scholarly journals Embracing ligands. A synthetic strategy towards new nitrogen–thioether multidentate ligands and characterization of the cobalt(iii) complexes

2003 ◽  
pp. 3693-3703 ◽  
Author(s):  
Clint A. Sharrad ◽  
Stefan R. Lüthi ◽  
Lawrence R. Gahan
Synlett ◽  
2022 ◽  
Author(s):  
Qing Li ◽  
Qi Wang ◽  
Yuan Yuan ◽  
Yulan Chen

Quantitative and real-time characterization of mechanically induced bond scission events taken place in polymeric hydrogels is essential to uncover their fracture mechanics. Herein, a class of mechanochemiluminescent swelling hydrogels have been synthesized through a facile micellar copolymerization method using chemiluminescent bis(adamantyl)-1,2-dioxetane (Ad) as a crosslinker. This design and synthetic strategy ensure intense mechanochemiluminescence from Ad located in a hydrophobic network inside micelles. Moreover, the mechanochemiluminescent colors can be tailored from blue to red by mixing variant acceptors. Taking advantages of the transient nature of dioxetane chemiluminescence, the damage distribution and crack evolution of the hydrogels can be visualized and analyzed with high spatial and temporal resolution. The results demonstrate the strengths of the Ad mechanophore and micellar copolymerization method in the study of damage evolution and fracture mechanism of swelling hydrogels.


2015 ◽  
Vol 44 (17) ◽  
pp. 8013-8020 ◽  
Author(s):  
Li Wu ◽  
Wei Zhong ◽  
Beibei Xu ◽  
Zhenhong Wei ◽  
Xiaoming Liu

Like iron(iii) complexes, copper(ii) complexes catalyse the direct hydroxylation of benzene to phenol with H2O2 as the oxidant and their catalytic efficiency correlates with the reduction potentials of the copper(ii) complexes.


2019 ◽  
Author(s):  
Apurba Ranjan Sahoo ◽  
Gummidi Lalitha ◽  
V. Murugesh ◽  
Christian Bruneau ◽  
Gangavaram V. M. Sharma ◽  
...  

A single step synthetic strategy for (±)10- Desbromoarborescidine A is described. Starting from tryptamine and pentan-1,5-diol, this acceptorless dehydrogenative condensation process is efficiently catalyzed by a ruthenium complex featuring proton-responsive phosphine pyridone ligand.<div>Manuscript is available supporting material is available and includes experimental procedures, characterization of compounds, 1H, 13C NMR spectra and chromatograms.</div>


2016 ◽  
Vol 7 (1) ◽  
Author(s):  
Nicolas Zydziak ◽  
Waldemar Konrad ◽  
Florian Feist ◽  
Sergii Afonin ◽  
Steffen Weidner ◽  
...  

Abstract Designing artificial macromolecules with absolute sequence order represents a considerable challenge. Here we report an advanced light-induced avenue to monodisperse sequence-defined functional linear macromolecules up to decamers via a unique photochemical approach. The versatility of the synthetic strategy—combining sequential and modular concepts—enables the synthesis of perfect macromolecules varying in chemical constitution and topology. Specific functions are placed at arbitrary positions along the chain via the successive addition of monomer units and blocks, leading to a library of functional homopolymers, alternating copolymers and block copolymers. The in-depth characterization of each sequence-defined chain confirms the precision nature of the macromolecules. Decoding of the functional information contained in the molecular structure is achieved via tandem mass spectrometry without recourse to their synthetic history, showing that the sequence information can be read. We submit that the presented photochemical strategy is a viable and advanced concept for coding individual monomer units along a macromolecular chain.


Nano Hybrids ◽  
2014 ◽  
Vol 7 ◽  
pp. 69-86 ◽  
Author(s):  
Amlan Kumar Das ◽  
Avinash Marwal ◽  
Ruchi Verma

Over the past two decades, there have been increased emphases on the topic of green chemistry and chemical processes. Utilization of non toxic chemicals, environmentally benign solvents, and renewable materials are some of the key issues that merit important consideration in a green synthetic strategy. The Datura Inoxia leaves possesses biomolecules such as cardiac glycosides, proteins, phenolic compounds, flavonoids and sugar, which could be used as reducing agent to react with ferrous and ferric ions and as scaffolds to direct the formation of Fe3O4 NPs in solution. To the best of our knowledge, the use of Dhatura innoxia plant extract at room temperature for the bio-reductive synthesis of Fe3O4 nanoparticles has not been reported. The formation of the Fe3O4 magnetic nanoparticles was first monitored using UV-Vis absorption spectroscopy. FT-IR spectroscopy and TGA/DTG analysis further confirms the formation of plant protein coated magnetite nanobio hybrid. The dried form of synthesized nanoparticles was further characterized using XRD, TEM.


2019 ◽  
Author(s):  
Apurba Ranjan Sahoo ◽  
Gummidi Lalitha ◽  
V. Murugesh ◽  
Christian Bruneau ◽  
Gangavaram V. M. Sharma ◽  
...  

A single step synthetic strategy for (±)10- Desbromoarborescidine A is described. Starting from tryptamine and pentan-1,5-diol, this acceptorless dehydrogenative condensation process is efficiently catalyzed by a ruthenium complex featuring proton-responsive phosphine pyridone ligand.<div>Manuscript is available supporting material is available and includes experimental procedures, characterization of compounds, 1H, 13C NMR spectra and chromatograms.</div>


2012 ◽  
Vol 3 (11) ◽  
pp. 1554-1558 ◽  
Author(s):  
Vladimir V. Plashnitsa ◽  
Felix Vietmeyer ◽  
Nattasamon Petchsang ◽  
Pornthip Tongying ◽  
Thomas H. Kosel ◽  
...  

Sign in / Sign up

Export Citation Format

Share Document