A flexible Eu(iii)-based metal–organic framework: turn-off luminescent sensor for the detection of Fe(iii) and picric acid

2013 ◽  
Vol 42 (34) ◽  
pp. 12403 ◽  
Author(s):  
Xin-Hui Zhou ◽  
Liang Li ◽  
Hong-Hui Li ◽  
Ao Li ◽  
Tao Yang ◽  
...  
2018 ◽  
Vol 18 (12) ◽  
pp. 7683-7689 ◽  
Author(s):  
Chenghui Zhang ◽  
Huaizhong Shi ◽  
Libo Sun ◽  
Yan Yan ◽  
Bolun Wang ◽  
...  

Nanomaterials ◽  
2018 ◽  
Vol 8 (10) ◽  
pp. 796 ◽  
Author(s):  
Yi Wang ◽  
Shaomin Lin ◽  
Jun Luo ◽  
Rui Huang ◽  
Hong Cai ◽  
...  

Sesamol, is well-known antioxidant and can reduce the rate of oxidation and prolong expiration date. It is also potentially antimutagenic and antihepatotoxic, the detection of sesamol is important and remains a huge challenge. Herein, a new 3D alkaline earth Sr metal organic framework [Sr(BDC)DMACH2O]n (BDC = benzene-1,4-dicarboxylate; DMAC = N,N-dimethylacetamide) is synthesized and a probe based on Tb3+ functionalized Sr-MOF. The Tb(3+)@Sr-MOF showed good luminescence and thermal property. Due to the energy competition between sesamol and ligand, the luminescence intensity of sesamol increases meantime luminescence intensity of Tb3+ decreases, the ratio of the emission intensities (I344/I545) linearly increases with sesamol in concentrations ranging from 1 × 10−7 to 8 × 10−4 M. Furthermore, the fluorescence-detected circular test shows that the composite Tb(3+)@Sr-MOF can serve as ratiometric sensor for sensing of sesamol. This is the first example for self-calibrated detecting sesamol based on metal-organic framework (MOF).


2018 ◽  
Vol 42 (4) ◽  
pp. 2767-2775 ◽  
Author(s):  
Jun-Cheng Jin ◽  
Jian Wu ◽  
Wei-Cong Liu ◽  
Ai-Qing Ma ◽  
Jian-Qiang Liu ◽  
...  

A new Zn(ii) metal–organic framework having 3D CdSO4 topology synthesized and deployed as a dual channel luminescent sensor for ferric ion and nitroaromatics, and a photocatalyst for the degradation of organic dyes.


2020 ◽  
Vol 49 (22) ◽  
pp. 7488-7495 ◽  
Author(s):  
Peng Li ◽  
Meng-Yue Guo ◽  
Lu-Lu Gao ◽  
Xue-Mei Yin ◽  
Shuai-Liang Yang ◽  
...  

Novel 2D → 2D entanglement affords close donor–acceptor contacts for electron transfer based photochromism and photomodulable fluorescence of a MOF, which also serves as a regenerable and sensitive luminescent sensor for nitrofuran antibiotics.


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