Kinetic reconstruction of TiO2 surfaces as visible-light-active crystalline phases with high photocatalytic performance

2014 ◽  
Vol 2 (14) ◽  
pp. 4907-4911 ◽  
Author(s):  
Peng Zheng ◽  
Ruipeng Hao ◽  
Jianghong Zhao ◽  
Suping Jia ◽  
Baoyue Cao ◽  
...  

Visible light responsive TiO2 crystals form on the surfaces of rutile TiO2 nanocrystals during kinetic phase transformation from anatase to rutile. The nanocrystals exhibit excellent photoelectric conversion properties for photocatalytic hydrogen production.

Catalysts ◽  
2018 ◽  
Vol 8 (9) ◽  
pp. 366 ◽  
Author(s):  
Hongwei Wang ◽  
Guiqing Huang ◽  
Zhiwei Chen ◽  
Weibing Li

In this study, we prepared carbon self-doped carbon nitride nanosheets through a glucose synergic co-condensation method. In the carbon self-doped structure, the N atoms in the triazine rings were substituted by C atoms, resulting in enhanced visible-light photocatalytic hydrogen production, which is three-times higher than that of bulk carbon nitride. The enhanced photocatalytic hydrogen production was attributed to the higher charge-carrier transfer rate and widened light absorption range of the carbon nitride nanosheets after carbon self-doping. Thus, this work highlights the importance of carbon self-doping for improving the photocatalytic performance. Meanwhile, it provides a feasible method for the preparation of carbon self-doped carbon nitride without destroying the 2D conjugated backbone structures.


RSC Advances ◽  
2015 ◽  
Vol 5 (72) ◽  
pp. 58485-58490 ◽  
Author(s):  
Sunil R. Kadam ◽  
Rajendra P. Panmand ◽  
Ravindra S. Sonawane ◽  
Suresh W. Gosavi ◽  
Bharat B. Kale

Herein, we have demonstrated the growth of uniformly distributed Bi2S3 QDs in a glass matrix as a visible light active catalyst for efficient solar H2 production.


Catalysts ◽  
2021 ◽  
Vol 11 (7) ◽  
pp. 848
Author(s):  
Jong-Wook Hong

Visible-light-driven hydrogen production through photocatalysis has attracted enormous interest owing to its great potential to address energy and environmental issues. However, photocatalysis possesses several limitations to overcome for practical applications, such as low light absorption efficiency, rapid charge recombination, and poor stability of photocatalysts. Here, the preparation of efficient noble metal–semiconductor hybrid photocatalysts for photocatalytic hydrogen production is presented. The prepared ternary Rh–TiO2–CeO2 hybrid photocatalysts exhibited excellent photocatalytic performance toward the hydrogen production reaction compared with their counterparts, ascribed to the synergistic combination of Rh, TiO2, and CeO2.


2017 ◽  
Vol 19 (36) ◽  
pp. 24915-24927 ◽  
Author(s):  
A. H. Reshak

The amalgamation of a wide optical band gap photocatalyst with visible-light-active CdO quantum dots (QDs) as sensitizers is one of the most efficient ways to improve photocatalytic performance under visible light irradiation.


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