scholarly journals Compact prototype microfabricated gas chromatographic analyzer for autonomous determinations of VOC mixtures at typical workplace concentrations

2018 ◽  
Vol 4 (1) ◽  
Author(s):  
Junqi Wang ◽  
Jonathan Bryant-Genevier ◽  
Nicolas Nuñovero ◽  
Chengyi Zhang ◽  
Bruce Kraay ◽  
...  
Keyword(s):  
2006 ◽  
Vol 65 (3-4) ◽  
pp. 191-200 ◽  
Author(s):  
José I. Gutiérrez-Ortiz ◽  
Beatriz de Rivas ◽  
Rubén López-Fonseca ◽  
Juan R. González-Velasco
Keyword(s):  

2012 ◽  
Vol 12 (2) ◽  
pp. 1021-1030 ◽  
Author(s):  
A. Kiendler-Scharr ◽  
S. Andres ◽  
M. Bachner ◽  
K. Behnke ◽  
S. Broch ◽  
...  

Abstract. Stress-induced volatile organic compound (VOC) emissions from transgenic Grey poplar modified in isoprene emission potential were used for the investigation of photochemical secondary organic aerosol (SOA) formation. In poplar, acute ozone stress induces the emission of a wide array of VOCs dominated by sesquiterpenes and aromatic VOCs. Constitutive light-dependent emission of isoprene ranged between 66 nmol m−2 s−1 in non-transgenic controls (wild type WT) and nearly zero (<0.5 nmol m−2 s−1) in isoprene emission-repressed plants (line RA22), respectively. Nucleation rates of up to 3600 cm−3 s−1 were observed in our experiments. In the presence of isoprene new particle formation was suppressed compared to non-isoprene containing VOC mixtures. Compared to isoprene/monoterpene systems emitted from other plants the suppression of nucleation by isoprene was less effective for the VOC mixture emitted from stressed poplar. This is explained by the observed high efficiency of new particle formation for emissions from stressed poplar. Direct measurements of OH in the reaction chamber revealed that the steady state concentration of OH is lower in the presence of isoprene than in the absence of isoprene, supporting the hypothesis that isoprenes' suppressing effect on nucleation is related to radical chemistry. In order to test whether isoprene contributes to SOA mass formation, fully deuterated isoprene (C5D8) was added to the stress-induced emission profile of an isoprene free poplar mutant. Mass spectral analysis showed that, despite the isoprene-induced suppression of particle formation, fractions of deuterated isoprene were incorporated into the SOA. A fractional mass yield of 2.3% of isoprene was observed. Future emission changes due to land use and climate change may therefore affect both gas phase oxidation capacity and new particle number formation.


2021 ◽  
Vol 10 (1) ◽  
pp. 44
Author(s):  
Bhargavi Mahesh ◽  
Teresa Scholz ◽  
Jana Streit ◽  
Thorsten Graunke ◽  
Sebastian Hettenkofer

Metal oxide (MOX) sensors offer a low-cost solution to detect volatile organic compound (VOC) mixtures. However, their operation involves time-consuming heating cycles, leading to a slower data collection and data classification process. This work introduces a few-shot learning approach that promotes rapid classification. In this approach, a model trained on several base classes is fine-tuned to recognize a novel class using a small number (n = 5, 25, 50 and 75) of randomly selected novel class measurements/shots. The used dataset comprises MOX sensor measurements of four different juices (apple, orange, currant and multivitamin) and air, collected over 10-minute phases using a pulse heater signal. While high average accuracy of 82.46 is obtained for five-class classification using 75 shots, the model’s performance depends on the juice type. One-shot validation showed that not all measurements within a phase are representative, necessitating careful shot selection to achieve high classification accuracy. Error analysis revealed contamination of some measurements by the previously measured juice, a characteristic of MOX sensor data that is often overlooked and equivalent to mislabeling. Three strategies are adopted to overcome this: (E1) and (E2) fine-tuning after dropping initial/final measurements and the first half of each phase, respectively, (E3) pretraining with data from the second half of each phase. Results show that each of the strategies performs best for a specific number of shots. E3 results in the highest performance for five-shot learning (accuracy 63.69), whereas E2 yields the best results for 25-/50-shot learning (accuracies 79/87.1) and E1 predicts best for 75-shot learning (accuracy 88.6). Error analysis also showed that, for all strategies, more than 50% of air misclassifications resulted from contamination, but E1 was affected the least. This work demonstrates how strongly data quality can affect prediction performance, especially for few-shot classification methods, and that a data-centric approach can improve the results.


2021 ◽  
pp. 131678
Author(s):  
Wenjun Wang ◽  
Fawei Lin ◽  
Taicheng An ◽  
Saixi Qiu ◽  
Hongdi Yu ◽  
...  

2002 ◽  
Vol 38 (4) ◽  
pp. 251-258 ◽  
Author(s):  
Nerea Burgos ◽  
Marı́a Paulis ◽  
M. Mirari Antxustegi ◽  
Mario Montes
Keyword(s):  

Author(s):  
B. C. Baltzis ◽  
C. J. Mpanias ◽  
S. Bhattacharya

2012 ◽  
Vol 12 (2) ◽  
pp. 6049-6084 ◽  
Author(s):  
J. P. DiGangi ◽  
S. B. Henry ◽  
A. Kammrath ◽  
E. S. Boyle ◽  
L. Kaser ◽  
...  

Abstract. We present simultaneous fast, in-situ measurements of formaldehyde and glyoxal from two rural campaigns, BEARPEX 2009 and BEACHON-ROCS, both located in Pinus Ponderosa forests with emissions dominated by biogenic volatile organic compounds (VOCs). Despite considerable variability in the formaldehyde and glyoxal concentrations, the ratio of glyoxal to formaldehyde, RGF, displayed a very regular diurnal cycle over nearly 2 weeks of measurements. The only deviations in RGF were toward higher values and were the result of a biomass burning event during BEARPEX 2009 and very fresh anthropogenic influence during BEACHON-ROCS. Other rapid changes in glyoxal and formaldehyde concentrations have hardly any affect on RGF and could reflect transitions between low and high NO regimes. The trend of increased RGF from both anthropogenic reactive VOC mixtures and biomass burning compared to biogenic reactive VOC mixtures is robust due to the short timescales over which the observed changes in RGF occurred. Satellite retrievals, which suggest higher RGF for biogenic areas, are in contrast to our observed trends. It remains important to address this discrepancy, especially in view of the importance of satellite retrievals and in-situ measurements for model comparison. In addition, we propose that RGF, together with the absolute concentrations of glyoxal and formaldehyde, represents a useful metric for biogenic or anthropogenic reactive VOC mixtures. In particular, RGF yields information about not simply the VOCs in an airmass, but the VOC processing that directly couples ozone and secondary organic aerosol production.


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