scholarly journals Manipulating interstitial carbon atoms in the nickel octahedral site for highly efficient hydrogenation of alkyne

2020 ◽  
Vol 11 (1) ◽  
Author(s):  
Yiming Niu ◽  
Xing Huang ◽  
Yongzhao Wang ◽  
Ming Xu ◽  
Junnan Chen ◽  
...  
Author(s):  
M.J. Witcomb ◽  
M.A. O'Keefe ◽  
CJ. Echer ◽  
C. Nelson ◽  
J.H. Turner ◽  
...  

Under normal circumstances, Pt dissolves only a very small amount of interstitial carbon in solid solution. Even so, an appropriate quench/age treatment leads to the formation of stable Pt2C {100} plate precipitates. Excess (quenched-in) vacancies play a critical role in the process by accommodating the volume and structural changes that accompany the transformation. This alloy system exhibits other interesting properties. Due to a large vacancy/carbon atom binding energy, Pt can absorb excess carbon at high temperatures in a carburizing atmosphere. In regions rich in carbon and vacancies, another carbide phase, Pt7C which undergoes an order-disorder reaction was formed. The present study of Pt carburized at 1160°C and aged at 515°C shows that other carbides in the PtxC series can be produced.


2020 ◽  
Vol 56 (27) ◽  
pp. 3851-3854 ◽  
Author(s):  
Xiaomin Chai ◽  
Hai-Hua Huang ◽  
Huiping Liu ◽  
Zhuofeng Ke ◽  
Wen-Wen Yong ◽  
...  

A Co-based complex displayed the highest photocatalytic performance for CO2 to CO conversion in aqueous media.


Nanoscale ◽  
2020 ◽  
Vol 12 (30) ◽  
pp. 16136-16142
Author(s):  
Xuan Wang ◽  
Ming-Jie Dong ◽  
Chuan-De Wu

An effective strategy to incorporate accessible metalloporphyrin photoactive sites into 2D COFs by establishing a 3D local connection for highly efficient photocatalysis was developed.


2010 ◽  
Vol E93-C (8) ◽  
pp. 1323-1332 ◽  
Author(s):  
Tsunayuki YAMAMOTO ◽  
Kazuhiro FUJIMORI ◽  
Minoru SANAGI ◽  
Shigeji NOGI
Keyword(s):  

2008 ◽  
Vol 67 (7) ◽  
pp. 645-653
Author(s):  
L. P. Shuba ◽  
M. V. Kirichenko ◽  
V. R. Kopach ◽  
V. A. Antonova ◽  
A. M. Listratenko

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