Preparation of VxW1−xO2(M)@SiO2 ultrathin nanostructures with high optical performance and optimization for smart windows by etching

2013 ◽  
Vol 1 (40) ◽  
pp. 12545 ◽  
Author(s):  
Aibin Huang ◽  
Yijie Zhou ◽  
Yamei Li ◽  
Shidong Ji ◽  
Hongjie Luo ◽  
...  
2021 ◽  
Author(s):  
Zemin He ◽  
Ping Yu ◽  
Huimin Zhang ◽  
Yuzhen Zhao ◽  
Yanfang Zhu ◽  
...  

Abstract In this work, two silicon nanostructures were doped into polymer/nematic liquid crystal composites to regulate the electric-optical performance. Commercial SiO2 nanoparticles and synthesized thiol polyhedral oligomeric silsesquioxane (POSS-SH) were chosen as the dopants to afford the silicon nanostructures. SiO2 nanoparticles were physically dispersed in the composites and the nanostructure from POSS-SH was implanted into the polymer matrix of the composites via photoinduced thiol-ene crosslinking. SEM results indicated that the implantation of POSS microstructure into the polymer matrix was conducive to obtaining the uniform porous polymer microstructures in the composites while the introduction of SiO2 nanoparticles led to the loose and heterogeneous polymer morphologies. The electric-optical performance test results also demonstrated that the electric-optical performance regulation effect of POSS microstructure was more obvious than that of SiO2 nanoparticles. The driving voltage was reduced by almost 80% if the concentration of POSS-SH in the composite was nearly 8 wt% and the sample could be completely driven by the electric field whose voltage was lower than the safe voltage for continuous contact (24 V). This work could provide a creative approach for the regulation of electric-optical performance for polymer/nematic liquid crystal composites and the fabrication of low voltage-driven PDLC films for smart windows.


2020 ◽  
Vol 10 (1) ◽  
Author(s):  
Sai Liu ◽  
Chi Yan Tso ◽  
Hau Him Lee ◽  
Yi Zhang ◽  
Kin Man Yu ◽  
...  

2021 ◽  
Author(s):  
Chiyuan Wang ◽  
Huiyan Xu ◽  
Shang Wang ◽  
Xiaodan Guo ◽  
Xin Ma ◽  
...  

2019 ◽  
Vol 88 (3) ◽  
pp. 30301
Author(s):  
Houao Liu ◽  
Hao Song ◽  
Hao Xie ◽  
Guanchao Yin

VO2 is a widely studied thermochromic material for smart windows. In this work, we comprehensively studied optical responses of VO2-based multilayer structures. It is discovered that one-layer antireflection layer is capable of effectively enhancing both luminous transmittance (Tlum) and solar transmittance (Tsol), solar spectrum modulation (ΔTsol) is however quite moderate. Employing a two-top-layer strategy further improves the optical performance of VO2, especially with an increase of ΔTsol from 0.068 to 0.082. Remarkably, combining a layer with an index of 2.2 at the VO2/glass interface continues to enhance the optical performance, leading to the highest Tlum and ΔTsol among the investigated multilayer structures. Compared to the base structure of VO2/glass, it contributes to a relative enhancement of 26.4% (from 0.435 to 0.550) for Tlum (<τc), 35.3% (from 0.362 to 0.490) for Tlum (>τc), and 71.7% (from 0.060 to 0.103) for ΔTsol.


2018 ◽  
Author(s):  
Dmitrii Moldarev ◽  
Elbruz M. Baba ◽  
Marcos V. Moro ◽  
Chang C. You ◽  
Smagul Zh. Karazhanov ◽  
...  

It has been recently demonstrated that yttrium oxyhydride(YHO) films can exhibit reversible photochromic properties when exposed to illumination at ambient conditions. This switchable optical propertyenables their utilization in many technological applications, such as smart windows, sensors, goggles, medical devices, etc. However, how the composition of the films affects their optical properties is not fully clear and therefore demands a straightforward investigation. In this work, the composition of YHO films manufactured by reactive magnetron sputtering under different conditions is deduced in a ternary diagram from Time-of-Flight Elastic Recoil Detection Analysis (ToF-ERDA). The results suggest that stable compounds are formed with a specificchemical formula – YH<sub>2-δ</sub>O<sub>δ</sub>. In addition, optical and electrical properties of the films are investigated, and a correlation with their compositions is established. The corresponding photochromic response is found in a specific oxygen concentration range (0.45 < δ < 1.5) with maximum and minimum of magnitude on the lower and higher border, respectively.


Author(s):  
Seok Je Lee ◽  
Fangnan Yao ◽  
Seung Il Lee ◽  
Cao Jin ◽  
Woo Young Kim ◽  
...  

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