scholarly journals Quantifying Concentration Polarization – Raman Microspectroscopy for In-Situ Measurement in a Flat Sheet Cross-flow Nanofiltration Membrane Unit

2019 ◽  
Vol 9 (1) ◽  
Author(s):  
Oliver Jung ◽  
Florencia Saravia ◽  
Michael Wagner ◽  
Stefan Heißler ◽  
Harald Horn
Keyword(s):  
Concentration Polarization ◽  
Cross Flow ◽  
Raman Microspectroscopy ◽  
Channel Height ◽  
Concentration Profiles ◽  
Operating Pressure ◽  
Membrane Unit ◽  
Lower Velocity ◽  
Flat Sheet

Abstract In this work, the concentration polarization layer (CPL) of sulphate in a cross-flow membrane system was measured in-situ using Raman microspectroscopy (RM). The focus of this work is to introduce RM as a new tool for the study of mass transfer inside membrane channels in reverse osmosis (RO) and nanofiltration (NF) generally. Specifically, this work demonstrates how to use RM for locally resolved measurement of sulphate concentration in a cross-flow flat-sheet NF membrane flow cell with channel dimensions similar to commonly applied RO/NF spiral wound modules (channel height about 0.7 mm). Concentration polarization profiles of an aqueous magnesium sulphate solution of 10 gsulphate·L−1 were obtained at operating pressure of 10 bar and cross-flow velocities of 0.04 and 0.2 m·s−1. The ability of RM to provide accurate concentration profiles is discussed thoroughly. Optical effects due to refraction present one of the main challenges of the method by substantially affecting signal intensity and depth resolution. The concentration profiles obtained in this concept study are consistent with theory and show reduced CPL thickness and membrane wall concentration with increasing cross-flow velocity. The severity of CP was quantified to reach almost double the bulk concentration at the lower velocity.

In Situ Characterization by SAXS of Concentration Polarization Layers during Cross-Flow Ultrafiltration of Laponite Dispersions

Langmuir ◽  
2011 ◽  
Vol 28 (2) ◽  
pp. 1083-1094 ◽  
Author(s):  
F. Pignon ◽  
M. Abyan ◽  
C. David ◽  
A. Magnin ◽  
M. Sztucki
Keyword(s):  
Concentration Polarization ◽  
Cross Flow ◽  
In Situ Characterization

Microbial ecology of sulfate-reducing bacteria in wastewater biofilms analyzed by microelectrodes and fish (fluorescent in situ hybridization) technique

1999 ◽  
Vol 39 (7) ◽  
pp. 41-47 ◽  
Author(s):  
Satoshi Okabe ◽  
Hisashi Satoh ◽  
Tsukasa Itoh ◽  
Yoshimasa Watanabe
Keyword(s):  
In Situ Hybridization ◽  
Sulfate Reduction ◽  
Sulfate Reducing Bacteria ◽  
Hybridization Technique ◽  
Concentration Profiles ◽  
Reduction Zone ◽  
Sulfate Reducing ◽  
Reducing Bacteria ◽  
Culture Dependent

The vertical distribution of sulfate-reducing bacteria (SRB) in microaerophilic wastewater biofilms grown on fully submerged rotating disk reactors (RDR) was determined by the conventional culture-dependent MPN method and in situ hybridization of fluorescently-labelled 16S rRNA-targeted oligonucleotide probes for SRB in parallel. Chemical concentration profiles within the biofilm were also measured using microelectrodes for O2, S2-, NO3- and pH. In situ hybridization revealed that the SRB probe-stained cells were distributed throughout the biofilm even in the oxic surface zone in all states from single scattered cells to clustered cells. The higher fluorescence intensity and abundance of SRB probe-stained cells were found in the middle part of the biofilm. This result corresponded well with O2 and H2S concentration profiles measured by microelectrodes, showing sulfate reduction was restricted to a narrow anaerobic zone located about 500 μm below the biofilm surface. Results of the MPN and potential sulfate reducing activity (culture-dependent approaches) indicated a similar distribution of cultivable SRB in the biofilm. The majority of the general SRB probe-stained cells were hybridized with SRB 660 probe, suggesting that one important member of the SRB in the wastewater biofilm could be the genus Desulfobulbus. An addition of nitrate forced the sulfate reduction zone deeper in the biofilm and reduced the specific sulfate reduction rate as well. The sulfate reduction zone was consequently separated from O2 and NO3- respiration zones. Anaerobic H2S oxidation with NO3- was also induced by addition of nitrate to the medium.

scholarly journals Impact of FO Operating Pressure and Membrane Tensile Strength on Draw-Channel Geometry and Resulting Hydrodynamics

Membranes ◽  
2020 ◽  
Vol 10 (5) ◽  
pp. 111
Author(s):  
Alexander J. Charlton ◽  
Boyue Lian ◽  
Gaetan Blandin ◽  
Greg Leslie ◽  
Pierre Le-Clech
Keyword(s):  
Fluid Dynamics ◽  
Computational Fluid Dynamics ◽  
Reynolds Number ◽  
Shear Rate ◽  
Membrane Surface ◽  
Forward Osmosis ◽  
Transmembrane Pressure ◽  
Channel Height ◽  
Operating Pressure ◽  
Channel Geometry

In an effort to improve performances of forward osmosis (FO) systems, several innovative draw spacers have been proposed. However, the small pressure generally applied on the feed side of the process is expected to result in the membrane bending towards the draw side, and in the gradual occlusion of the channel. This phenomenon potentially presents detrimental effects on process performance, including pressure drop and external concentration polarization (ECP) in the draw channel. A flat sheet FO system with a dot-spacer draw channel geometry was characterized to determine the degree of draw channel occlusion resulting from feed pressurization, and the resulting implications on flow performance. First, tensile testing was performed on the FO membrane to derive a Young’s modulus, used to assess the membrane stretching, and the resulting draw channel characteristics under a range of moderate feed pressures. Membrane apex reached up to 67% of the membrane channel height when transmembrane pressure (TMP) of 1.4 bar was applied. The new FO channels considerations were then processed by computational fluid dynamics model (computational fluid dynamics (CFD) by ANSYS Fluent v19.1) and validated against previously obtained experimental data. Further simulations were conducted to better assess velocity profiles, Reynolds number and shear rate. Reynolds number on the membrane surface (draw side) increased by 20% and shear rate increased by 90% when occlusion changed from 0 to 70%, impacting concentration polarisation (CP) on the membrane surface and therefore FO performance. This paper shows that FO draw channel occlusion is expected to have a significant impact on fluid hydrodynamics when the membrane is not appropriately supported in the draw side.

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