovician arc-continent collision and subduction polarity flip

Arc-continent collision, followed by subduction polarity flip, occurs during closure of oceanic basins and contributes to the growth of continental crust. Such a setting may lead to a highly unusual association of ultrapotassic and mid-ocean ridge basalt (MORB)-type volcanic rocks as documented here from an Ordovician succession of the Scandinavian Caledonides. Interbedded with deep-marine turbidites, pillow basalts evolve from depleted-MORB (εNdt 9.4) to enriched-MORB (εNdt 4.8) stratigraphically upward, reflecting increasingly deeper melting of asthenospheric mantle. Intercalated intermediate to felsic lava and pyroclastic units, dated at ca. 474−469 Ma, are extremely enriched in incompatible trace elements (e.g., Th) and have low εNdt (−8.0 to −6.6) and high Sri (0.7089−0.7175). These are interpreted as ultrapotassic magmas derived from lithospheric mantle domains metasomatized by late Paleoproterozoic to Neoproterozoic crust-derived material (isotopic model ages 1.7−1.3 Ga). Detrital zircon spectra reveal a composite source for the interbedded turbidites, including Archean, Paleo-, to Neoproterozoic, and Cambro-Ordovician elements; clasts of Hølonda Porphyrite provide a link to the Hølonda terrane of Laurentian affinity. The entire volcano-sedimentary succession is interpreted to have formed in a rift basin that opened along the Laurentian margin as a result of slab rollback subsequent to arc-continent collision, ophiolite obduction and subduction polarity flip. The association of MORBs and ultrapotassic rocks is apparently a unique feature along the Caledonian-Appalachian orogen. Near-analogous modern settings include northern Taiwan and the Tyrrhenian region of the Mediterranean, but other examples of strictly concurrent MORB and ultrapotassic volcanism remain to be documented.

Lithostratigraphy and lithogeochemistry of Ediacaran alkaline basaltic rocks of the Musgravetown Group, Bonavista Peninsula, northeastern Newfoundland, Canada: an extensional volcanogenic basin in the type-Avalon terrane

Volcanic rocks of the Ediacaran Musgravetown Group on Bonavista Peninsula, Avalon terrane, Newfoundland, include basal ca. 600 Ma calc-alkaline basalt succeeded by continental tholeiite and alkaline rhyolite of the ca. 592 Ma Plate Cove volcanic belt (Bull Arm Formation), indicating a change from subduction-related to extensionrelated tectonic regimes during that interval. Alkalic basalts on northeastern (Dam Pond area) and southwestern (British Harbour area) Bonavista Peninsula occur below and above, respectively, the ca. 580 Ma glacial Trinity facies. Dam Pond basalt occurs in a structural dome intercalated with and flanked by fine-grained, siliciclastic deposits (Big Head Formation) overlain by Trinity facies. The British Harbour basalt occurs above the Trinity facies, in an upward- coarsening sandstone sequence (Rocky Harbour Formation) overlain by red beds of the Crown Hill Formation (uppermost Musgravetown Group). The Rocky Harbour and Big Head formations are likely stratigraphically interfingered proximal and distal deposits, respectively, derived from erosion of the Bull Arm Formation and older Avalonian assemblages.The Big Head basalts have lower SiO2, Zr, FeOT, P2O5, TiO2 and higher Mg#, Cr, V, Co and Ni contents, and are therefore more primitive than the more FeOT-, TiO2-, and P2O5-rich British Harbour basalts. Large-ionlithophile and rare-earth-element concentrations and ratios indicate that both suites originated from low degree partial melts of deep, weakly garnet-bearing, undepleted asthenospheric peridotite sources, with magma conduits likely focused along regional extensional faults. The protracted and episodic extension-related volcanic activity is consistent with a geodynamic setting that evolved from a mature arc into extensional basins with slowly waning magmatism, possibly involving slab rollback and delamination followed by magmatic underplating. The duration and variation of both volcanism and sedimentation indicate that the Musgravetown Group should be elevated to a Supergroup in order to facilitate future correlation of its constituent parts with other Avalonian basins.

West Antarctic mantle deduced from mafic magmatism

Distinct mantle compositions recorded in primitive West Antarctic magmatic rocks vary by tectonic setting and time. Deep asthenospheric mantle plume sources or shallow metasomatised mantle sources may operate either coincidently or independently to supply melts for magmatism. For example, contemporaneous subduction–plume dynamics produced the Ferrar-Karoo large igneous province; subduction-related melting followed by slab-rollback or melting of slab-hosted pyroxenite explains Antarctic Peninsula volcanism through time; Marie Byrd Land magmatism results from plume materials variably mixed with subduction modified mantle; while magmatism in Victoria Land and western Ross Sea is best explained by plate dynamics and melting of asthenospheric and metasomatised lithospheric sources and not by an upwelling plume. Element and isotopic ratios show a fundamental change between Marie Byrd Land and Victoria Land mantle domains. Specifically, Pb isotopes indicate that Victoria Land magmatism sources have a stronger focal zone (FOZO) mantle component while Marie Byrd Land magmatism possesses more of the HIMU mantle component. The chemical and isotopic heterogeneity of relatively unfractionated igneous rocks in West Antarctica reflects fundamental differences in mantle domains and melting conditions. This mantle variability coincides with changes in crustal structure and composition and has a geophysical signature that is manifest in seismic data and tomographic models.

Ediacaran initial subduction and Cambrian slab rollback of the Junggar Ocean: New evidence from igneous tectonic blocks and gabbro enclave in Early Palaeozoic accretionary complexes, southern West Junggar, NW China

New zircon U–Pb ages and whole-rock chemical data from four adakitic and two non-adakitic igneous rocks as tectonic blocks in the southern West Junggar accretionary complexes, northwestern China and one gabbro enclave in adakitic block provide further constraints on the initial subduction and following rollback process of the Junggar Ocean as part of southern Palaeo-Asian Ocean. The oldest adakitic monzonite in Tangbale is intruded by the non-adakitic quartz monzonite at 549 Ma, and the youngest adakitic diorite in Tierekehuola formed at 520 Ma. The Ediacaran–Cambrian magmatism show a N-wards younger trend. The high-SiO2 adakitic rocks have high Sr (300–663 ppm) and low Y (6.68–12.2 ppm), with Sr/Y = 40–84 and Mg no. = 46–60, whereas the non-adakitic rocks have high Y (13.2–22.7 ppm) and Yb (2.32–2.92 ppm), with Mg no. = 36–40. The gabbro has high MgO (14.81–15.11 wt%), Co (45–48 ppm), Cr (1120–1360 ppm) and Ni (231–288 ppm), with Mg no. = 72–73. All the samples show similar large-ion lithophile element (LILE) and light rare earth element (LREE) enrichment and Nb, Ta, Ti and varying Zr and Hf depletion, suggesting that they were formed in a subduction-related setting. The adakitic rocks were produced by partial melting of subducted oceanic slab, but the melts were modified by mantle wedge and slab-derived fluids; the non-adakitic rocks were likely derived from partial melts of the middle-lower arc crust; and the gabbro originated from the mantle wedge modified by slab-derived fluids. The magmatism could have been generated during the Ediacaran initial subduction and Cambrian slab rollback of the Junggar Ocean.