Molecular Structures of Gellan Gum Imaged with Atomic Froce Microscopy (AFM) in Relation to the Rheological Behavior in an Aqueous Systems. Gellan Gum with Various Acyl Contents in the Presence or Absence of Potassium

2013 ◽  
Vol 284-287 ◽  
pp. 20-24 ◽  
Author(s):  
Yue Cheng Meng ◽  
Lun Bo Hong ◽  
Jian Qiu Jin

The effects of gellan gum and calcium ions concentration on gelation characteristics and rheological behavior were investigated using TA(texture analysis)and mechanical rheometer which monitored respectively press strength and the evolution of G′. At a premium gellan gum content of 0.02g in 100ml buffer solution, increasing calcium ions concentration led to an increase in the gelation strength, but when calcium ions content reached a critical concentration values range from 0.015% to 0.02%, gelation strength begin to decrease. While in the same content of calcium ions, calcium lactate exhibits grater effects on gelation strength than calcium chloride. The temperature at the onset of gelation and the gelation rates showed an increase with the increasing of gellen and calcium ions content. At the same calcium ions concentration, the evolution of modulus storage (G′), gel temperature and rate are higher with the addition of calcium lactate than using calcium chloride. Our study indicated exponential relationship between gelling temperature (gelling rate) and calcium concentration.


Author(s):  
Ahmed H. Kamel

Surfactant-based fluids, SB fluids exhibit complex rheological behavior due to substantial structural change caused by the molecules self-assembled colloidal aggregation. Various factors affect their rheological properties. Among these factors, surfactant concentration, shear rate, temperature, and salinity are investigated. One of the most popular surfactants, Aromox® APA-T viscoelastic surfactant (VES) is examined. The study focuses on four different concentrations (1.5%, 2%, 3%, and 4%) over a shear rate ranging from 0.0526 sec−1 to 1944 sec−1 using Bohlin rheometer. For salinity effects, two brine solutions are used; 2 and 4% KCl while for temperature effects, a wide range from ambient temperature of 72°F up to 200°F is covered. The results show that SB fluids exhibit a complex rheological behavior due to its unique nature and the various structures form in the solution. In general, SB fluids at all concentrations exhibit a non-Newtonian pseudo-plastic shear thinning behavior. As the surfactant concentration and/or shear increases, a stronger shear thinning behavior can be seen. Increasing solution salinity promotes formation of rod-like micelles and increases its flexibility. Salinity affects micelles’ growth and their rheological behavior is very sensitive to the nature and structure of the added salt. Different molecular structures are formed; spherical micelles occur first and then increased shear rate and/or salinity promotes the formation of rod-like micelles. Later, rod-like micelles are aligned in the flow direction and form a large super ordered structure of micellar bundles or aggregates called shear induced structure (SIS). Different structures implies different rheological properties. Likewise, rheology improves with increasing temperature up to 100°F. Further increase in temperature reverses the effects and viscosity decreases. However, the effects of temperature and salinity diminish at higher shear rates. Furthermore, a rheology master curve is developed to further understand the rheological behavior of SB fluids and correlate rheological properties to its microscopic structure.


2021 ◽  
pp. 101165
Author(s):  
Juliana Nascimento da Costa ◽  
Luis Gustavo Lima Nascimento ◽  
Amanda Rodrigues Leal ◽  
Florina Danalache ◽  
Bruno Souza Moreira Leite ◽  
...  

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