Structural characterization of metal–metal bonded polymer [Ru(L)(CO)2]n (L = 2,2′-bipyridine) in the solid state using high-resolution NMR and DFT chemical shift calculations

2010 ◽  
Vol 12 (47) ◽  
pp. 15428 ◽  
Author(s):  
Guillaume Gerbaud ◽  
Jean-Marie Mouesca ◽  
Sabine Hediger ◽  
Sylvie Chardon-Noblat ◽  
Frédéric Lafolet ◽  
...  
Keyword(s):  
Solid State ◽  
High Resolution ◽  
Chemical Shift ◽  
Structural Characterization ◽  
Metal Metal ◽  
High Resolution Nmr ◽  
Chemical Shift Calculations

Hydrotelluration of acetylenic esters: structural characterization of stereoisomers of methyl/ethyl β-(aryltelluro)acrylates

RSC Advances ◽  
2015 ◽  
Vol 5 (72) ◽  
pp. 58246-58254 ◽  
Author(s):  
Bandana Singh ◽  
Ashok K. S. Chauhan ◽  
Ramesh C. Srivastava ◽  
Andrew Duthie ◽  
R. J. Butcher
Keyword(s):  
Solid State ◽  
Chemical Shift ◽  
Structural Characterization ◽  
Methyl Ethyl ◽  
Acetylenic Esters ◽  
Solid State Structures

Synthesis of tellurated acrylates, ArTeCHCHCOOR and their solid state structures have been explored. The 125Te chemical shift and 2J(1H–125Te) are useful indicators of their geometry in solution.

Structural characterization of polyallene in the solid state as studied by variable-temperature high-resolution carbon-13 NMR spectroscopy

1991 ◽  
Vol 24 (8) ◽  
pp. 2011-2014 ◽  
Author(s):  
Kyung Hoon Min ◽  
Hiromichi Kurosu ◽  
Isao Ando ◽  
Takakazu Yamamoto ◽  
Takaki Kanbara
Keyword(s):  
Solid State ◽  
Nmr Spectroscopy ◽  
High Resolution ◽  
Structural Characterization ◽  
Variable Temperature

scholarly journals Structural characterization of water-bearing silicate and aluminosilicate glasses by high-resolution solid-state NMR

2001 ◽  
Vol 174 (1-3) ◽  
pp. 291-305 ◽  
Author(s):  
Eric Robert ◽  
Alan Whittington ◽  
Franck Fayon ◽  
Michel Pichavant ◽  
Dominique Massiot
Keyword(s):  
Solid State ◽  
High Resolution ◽  
Structural Characterization ◽  
Solid State Nmr ◽  
Aluminosilicate Glasses

Characterization of Elastomers and Rubber Chemicals by Modern NMR Techniques

1986 ◽  
Vol 59 (2) ◽  
pp. 328-346 ◽  
Author(s):  
R. A. Komoroski ◽  
J. P. Shockcor ◽  
E. C. Gregg ◽  
J. L. Savoca
Keyword(s):  
Solid State ◽  
High Resolution ◽  
Synthetic Polymers ◽  
Computing Systems ◽  
Standard Spectrum ◽  
High Resolution Nmr ◽  
Potential Applications ◽  
Nmr Techniques ◽  
High Degree

Abstract High resolution NMR has undergone a revolution in the last ten years or so. The ability to manipulate spin systems to a high degree in the pulse FT NMR experiment, coupled with advances in NMR computing systems, has led to the design of many multipulse and two-dimensional (2-D) NMR experiments which can provide considerably more information than a standard spectrum. In addition, experiments to obtain high resolution NMR spectra of solid materials have opened a whole area of chemistry to NMR. The new interpretive techniques for spectra obtained in solution have been applied to synthetic polymers or polymer chemicals only recently. However, the solid-state methods already have seen wide application in the polymer area. In this report, we describe some work from our laboratory employing some of these advanced methods in both solution and the solid state. This is not meant to serve as a detailed discussion of the techniques employed, but rather as an introduction to potential applications in the rubber and polymer industries.

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