scholarly journals Highly efficient and air-stable Eu(II)-containing azacryptates ready for organic light-emitting diodes

2020 ◽  
Vol 11 (1) ◽  
Author(s):  
Jiayi Li ◽  
Liding Wang ◽  
Zifeng Zhao ◽  
Boxun Sun ◽  
Ge Zhan ◽  
...  

Abstract Divalent europium 5d-4f transition has aroused great attention in many fields, in a way of doping Eu2+ ions into inorganic solids. However, molecular Eu2+ complexes with 5d-4f transition are thought to be too air-unstable to explore their applications. In this work, we synthesized four Eu2+-containing azacryptates EuX2-Nn (X = Br, I, n = 4, 8) and systematically studied the photophysical properties in crystalline samples and solutions. Intriguingly, the EuX2-N8 complexes exhibit near-unity photoluminescence quantum yield, good air-/thermal-stability and mechanochromic property (X = I). Furthermore, we proved the application of Eu2+ complexes in organic light-emitting diodes (OLEDs) with high efficiency and luminance. The optimized device employing EuI2-N8 as emitter has the best performance as the maximum luminance, current efficiency, and external quantum efficiency up to 25470 cd m−2, 62.4 cd A−1, and 17.7%, respectively. Our work deepens the understanding of structure-property relationship in molecular Eu2+ complexes and could inspire further research on application in OLEDs.

2016 ◽  
Vol 4 (19) ◽  
pp. 4226-4235 ◽  
Author(s):  
Zhen Zhang ◽  
Jingwei Xie ◽  
Zixing Wang ◽  
Bowen Shen ◽  
Hedan Wang ◽  
...  

Structure–property relationship of pyridine-modified δ-carboline derivatives as bipolar hosts for highly efficient blue OLED.


2017 ◽  
Vol 5 (28) ◽  
pp. 6989-6996 ◽  
Author(s):  
Junming Li ◽  
Shou-Cheng Dong ◽  
Andreas Opitz ◽  
Liang-Sheng Liao ◽  
Norbert Koch

Host materials for modern high-efficiency organic light-emitting diodes (OLEDs) based on phosphorescence and thermally activated delayed fluorescence were optimized with respect to thermal stability, photophysical properties, energy levels, and charge carrier transport.


2017 ◽  
Vol 5 (16) ◽  
pp. 3869-3897 ◽  
Author(s):  
Cyril Poriel ◽  
Joëlle Rault-Berthelot

The aim of the present review is to report the state of the art of an emerging family of molecules, namely 4-substituted spirobifluorenes (SBFs).


2021 ◽  
Vol 15 (3) ◽  
pp. 208-215 ◽  
Author(s):  
Soon Ok Jeon ◽  
Kyung Hyung Lee ◽  
Jong Soo Kim ◽  
Soo-Ghang Ihn ◽  
Yeon Sook Chung ◽  
...  

2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Maria Vasilopoulou ◽  
Abd. Rashid bin Mohd Yusoff ◽  
Matyas Daboczi ◽  
Julio Conforto ◽  
Anderson Emanuel Ximim Gavim ◽  
...  

AbstractBlue organic light-emitting diodes require high triplet interlayer materials, which induce large energetic barriers at the interfaces resulting in high device voltages and reduced efficiencies. Here, we alleviate this issue by designing a low triplet energy hole transporting interlayer with high mobility, combined with an interface exciplex that confines excitons at the emissive layer/electron transporting material interface. As a result, blue thermally activated delay fluorescent organic light-emitting diodes with a below-bandgap turn-on voltage of 2.5 V and an external quantum efficiency (EQE) of 41.2% were successfully fabricated. These devices also showed suppressed efficiency roll-off maintaining an EQE of 34.8% at 1000 cd m−2. Our approach paves the way for further progress through exploring alternative device engineering approaches instead of only focusing on the demanding synthesis of organic compounds with complex structures.


2011 ◽  
Vol 12 (5) ◽  
pp. 843-850 ◽  
Author(s):  
Chao Cai ◽  
Shi-Jian Su ◽  
Takayuki Chiba ◽  
Hisahiro Sasabe ◽  
Yong-Jin Pu ◽  
...  

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