scholarly journals Phlogopite-pargasite coexistence in an oxygen reduced spinel-peridotite ambient

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Costanza Bonadiman ◽  
Valentina Brombin ◽  
Giovanni B. Andreozzi ◽  
Piera Benna ◽  
Massimo Coltorti ◽  
...  
Keyword(s):  
Oxygen Fugacity ◽  
Upper Mantle ◽  
Mantle Xenoliths ◽  
Spinel Peridotite ◽  
Simultaneous Formation ◽  
Empirical Potentials ◽  
Elastic Data ◽  
Mineralogical Study ◽  
Semi Empirical ◽  
T Locus

AbstractThe occurrence of phlogopite and amphibole in mantle ultramafic rocks is widely accepted as the modal effect of metasomatism in the upper mantle. However, their simultaneous formation during metasomatic events and the related sub-solidus equilibrium with the peridotite has not been extensively studied. In this work, we discuss the geochemical conditions at which the pargasite-phlogopite assemblage becomes stable, through the investigation of two mantle xenoliths from Mount Leura (Victoria State, Australia) that bear phlogopite and the phlogopite + amphibole (pargasite) pair disseminated in a harzburgite matrix. Combining a mineralogical study and thermodynamic modelling, we predict that the P–T locus of the equilibrium reaction pargasite + forsterite = Na-phlogopite + 2 diopside + spinel, over the range 1.3–3.0 GPa/540–1500 K, yields a negative Clapeyron slope of -0.003 GPa K–1 (on average). The intersection of the P–T locus of supposed equilibrium with the new mantle geotherm calculated in this work allowed us to state that the Mount Leura xenoliths achieved equilibrium at 2.3 GPa /1190 K, that represents a plausible depth of ~ 70 km. Metasomatic K-Na-OH rich fluids stabilize hydrous phases. This has been modelled by the following equilibrium equation: 2 (K,Na)-phlogopite + forsterite = 7/2 enstatite + spinel + fluid (components: Na2O,K2O,H2O). Using quantum-mechanics, semi-empirical potentials, lattice dynamics and observed thermo-elastic data, we concluded that K-Na-OH rich fluids are not effective metasomatic agents to convey alkali species across the upper mantle, as the fluids are highly reactive with the ultramafic system and favour the rapid formation of phlogopite and amphibole. In addition, oxygen fugacity estimates of the Mount Leura mantle xenoliths [Δ(FMQ) = –1.97 ± 0.35; –1.83 ± 0.36] indicate a more reducing mantle environment than what is expected from the occurrence of phlogopite and amphibole in spinel-bearing peridotites. This is accounted for by our model of full molecular dissociation of the fluid and incorporation of the O-H-K-Na species into (OH)-K-Na-bearing mineral phases (phlogopite and amphibole), that leads to a peridotite metasomatized ambient characterized by reduced oxygen fugacity.

scholarly journals Water contents of nominally anhydrous orthopyroxenes from oceanic peridotites determined by SIMS and FTIR

2021 ◽  
Author(s):  
Kirsten T. Wenzel ◽  
Michael Wiedenbeck ◽  
Jürgen Gose ◽  
Alexander Rocholl ◽  
Esther Schmädicke
Keyword(s):  
Upper Mantle ◽  
Secondary Ion Mass Spectrometry ◽  
Spinel Peridotite ◽  
Structural Water ◽  
Major Element Composition ◽  
Mantle Peridotites ◽  
History Of ◽  
Polarized Ftir ◽  
Water Contents ◽  
Forearc Region

AbstractThis study presents new secondary ion mass spectrometry (SIMS) reference materials (RMs) for measuring water contents in nominally anhydrous orthopyroxenes from upper mantle peridotites. The enstatitic reference orthopyroxenes from spinel peridotite xenoliths have Mg#s between 0.83 and 0.86, Al2O3 ranges between 4.02 and 5.56 wt%, and Cr2O3 ranges between 0.21 and 0.69 wt%. Based on Fourier-transform infrared spectroscopy (FTIR) characterizations, the water contents of the eleven reference orthopyroxenes vary from dry to 249 ± 6 µg/g H2O. Using these reference grains, a set of orthopyroxene samples obtained from variably altered abyssal spinel peridotites from the Atlantic and Arctic Ridges as well as from the Izu-Bonin-Mariana forearc region was analyzed by SIMS and FTIR regarding their incorporation of water. The major element composition of the sample orthopyroxenes is typical of spinel peridotites from the upper mantle, characterized by Mg#s between 0.90 and 0.92, Al2O3 between 1.66 and 5.34 wt%, and Cr2O3 between 0.62 and 0.96 wt%. Water contents as measured by SIMS range from 68 ± 7 to 261 ± 11 µg/g H2O and correlate well with Al2O3 contents (r = 0.80) and Cr#s (r. = -0.89). We also describe in detail an optimized strategy, employing both SIMS and FTIR, for quantifying structural water in highly altered samples such as abyssal peridotite. This approach first analyzes individual oriented grains by polarized FTIR, which provides an overview of alteration. Subsequently, the same grain along with others of the same sample is measured using SIMS, thereby gaining information about homogeneity at the hand sample scale, which is key for understanding the geological history of these rocks.

Fluid inclusions in upper mantle xenoliths from Northern Patagonia, Argentina: Evidence for an upper mantle diapir

1997 ◽  
Vol 60 (3-4) ◽  
pp. 145-164 ◽  
Author(s):  
M. E. Varela ◽  
E. A. Bjerg ◽  
R. Clocchiatti ◽  
C. H. Labudia ◽  
G. Kurat
Keyword(s):  
Fluid Inclusions ◽  
Upper Mantle ◽  
Mantle Xenoliths ◽  
Northern Patagonia ◽  
Mantle Diapir

Petrology of ultramafic xenoliths from Rayfield River, south-central British Columbia

1987 ◽  
Vol 24 (8) ◽  
pp. 1679-1687 ◽  
Author(s):  
Dante Canil ◽  
Mark Brearley ◽  
Christopher M. Scarfe
Keyword(s):  
British Columbia ◽  
Phase Equilibrium ◽  
Partial Melting ◽  
Upper Mantle ◽  
Mantle Xenoliths ◽  
Spinel Lherzolite ◽  
Equilibrium Constraints ◽  
Host Magma ◽  
South Central ◽  
Ultramafic Xenoliths

One hundred mantle xenoliths were collected from a hawaiite flow of Miocene–Pliocene age near Rayfield River, south-central British Columbia. The massive host hawaiite contains subrounded xenoliths that range in size from 1 to 10 cm and show protogranular textures. Both Cr-diopside-bearing and Al-augite-bearing xenoliths are represented. The Cr-diopside-bearing xenolith suite consists of spinel lherzolite (64%), dunite (12%), websterite (12%), harzburgite (9%), and olivine websterite (3%). Banding and veining on a centimetre scale are present in four xenoliths. Partial melting at the grain boundaries of clinopyroxene is common and may be due to natural partial melting in the upper mantle, heating by the host magma during transport, or decompression during ascent.Microprobe analyses of the constituent minerals show that most of the xenoliths are well equilibrated. Olivine is Fo89 to Fo92, orthopyroxene is En90, and Cr diopside is Wo47En48Fs5. More Fe-rich pyroxene compositions are present in some of the websterite xenoliths. The Mg/(Mg + Fe2+) and Cr/(Cr + Al + Fe3+) ratios in spinel are uniform in individual xenoliths, but they vary from xenolith to xenolith. Equilibration temperatures for the xenoliths are 860–980 °C using the Wells geothermometer. The depth of equilibration estimated for the xenoliths using geophysical and phase equilibrium constraints is 30–40 km.

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