Exchange Dynamics of Typical Emerging and Legacy Persistent Organic Pollutants at the Air‐Water Interface Over a Strongly Human‐Influenced Large River Estuary

2020 ◽  
Vol 125 (13) ◽  
Author(s):  
Tianfeng Guo ◽  
Yuanyuan Li ◽  
Tian Lin ◽  
Zilan Wu ◽  
Yuqing Jiang ◽  
...  
Keyword(s):  
Organic Pollutants ◽  
Persistent Organic Pollutants ◽  
River Estuary ◽  
Large River ◽  
Water Interface ◽  
Air Water Interface

scholarly journals Dispersal of persistent organic pollutants from fiber-contaminated sediments: biotic and abiotic pathways

2021 ◽  
Author(s):  
Anna-Karin Dahlberg ◽  
Anna Apler ◽  
Paul Frogner-Kockum ◽  
Gunnel Göransson ◽  
Ian Snowball ◽  
...  
Keyword(s):  
Organic Pollutants ◽  
Persistent Organic Pollutants ◽  
River Estuary ◽  
Contaminated Sediments ◽  
The Body ◽  
Passive Samplers ◽  
The Other ◽  
Sediment Surface ◽  
Average Particle ◽  
Particle Resuspension

Abstract Purpose Numerous sites contaminated with fiber emissions from pulp and paper industries are found in coastal areas of the Baltic Sea, but there is limited knowledge about the magnitude of dispersal of persistent organic pollutants (POPs) from these anthropogenic, organic-rich sediments called fiberbanks. The aim of this study was to quantify and compare different POP dispersal pathways from such fiberbanks. Dispersal mechanisms studied included abiotic and biotic routes (dissolved in water, particle-bound, and bioaccumulation). Materials and methods Contaminated fibrous sediments located in Ångermanälven River estuary in north-eastern Sweden were studied in sediment types representing different fiber content (i.e., fiberbanks, fiber-rich sediments, and less fiber impacted sediments). Sediment-to-water fluxes of dissolved contaminants (polychlorinated biphenyls (PCBs), hexachlorobenzene (HCB), and dichlorodiphenyltrichloroethane (DDT)) were measured in situ using benthic flux chambers. Particle resuspension was measured by sampling bottom water, before and after disturbing the sediment surface. Benthic biota was collected to determine the body burden of contaminants and to determine biota-pore water accumulation factors (BAFPW) and biota-sediment accumulation factors (BSAFs). In addition, concentrations of dissolved POPs in the water column were measured in field using passive samplers. Instrumental analysis was performed using gas chromatography coupled to a triple quadrupole mass spectrometer (GC-MS/MS). Results and discussion The flux of dissolved Σ20PCBs was approximately two times higher from one of the investigated fiberbanks (3.4 ng m− 2 day− 1) compared to the other. The average particle burden of PCBs was also higher at this fiberbank after artificial disturbance (15 ng g−1 particle), which indicates that larger amounts of contaminants are likely to disperse via particle resuspension from this site compared to the other fiberbank (4.8 ng g− 1 particle). The difference might be associated with a layer of recently settled minerogenic material that covers one of the fiberbanks, which probably functions as a protective barrier. The lack of benthic biota implies that contaminant release by bioturbation is negligible in the studied fiberbanks. However, benthic biota from fiber-rich sediment showed bioaccumulation and biomagnification of contaminants. Conclusions The importance of diffusive flux from fiberbanks under undisturbed conditions became apparent when the different dispersal pathways were quantified. However, no dispersal pathway could be judged as irrelevant, since even under undisturbed conditions, advective particle transport was significant. Additionally, the uptake by biota and trophic transfer can be considerable. Quantification of dispersal routes and understanding of the relative importance of various pathways is critical for proper risk assessment and management of contaminated sediments.

Air-Water Interface Photocatalysis: A Realizable Approach for Decomposition of Aqueous Organic Pollutants

2013 ◽  
Vol 5 (8) ◽  
pp. 1006-1012 ◽  
Author(s):  
Sheng Wang ◽  
Tao Wang ◽  
Yuanwei Ding ◽  
Qiying Su ◽  
Youfeng Xu ◽  
...  
Keyword(s):  
Organic Pollutants ◽  
Water Interface ◽  
Air Water Interface

Heavy metals and persistent organic pollutants contamination in river, estuary, and marine sediments from Atlantic Coast of Democratic Republic of the Congo

2020 ◽  
Vol 27 (16) ◽  
pp. 20000-20013
Author(s):  
Robert Bueya Suami ◽  
Periyasamy Sivalingam ◽  
Dhafer Mohammed Al Salah ◽  
Dominique Grandjean ◽  
Crispin Kyela Mulaji ◽  
...  
Keyword(s):  
Heavy Metals ◽  
Organic Pollutants ◽  
Marine Sediments ◽  
Persistent Organic Pollutants ◽  
Democratic Republic ◽  
Atlantic Coast ◽  
River Estuary ◽  
Republic Of The Congo

Sampling and analysis of the air-water interface with SEM and EDS of microlayers

1989 ◽  
Vol 47 ◽  
pp. 1004-1005
Author(s):  
Randall W. Smith ◽  
John Dash
Keyword(s):  
Heavy Metals ◽  
Surface Microlayer ◽  
Surface Films ◽  
Water Interface ◽  
Physical Processes ◽  
Infrared Spectroscopic Analysis ◽  
Eds Analysis ◽  
Air Water Interface ◽  
Significant Area ◽  
Bulk Chemical

The structure of the air-water interface forms a boundary layer that involves biological ,chemical geological and physical processes in its formation. Freshwater and sea surface microlayers form at the air-water interface and include a diverse assemblage of organic matter, detritus, microorganisms, plankton and heavy metals. The sampling of microlayers and the examination of components is presently a significant area of study because of the input of anthropogenic materials and their accumulation at the air-water interface. The neustonic organisms present in this environment may be sensitive to the toxic components of these inputs. Hardy reports that over 20 different methods have been developed for sampling of microlayers, primarily for bulk chemical analysis. We report here the examination of microlayer films for the documentation of structure and composition.Baier and Gucinski reported the use of Langmuir-Blogett films obtained on germanium prisms for infrared spectroscopic analysis (IR-ATR) of components. The sampling of microlayers has been done by collecting fi1ms on glass plates and teflon drums, We found that microlayers could be collected on 11 mm glass cover slips by pulling a Langmuir-Blogett film from a surface microlayer. Comparative collections were made on methylcel1ulose filter pads. The films could be air-dried or preserved in Lugol's Iodine Several slicks or surface films were sampled in September, 1987 in Chesapeake Bay, Maryland and in August, 1988 in Sequim Bay, Washington, For glass coverslips the films were air-dried, mounted on SEM pegs, ringed with colloidal silver, and sputter coated with Au-Pd, The Langmuir-Blogett film technique maintained the structure of the microlayer intact for examination, SEM observation and EDS analysis were then used to determine organisms and relative concentrations of heavy metals, using a Link AN 10000 EDS system with an ISI SS40 SEM unit. Typical heavy microlayer films are shown in Figure 3.

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