scholarly journals Clays are not created equal: How clay mineral type affects soil parameterization

Author(s):  
P. Lehmann ◽  
B. Leshchinsky ◽  
S. Gupta ◽  
B.B. Mirus ◽  
S. Bickel ◽  
...  
Keyword(s):  
Minerals ◽  
2020 ◽  
Vol 10 (12) ◽  
pp. 1064
Author(s):  
Masanori Kohno

Considering the relevance of clay mineral-bearing geomaterials in landslide/mass movement hazard assessment, various engineering projects for resource development, and stability evaluation of underground space utilization, it is important to understand the permeability of these clay mineral-based geomaterials. However, only a few quantitative data have been reported to date regarding the effects of the clay mineral type and hydraulic gradient on the permeability of clay mineral materials. This study was conducted to investigate the permeability of clay mineral materials based on the clay mineral type, under different hydraulic gradient conditions, through a constant-pressure permeability test. Comparative tests have revealed that the difference in the types of clay mineral influences the swelling pressure and hydraulic conductivity. In addition, it has been found that the difference in water pressure (hydraulic gradient) affects the hydraulic conductivity of clay mineral materials. The hydraulic conductivity has been found to be closely associated with the specific surface area of the clay mineral material. Furthermore, the hydraulic conductivity value measured is almost consistent with the value calculated theoretically using the Kozeny–Carman equation. Moreover, the hydraulic conductivity is also found to be closely associated with the hydrogen energy, calculated from the consistency index of clay. This result suggests that the hydraulic conductivity of clay mineral materials can be estimated based on the specific surface area and void ratio, or consistency index of clay.


2020 ◽  
Vol 44 (7) ◽  
pp. 2966-2979
Author(s):  
Jahaziel Amaya ◽  
Natalia Suarez ◽  
Andrés Moreno ◽  
Sonia Moreno ◽  
Rafael Molina

A clay mineral-type modified bentonite, produced via delamination and subsequent incorporation of AlZr and AlCe species to modulate their acid properties, was used to obtain bifunctional catalysts with the incorporation of NiMo, CoMo, NiW and CoW.


2021 ◽  
Author(s):  
Peter Lehmann ◽  
Ben Leshchinsky ◽  
Surya Gupta ◽  
Ben Mirus ◽  
Samuel Bickel ◽  
...  

<p>Clay minerals dominate the soil colloidal fraction and often carry the largest specific surface area – a property that controls various soil hydraulic and mechanical properties (SHMPs; e.g. water retention, permeability, and internal friction). Differences in microscale structure among clay mineral types in tropical and temperate regions affect the specific surface area and result in higher permeability and internal friction angle values for tropical soils with inactive kaolinite clay minerals. Presently, the soil clay size fraction used to parameterize SHMPs with pedotransfer functions (PTFs) ignores clay mineral type, leading to inconsistent parameter representation. In this study, we present new PTFs informed by clay minerals, enabling enhanced estimation of friction angle and saturated hydraulic conductivity. To capture higher conductivity and lower air entry values in tropical soils, we developed a hierarchical packing model and validated this new PTF approach using literature data from various tropical regions. We leveraged recent global maps of clay minerals to demonstrate that a strong climatic and spatial segregation of active and inactive clays enable spatially resolved consideration of clay mineral type in SHMP estimation. We applied these clay-informed PTFs to improve SHMP representation regionally with implications for a wide range of hydrological and geomechanical Earth surface processes.</p>


2013 ◽  
Author(s):  
Tongwei Zhang ◽  
Geoffrey S. Ellis ◽  
Stephen C. Ruppel ◽  
Kitty Milliken ◽  
Mike Lewan ◽  
...  

Clay Minerals ◽  
2018 ◽  
Vol 53 (4) ◽  
pp. 721-732 ◽  
Author(s):  
Masanori Kohno ◽  
Yoshitaka Nara ◽  
Masaji Kato ◽  
Tsuyoshi Nishimura

ABSTRACTClay-mineral type and content, bulk mineralogical composition and alteration of bentonite are very important factors for the ultra-long-term stabilization of barriers and backfills in radioactive waste disposal. This study investigates the effects of clay-mineral type and content on the swelling characteristics and permeability of bentonite–sand mixtures with clay minerals using one-dimensional swelling-pressure and constant-pressure permeability tests. The hydraulic conductivity of bentonite–sand–clay mineral mixtures increased with increasing content of non-swelling alteration products of montmorillonite. Furthermore, hydraulic conductivity was comparable to that determined with the Kozeny–Carman equation for a specific surface area, suggesting that hydraulic conductivity may be estimated based on the abundance of expected alteration products of montmorillonite. This study provides a basis for evaluation of the hydraulic conductivity of bentonite–sand mixtures with known quantities of expected alteration products of montmorillonite.


2014 ◽  
Vol 468-469 ◽  
pp. 302-305 ◽  
Author(s):  
Fiona P. Brennan ◽  
Emma Moynihan ◽  
Bryan S. Griffiths ◽  
Stephen Hillier ◽  
Jason Owen ◽  
...  
Keyword(s):  

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