Facile synthesis of hierarchical conducting polypyrrole nanostructures via a reactive template of MnO2and their application in supercapacitors

RSC Advances ◽  
2014 ◽  
Vol 4 (1) ◽  
pp. 199-202 ◽  
Author(s):  
Jian-Gan Wang ◽  
Bingqing Wei ◽  
Feiyu Kang
2008 ◽  
Vol 47-50 ◽  
pp. 201-204 ◽  
Author(s):  
Fei Fei Fang ◽  
Jae Lim You ◽  
Hyoung Jin Choi

Large density of the dispersed phase in magnetorheological (MR) fluids has hindered operating MR test and their industrial application. This present work adopted Fe3O4 nanoparticles to prepare MR fluid because of their moderate density and good magnetic property. Furthermore, in order to resolve aggregation problem of Fe3O4 particles due to their nano-scaled size, conducting polypyrrole (PPY) was synthesized around naono-sized Fe3O4 particles via conventional oxidation polymerization. Weight ratio of PPY to Fe3O4 was adjusted to be 5% to avoid possible deterioration of the magnetic property of Fe3O4 particles. TEM images described the morphology for PPY-Fe3O4, and XRD pattern provided information on structural characterization and particle size. Finally, MR performances of pure Fe3O4 and PPY-Fe3O4 nanocomposites were investigated via rotational and oscillatory tests.


2019 ◽  
Vol 14 (8) ◽  
pp. 828-830 ◽  
Author(s):  
Weihua Meng ◽  
Weihong Wu ◽  
Weiwei Zhang ◽  
Luyao Cheng ◽  
Yunhong Jiao ◽  
...  

Synlett ◽  
1991 ◽  
Vol 1991 (09) ◽  
pp. 725-727 ◽  
Author(s):  
Takeshi Shimizu ◽  
Sayoko Hiranuma ◽  
Zhao-hui Qian ◽  
Hirosuke Yoshioka

2015 ◽  
Vol 12 (1) ◽  
pp. 3910-3918 ◽  
Author(s):  
Dr Remon M Zaki ◽  
Prof Adel M. Kamal El-Dean ◽  
Dr Nermin A Marzouk ◽  
Prof Jehan A Micky ◽  
Mrs Rasha H Ahmed

 Incorporating selenium metal bonded to the pyridine nucleus was achieved by the reaction of selenium metal with 2-chloropyridine carbonitrile 1 in the presence of sodium borohydride as reducing agent. The resulting non isolated selanyl sodium salt was subjected to react with various α-halogenated carbonyl compounds to afford the selenyl pyridine derivatives 3a-f  which compounds 3a-d underwent Thorpe-Ziegler cyclization to give 1-amino-2-substitutedselenolo[2,3-b]pyridine compounds 4a-d, while the other compounds 3e,f failed to be cyclized. Basic hydrolysis of amino selenolo[2,3-b]pyridine carboxylate 4a followed by decarboxylation furnished the corresponding amino selenolopyridine compound 6 which was used as a versatile precursor for synthesis of other heterocyclic compound 7-16. All the newly synthesized compounds were established by elemental and spectral analysis (IR, 1H NMR) in addition to mass spectra for some of them hoping these compounds afforded high biological activity.


2019 ◽  
Author(s):  
Min Zhou ◽  
Jet Tsien ◽  
Tian Qin

<p>Herein we report a sulfur (IV) mediated cross-coupling for facile synthesis of heteroaromatic substrates. Addition of heteroaryl nucleophiles onto a simple, readily-accessible alkyl sulfinyl (IV) chloride allows formation of a trigonal bipyramidal sulfurane intermediate. Reductive elimination therefrom provides bis-heteroaryl products in a practical and efficient fashion. <br></p>


Author(s):  
Kathryn Kellett ◽  
Brendan M. Duggan ◽  
Michael Gilson

We have described simple, high-yield, protocols, which require only commonly accessible equipment, to synthesize a wide range of β-CD derivatives mono-substituted at the secondary face. These derivatives may be useful in their own right, and they are also scaffolds for further modification, and examples of the far broader array of derivatives that may be accessed by these procedures.


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